O,O-Dimethyl-O-(6-nitro-3-methylphenyl)-thiophosphat | 724-96-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: O,O-Dimethyl-O-(6-nitro-3-methylphenyl)-thiophosphat
• 英文别名: O,O-Dimethyl-O-<4-nitro-3-methyl-phenyl>thiophosphorsaeure；O,O-Dimethyl O-(6-nitro-m-tolyl) phosphorothioate；dimethoxy-(5-methyl-2-nitrophenoxy)-sulfanylidene-λ5-phosphane
• CAS: 724-96-9
• 化学式: C₉H₁₂NO₅PS
• 分子量: 277.238
• InChiKey: FYRULNKZJJDADM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  106
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• An insecticidal and miticidal composition which contains a carbamate and an organic phosphorus compound, and a method of controlling insects and mites therewith
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0017738A1

  公开（公告）日：1980-10-29

  An insecticidal and miticidal composition in which 2-dimethylamino-5,6-dimethylpyrimidin-4-yl dimethylcarbamate and at least one organic phosphorus compound, methylcarbamate compound, or pyrethroid compound are mixed with an inert carrier.

  一种杀虫和杀螨剂组合物，其中 2-二甲基氨基-5,6-二甲基嘧啶-4-基二甲基氨基甲酸酯和至少一种有机磷化合物、甲基氨基甲酸酯化合物或拟除虫菊酯化合物与惰性载体混合。
• Organophosphorus compounds, process for their preparation and insecticidal, miticidal, nematicidal or soil pesticidal compositions containing them
  申请人：ISHIHARA SANGYO KAISHA, LTD.

  公开号：EP0186124A1

  公开（公告）日：1986-07-02

  An organophosphorus compound having the formula: wherein each of X1, X2 and X3 is a hydrogen atom; an alkyl, alkoxy or alkenyl group which may be substituted by halogen, alkoxy, alkylthio, cycloalkyl or phenyl; a phenyl group which may be substituted by halogen; or a cycloalkyl group, each of Y1, Y2 and Y3 is an oxygen atom or a sulfur atom, Z is a carbonyl group; or a methylene group which may be substituted by a cyloalkyl group, by a phenyl group which may be substituted by halogen, or by an alkyl, alkoxy or alkenyl group which may be substituted by halogen, alkoxy, alkylthio, cycloalkyl or phenyl, and each of R1 and R2 is an alkyl group which may be substituted by halogen, alkoxy or alkylthio.

  一种有机磷化合物，其式如下 其中X1、X2和X3各为氢原子；可被卤素、烷氧基、烷硫基、环烷基或苯基取代的烷基、烷氧基或烯基；可被卤素取代的苯基；或环烷基，Y1、Y2和Y3各为氧原子或硫原子，Z为羰基； 或可被环烷基取代的亚甲基，可被卤素取代的苯基，或可被卤素、烷氧基、烷硫基、环烷基或苯基取代的烷基、烷氧基或烯基，且 R1 和 R2 各为可被卤素、烷氧基或烷硫基取代的烷基。
• Benzoylurea derivative, process for producing the same, insecticide containing the same, reaction intermediate of the same and process for producing the intermediate
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0337600A2

  公开（公告）日：1989-10-18

  A benzoylurea derivative represented by the following formula, wherein R¹ is a fluorine or chlorine atom, R² is a fluorine atom when R¹ is a fluorine atom, and R² is a hydrogen atom when R¹ is a chlorine atom, and X is CF₂Br, CCl₂H, CBr₂H, CFHCl, CFHCF₃, CFHOCF₃, CFHOC₂F₅ or CFHOC₃F₇-n, is a useful insecticide or ovicide and can be formulated it into a composition for such use. An intermediate from which the benzoylurea (I) can be prepared is an aniline of the formula wherein X is as defined above.

  由下式代表的苯甲酰脲衍生物、 其中 R¹ 是氟原子或氯原子，当 R¹ 是氟原子时，R² 是氟原子，当 R¹ 是氯原子时，R² 是氢原子，X 是 CF₂Br、CCl₂H、CBr₂H、CFHCl、CFHCF₃、CFHOCF₃、CFHOC₂F₅或 CFHOC₃F₇-n，是一种有用的杀虫剂或杀卵剂，可将其配制成用于此类用途的组合物。 可以制备苯甲酰脲（I）的中间体是如下式的苯胺 其中 X 如上定义。
• Stabilized agrochemical compositions
  申请人：NIHON BAYER AGROCHEM K.K.

