Nonadecafluorononanesulfonyl fluoride | 68259-06-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: Nonadecafluorononanesulfonyl fluoride
• 英文别名: 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-nonadecafluorononane-1-sulfonyl fluoride
• CAS: 68259-06-3
• 化学式: C₉F₂₀O₂S
• 分子量: 552.13
• InChiKey: NBFKXQZHVNHRSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  22

文献信息

• Production method of fluorinated purine nucleoside derivative, intermediate therefor and production method thereof
  申请人：Ajinomoto Co., Inc.

  公开号：EP1816135A1

  公开（公告）日：2007-08-08

  Purine nucleosides which are fluorinated at the 3'-position (preferably the α-position), may be economically and efficiently produced by fluorinating a novel purine nucleoside derivative (1) in which the hydroxyl group at the 5'-position is protected to obtain a novel purine nucleoside derivative (2) in a high yield. The derivative (2) is subjected to desulfurization, deprotection of R1 and, as necessary protection, deprotection, or modification of nucleic acid base moiety, to obtain the desired purine nucleoside (3). wherein each symbol is as defined in the specification.

  嘌呤核苷在3'-位（最好是α-位）被氟化后，可以通过氟化一种新的嘌呤核苷衍生物（1）来经济高效地生产，其中5'-位的羟基被保护以获得高产率的新嘌呤核苷衍生物（2）。衍生物（2）经过脱硫化、去保护R1，必要时保护、去保护或修饰核酸碱基部分，以获得所需的嘌呤核苷（3）。 其中每个符号的定义如规范中所述。
• Modified silicon dioxide material of fluorocarbon active agent type super-amphiphobic cutting-carrying agent suitable for water-based drilling fluid and preparation method thereof
  申请人：CHINA UNIVERSITY OF PETROLEUM (BEIJING)

  公开号：US10876034B1

  公开（公告）日：2020-12-29

  The present disclosure relates to the technical field of oil and gas drilling, and particularly relates to a modified silicon dioxide material of a fluorocarbon active agent type super-amphiphobic cutting-carrying agent suitable for a water-based drilling fluid, and a preparation method thereof. The preparation method of the modified silicon dioxide material comprises the following steps: subjecting silicon dioxide and a silane coupling agent represented by Formula (1) to a first contact reaction in a mixed solvent containing alcohol and water; subjecting the product of the first contact reaction, the compound represented by Formula (2) and the compound represented by Formula (3) to a second contact reaction; subjecting the product of the second contact reaction and the compound represented by Formula (4) to a third contact reaction. The modified silicon dioxide material can be used as a cutting-carrying agent in a water-based drilling fluid and produce an excellent cutting-carrying effect.

  本公开涉及油气钻井技术领域，尤其涉及一种适用于水基钻井液的氟碳活性剂型超疏水性切削携带剂的改性二氧化硅材料及其制备方法。该改性二氧化硅材料的制备方法包括以下步骤：将二氧化硅和由式（1）代表的硅烷偶联剂在含有醇和水的混合溶剂中进行第一次接触反应；将第一次接触反应的产物、由式（2）代表的化合物和由式（3）代表的化合物进行第二次接触反应；将第二次接触反应的产物和由式（4）代表的化合物进行第三次接触反应。改性二氧化硅材料可用作水基钻井液中的切削携带剂，并产生极佳的切削携带效果。
• METHOD FOR PRODUCING TRIS(PERFLUOROALKANESULFONYL)METHIDE ACID SALT
  申请人：Central Glass Company, Limited

  公开号：EP2080753B1

  公开（公告）日：2012-02-15
• Method for Producing Tris(Perfluoroalkanesulfonyl)Methide Acid Salt
  申请人：Nanmyo Tsutomu

  公开号：US20100022803A1

  公开（公告）日：2010-01-28

  There is provided a method for producing a tris(perfluoroalkanesulfonyl)methide acid salt represented by formula [1], including the steps of (a) reacting a methylmagnesium halide represented by formula [2] with a perfluoroalkanesulfonyl fluoride represented by formula [3], thereby obtaining a reaction mixture; and (b) directly reacting the obtained reaction mixture with at least one selected from the group consisting of alkali metal halides, quaternary ammonium salts, and quaternary phosphonium salts. By this method, it is possible to easily produce the target methide acid salt with high yield.
• US8304580B2
  申请人：——

  公开号：US8304580B2

  公开（公告）日：2012-11-06