申请人:3M INNOVATIVE PROPERTIES COMPANY
公开号:US10577451B2
公开(公告)日:2020-03-03
Thermally stable microstructured layers comprising polyurethane, polyurea and/or polyurethane/urea semi-IPN materials are provided which have microstructured surfaces which are highly durable, erosion resistant, and thermally stable. The microstructured layer comprises a semi-IPN of a polymer network selected from the group consisting of urethane acrylate polymer networks, urethane/urea acrylate polymer networks and urea acrylate polymer networks and a linear or branched polymer that is a thermoplastic polymer selected from the group consisting of thermoplastic polyurethanes, thermoplastic polyurethane/polyureas, thermoplastic polyureas, and combinations thereof. The microstructures are thermally stable at temperatures above the crossover point of the thermoplastic polymer, despite comprising a majority of such thermoplastic material. In another aspect, the present disclosure provides methods of making microstructured layers according to the present disclosure.
本发明提供了由聚氨酯、聚脲和/或聚氨酯/脲半 IPN 材料组成的热稳定微结构层,其微结构表面具有高度耐久性、抗侵蚀性和热稳定性。微结构层由选自聚氨酯丙烯酸酯聚合物网络、聚氨酯/尿素丙烯酸酯聚合物网络和脲丙烯酸酯聚合物网络的聚合物网络以及选自热塑性聚氨酯、热塑性聚氨酯/聚脲、热塑性聚脲及其组合的热塑性聚合物的线性或支化聚合物组成的半 IPN 组成。微结构在高于热塑性聚合物交叉点的温度下具有热稳定性,尽管其大部分由此类热塑性材料组成。在另一方面,本公开提供了根据本公开制造微结构层的方法。