4-amino-N,N-dioctadecyl-1-hydroxy-2-naphthamide | 65208-33-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-amino-N,N-dioctadecyl-1-hydroxy-2-naphthamide
• 英文别名: 4-amino-1-hydroxy-N,N-dioctadecyl-2-naphthamide；2-Naphthalenecarboxamide, 4-amino-1-hydroxy-N,N-dioctadecyl-；4-amino-1-hydroxy-N,N-dioctadecylnaphthalene-2-carboxamide
• CAS: 65208-33-5
• 化学式: C₄₇H₈₂N₂O₂
• 分子量: 707.18
• InChiKey: MNTWOZWDLYSWPQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.8
• 重原子数：
  51
• 可旋转键数：
  35
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  66.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-amino-N,N-dioctadecyl-1-hydroxy-2-naphthamide 、 4-(2-cyanoethylsulfonyl)benzenesulfonyl chloride 在 水 、 正己烷 作用下， 以 吡啶 、 ice 为溶剂， 反应 2.0h， 以to give 18 g (62 percent) of a tan solid, melting point 85° to 86° C.的产率得到4-[4-(2-cyanoethylsulfonyl)benzenesulfonamido]-1-hydroxy-N,N-dioctadecyl-2-naphthamide
  参考文献：
  名称：

  Photographic products and processes employing novel nondiffusible

  摘要：

  本文描述了一种使用新型不可扩散化合物的摄影元素、扩散转移组合物和工艺，该化合物具有可释放的6-(2-噻吩基偶氮)-3-吡啶醇氰染料基团或其前体，该化合物包含：(a)在噻吩基偶氮基团的3位上有一个羧基、其盐或可水解的前体；(b)一个带有配重的载体基团，在碱性条件下能够释放可扩散的6-(2-噻吩基偶氮)-3-吡啶醇染料基团或其前体。

  公开号：

  US04385104A1

文献信息

• Nondiffusible heterocyclylazonaphthol dye-releasing compounds
  申请人：Eastman Kodak Company

  公开号：US04273706A1

  公开（公告）日：1981-06-16

  Nondiffusible compounds are described having at least one releasable 2-(2-heterocyclylazo)-1-naphthol dye moiety having the formula: ##STR1## wherein: G is hydroxy, a salt thereof, or a hydrolyzable precursor thereof; or a group which together with ##STR2## is CAR, said CAR being bonded to the naphthalene group through the oxygen of said ##STR3## group; Z represents the atoms necessary to complete a heterocyclic ring; CAR represents a ballasted carrier moiety; and t is a positive integer of 1 to 2.

  本文描述了至少具有一个可释放的2-(2-杂环偶氮基)-1-萘酚染料基团的不可扩散化合物，其分子式为：##STR1## 其中：G代表羟基，其盐或其可水解前体；或是与##STR2##一起形成CAR的基团，所述CAR通过##STR3##基团的氧原子与萘基结合；Z代表完成杂环环所需的原子；CAR代表负载载体基团；t为1至2的正整数。
• Photographic elements containing blocked photographic reagents and processes employing same
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0056444A2

  公开（公告）日：1982-07-28

  lmidomethyl blocked photographic reagents are useful in photographic elements and processes. The blocked photographic reagents have the structure: wherein X represents the atoms to complete a 5- or 6- membered ring or ring system; R represents hydrogen, alkyl of 1 to 4 carbon atoms or aryl of 6 to 12 carbon atoms; and PR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the imidomethyl blocking group.

  亚胺甲基封端感光试剂可用于感光元件和工艺中。 封端感光试剂具有以下结构：其中 X 代表原子，以完成 5 或 6 个成员的环或环系统；R 代表氢、1 至 4 个碳原子的烷基或 6 至 12 个碳原子的芳基；PR 代表含有杂原子的有机感光试剂的残留物，通过杂原子与亚胺甲基封端基团连接。
• Photographic elements containing nondiffusible 6-(2-thienylazo)-3-pyridinol cyan dye-releasing compounds
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0063808A1

  公开（公告）日：1982-11-03

  Photographic elements are described which employ nondiffusible compounds having a releasable 6-(2-thienylazo)-3-pyridinol cyan dye moiety or precursor thereof, the compounds containing: (a) in the 3-position of the thienylazo moiety a carboxy group, a salt thereof or a hydrolyzable precursor thereof; and (b) a ballasted carrier moiety which is capable of releasing the diffusible 6-(2-thienylazo)-3-pyridinol dye moiety or precursor thereof under alkaline conditions.