  公开号：EP0431362A1

  公开（公告）日：1991-06-12

  Compositions which contain, as the active ingredients, a combination of a heterocyclic compound of the general formula (I) and an organophosphous compound, in addition to an amorphous silica additive selected from the class consisting of: (a) an amorphous silica obtained by a process, wherein an amorphous silica hydrate, which has been produced by a wet synthetic method, is either silylated or heated to effect an etherification so as to decrease the surface silanol radicals of the amorphous silica hydrate, and (b) an anhydrous, amorphous silica obtained by a dry synthetic method, or a silylated derivative thereof, and optionally one or more compounds having a polyethyleneglycol or polypropyleneglycol chain or an ethyleneglycolpropyleneglycol copolymeric chain, or a mixture of these compounds which results in a stabilization of the active ingredients without any adverse influences on the physical properties of the ingredients.

  含有通式(I)杂环化合物和有机膦化合物的组合物作为活性成分，此外还含有一种无定形二氧化硅添加剂，该添加剂从以下类别中选出： (a) 通过以下工艺获得的无定形二氧化硅：将用湿合成方法制得的无定形二氧化硅水合物进行硅烷化或加热以实现醚化，从而减少无定形二氧化硅水合物的表面硅烷醇基，以及 (b) 用干法合成法得到的无水无定形二氧化硅或其硅烷化衍生物、 以及一种或多种具有聚乙二醇或聚丙二醇链或乙二醇-丙二醇共聚物链的化合物，或这 些化合物的混合物，它们能稳定活性成分，而不会对成分的物理性质产生任何不利影响。
• Imidazolidine derivatives, process for producing the same and pesticides containing the same
  申请人：ISHIHARA SANGYO KAISHA, LTD.

  公开号：EP0437784A1

  公开（公告）日：1991-07-24

  An imidazolidine derivative having the formula (I) or its salt: wherein X is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, a group (in which each of R¹, R², R³ and R⁴ is independently a hydrogen atom or an alkyl group, R⁵ is an alkyl group which may be substituted with a halogen atom, a cycloalkyl group which may be substituted or a phenyl group which may be substituted, W is an oxygen atom or a sulfur atom, and each of k, ℓ, m and n is independently 0 or 1, provided that (a) case where all of k, ℓ and m are 0 at the same time and (b) case where m and n are 0 at the same time and R⁵ is an alkyl group which may be substituted with a halogen atom, are excluded), or a group (in which each of R⁶ and R⁷ is independently a hydrogen atom or an alkyl group, each of R⁸ and R⁹ is independently an alkyl group, R¹⁰ is an alkyl group which may be substituted, an aryl group which may be substituted, a pyridyl group which may be substituted, an alkenyl group which may be substituted with a halogen atom or an alkynyl group which may be substituted with a halogen atom); Y is a 6-chloro-3-pyridyl group or a 2-chloro-5-thiazolyl group; Z is a hydrogen atom, an alkyl group or an acyl group; and j is an integer of from 0 to 2.

  具有式 (I) 或其盐的咪唑烷衍生物： 其中 X 是一个可被取代的烷基、一个可被取代的烯基、一个可被取代的炔基、一个可被取代的基团（其中 R¹、R²、R³ 和 R⁴各自独立地是氢原子或烷基）。 其中每个 R¹、R²、R³ 和 R⁴ 独立地为氢原子或烷基，R⁵ 为可被卤素原子取代的烷基、可被取代的环烷基或可被取代的苯基，W 为氧原子或硫原子、且 k、ℓ、m 和 n 中的每一个独立地为 0 或 1，但 (a) 所有 k、ℓ 和 m 同时为 0 的情况和 (b) m 和 n 同时为 0 且 R⁵ 是可被卤素原子取代的烷基的情况除外)，或一个基团（其中 R⁵ 中的每一个独立地为 0 或 1，但 (a) 所有 k、ℓ 和 m 同时为 0 的情况和 (b) m 和 n 同时为 0 且 R⁵ 是可被卤素原子取代的烷基的情况除外）。 基团（其中 R⁶ 和 R⁷ 各自独立地为氢原子或烷基，R⁸ 和 R⁹ 各自独立地为烷基，R¹⁰ 为可被取代的烷基、可被取代的芳基、可被取代的吡啶基、可被卤素原子取代的烯基或可被卤素原子取代的炔基）；Y 是 6-氯-3-吡啶基或 2-氯-5-噻唑基； Z 是氢原子、烷基或酰基；以及 j 是 0 至 2 的整数。