  所述照相元件采用了具有可释放的 6-(2-噻吩基偶氮)-3-吡啶醇青色染料分子或其前体的非扩散性化合物，这些化合物包含： (a) 在噻吩偶氮基 3-位上的羧基、其盐或其可水解前体；以及 (b) 在碱性条件下能释放可扩散的 6-(2-噻吩偶氮)-3-吡啶醇染料分子或其前体的压载载体分子。
• Photographic elements employing nondiffusible azoaminophenol magenta dye-releasing compounds or precursors thereof
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0070019A1

  公开（公告）日：1983-01-19

  Photographic elements are described which employ a novel, nondiffusible compound having a releasable, bridged, azoaminophenol magenta dye moiety or precursor thereof having the formula: wherein: (a) R represents hydrogen, a hydrolyzable moiety or CAR; (b) R1 represents hydrogen; (c) R2 represents an alkyl group of 1 to 6 carbon atoms or CAR; or R1 and R2 represent an alkylene group which can be taken together with the atoms to which they are attached to complete a 5- or 6-membered heterocyclic ring; (d) R3 represents an alkyl group of 1 to 6 carbon atoms or CAR; (e) R4 represents hydrogen; or R3 and R4 represent an alkylene group which can be taken together with the atoms to which they are attached to complete a 5- or 6-membered heterocyclic ring; with the proviso that at least one of the 5- or 6-membered heterocyclic rings of (c) or (e) is present in the compound; (f) CAR represents a ballasted carrier moiety capable of releasing the diffusible magenta dye moiety, or precursor thereof, under alkaline conditions; and (g) n is 0, 1 or 2, with the proviso that when n is 0, then at least one of R, R2 or R3 is CAR.

  所述照相元件采用了一种新型的、不可扩散的化合物，该化合物具有可释放的、桥接的、偶氮氨基苯酚品红色染料分子或其前体，其分子式为 其中 (a) R 代表氢、可水解基团或 CAR； (b) R1 代表氢 (c) R2 代表 1 至 6 个碳原子的烷基或 CAR；或 R1 和 R2 代表一个亚烷基，该亚烷基可与所连接的原子一起组成一个 5 或 6 元杂环； (d) R3 代表 1 至 6 个碳原子的烷基或 CAR； (e) R4 代表氢；或 R3 和 R4 代表一个亚烷基，该亚烷基可与所连接的原子一起组成一个 5 或 6 元杂环；但前提是化合物中至少存在一个(c)或(e)的 5 或 6 元杂环； (f) CAR 代表在碱性条件下能释放可扩散品红色染料分子或其前体的压载载体分子； 以及 (g) n 为 0、1 或 2，但当 n 为 0 时，R、R2 或 R3 中至少有一个是 CAR。
• Photographic products employing novel nondiffusible hydrazone dye-releasing compounds
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0147105A2

  公开（公告）日：1985-07-03

  Photographic elements, diffusion transfer assemblages, - coordination complexes and processes are described which employ a novel nondiffusible hydrazone compound capable of releasing at least one diffusible yellow dye or dye precursor thereof having the formula: wherein: (a) Z1 and Z2 each independently represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic ring; (b) CAR represents a ballasted carrier moiety capable of releasing the diffusible yellow dye moiety or precursor thereof as a function of development; (c) R represents hydrogen, an alkyl or substituted alkyl group of from 1 to about 12 carbon atoms, an aryl or substituted aryl group of from 6 to 12 carbon atoms, a substituted or unsubstituted 5- or 6-membered aromatic heterocylcic ring, or CAR; and (d) n is 0, 1 or 2, with the proviso that when n is 0, then R is CAR. The released hydrazone is premetallized or post metallized to provide excellent yellow image dyes.

  描述了照相元件、扩散转移组合物、配位复合物和工艺，其中采用了一种新型的非扩散腙化合物，该化合物能够释放出至少一种扩散性黄色染料或其染料前体，具有以下式子： 其中 (a) Z1 和 Z2 各自独立地代表完成 5 或 6 元芳香杂环所需的原子； (b) CAR 代表一种压载载体分子，该分子能够释放可扩散的黄色染料分子或其前体，作为发展的函数； (c) R 代表氢、1 至约 12 个碳原子的烷基或取代烷基、6 至 12 个碳原子的芳基或取代芳基、取代或未取代的 5 或 6 元芳香杂环或 CAR；以及 (d) n 为 0、1 或 2，但当 n 为 0 时，R 为 CAR。 释放出的腙经预金属化或金属化后，可提供极佳的黄色图像染料。