5-Acetamido-1-(acetyloxy)naphthalene-2-sulfonic acid | 72076-46-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 5-Acetamido-1-(acetyloxy)naphthalene-2-sulfonic acid
• 英文别名: 5-acetamido-1-acetyloxynaphthalene-2-sulfonic acid
• CAS: 72076-46-1
• 化学式: C₁₄H₁₃NO₆S
• 分子量: 323.32
• InChiKey: RYINRSWFVTYONC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  118
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5-Acetamido-1-(acetyloxy)naphthalene-2-sulfonic acid 、 环丁砜 、 三氯氧磷 在 水 作用下， 以 ice water 为溶剂， 反应 25.0h， 以to obtain 70 g (81% yield) of product的产率得到5-(乙酰氨基)-1-(乙酰氧基)萘-2-磺酰氯
  参考文献：
  名称：

  Photographic element

  摘要：

  一种含有式（I）所表示的化合物的摄影元素：##STR1## 其中G代表-OR.sup.1或-NHR.sup.2，R.sup.1代表氢或可水解的基团，R.sup.2代表氢或含有1至50个碳原子的烷基，Z代表摄影有用的基团，A代表形成芳香环的原子基团，Ball代表位于芳香环上的有机固定基团，其含有8至50个碳原子，m代表1或2的整数，X代表二价有机基团，Nu代表亲核基团，n代表1或2的整数，且X与亲核基团Nu能够通过氧化在被-NHSO.sub.2 Z基团取代的碳原子上形成一个具有电子亲合中心的5-至12元环。

  公开号：

  US04358532A1

文献信息

• Photographic element
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04358532A1

  公开（公告）日：1982-11-09

  A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.

  一种含有式（I）所表示的化合物的摄影元素：##STR1## 其中G代表-OR.sup.1或-NHR.sup.2，R.sup.1代表氢或可水解的基团，R.sup.2代表氢或含有1至50个碳原子的烷基，Z代表摄影有用的基团，A代表形成芳香环的原子基团，Ball代表位于芳香环上的有机固定基团，其含有8至50个碳原子，m代表1或2的整数，X代表二价有机基团，Nu代表亲核基团，n代表1或2的整数，且X与亲核基团Nu能够通过氧化在被-NHSO.sub.2 Z基团取代的碳原子上形成一个具有电子亲合中心的5-至12元环。
• Heat developable color photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0106211A2

  公开（公告）日：1984-04-25

  A heat-developable color photographic material comprising a support having thereon at least a light-sensitive silver halide, a hydrophilic binder and a dye releasing redox compound represented by the following general formula (I): wherein G represents -OR' or -NHR2; R' represents a hydrogen atom or a hydrolyzable group; R2 represents a hydrogen atom or an alkyl group containing from 1 to 50 carbon atoms; Z represents an image forming dye group; A represents an atomic group necessary for forming an aromatic ring; Ball represents an organic immobilizing group on the aromatic ring, and when two Ball groups exist, they may be the same or different from each other; m represents an integer of 1 or 2; X represents a divalent organic group containing from 1 to 8 atoms and X with a nucleophilic group (Nu) is capable of forming a 5- to 12-membered ring together with an electrophilic center (the carbon atom marked with *) which is formed by oxidation; Nu represents a nucleophilic group; and n represents an integer of 1 or 2. The heat-developable color photographic material can easily provide a dear and stable color image by imagewise exposure to light and a heat-development procedure. A method of forming a color image using the heatrdevelopable color photographic material is also disclosed.

  一种可热显影的彩色感光材料，包括至少有感光卤化银的支持物、亲水性粘合剂和由下通式(I)代表的染料释放氧化还原化合物： 其中 G 代表-OR'或-NHR2；R'代表氢原子或可水解基团；R2 代表氢原子或含有 1 至 50 个碳原子的烷基；Z 代表形成图像的染料基团；A 代表形成芳香环所必需的原子团；Ball 代表芳香环上的有机固定基团，当存在两个 Ball 基团时，它们可以相同或互不相同；m 代表 1 或 2 的整数；X 代表含有 1 至 8 个原子的二价有机基团，带有亲核基团（Nu）的 X 能与通过氧化形成的亲电中心（标有 * 的碳原子）一起形成 5 至 12 元环；Nu 代表亲核基团；n 代表 1 或 2 的整数。 这种可热显影的彩色感光材料可通过图像曝光和热显影程序轻松提供亲切而稳定的彩色图像。此外，还公开了一种使用热显影彩色感光材料形成彩色图像的方法。
• USH98H
  申请人：——

  公开号：USH98H

  公开（公告）日：1986-08-05
• Heat-developable color photographic material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：USH0000098H1

  公开（公告）日：1986-08-05

  A heat-developable color photographic material comprising a support having thereon at least a light-sensitive silver halide, a hydrophilic binder and a dye releasing redox compound represented by the following general formula (I): ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2 ; R.sup.1 represents a hydrogen atom or a hydrolyzable group; R.sup.2 represents a hydrogen atom or an alkyl group containing from 1 to 50 carbon atoms; Z represents an image forming dye group; A represents an atomic group necessary for forming an aromatic ring; Ball represents an organic immobilizing group on the aromatic ring, and when two Ball groups exist, they may be the same or different from each other; m represents an integer of 1 or 2; X represents a divalent organic group containing from 1 to 8 atoms and X with a nucleophilic group (Nu) is capable of forming a 5- to 12-membered ring together with an electrophilic center (the carbon atom marked with *) which is formed by oxidation; Nu represents a nucleophilic group; and n represents an integer of 1 or 2. The heat-developable color photographic material can easily provide a clear and stable color image by imagewise exposure to light and a heat-development procedure. A method of forming a color image using the heat-developable color photographic material is also disclosed.

  一种热显影彩色感光材料，包括支撑物，其上至少具有一种光敏银卤化物、一种亲水性粘合剂以及一种由下列通式（I）表示的染料释放氧化还原化合物：##STR1## 其中，G代表--OR.sup.1或--NHR.sup.2；R.sup.1代表氢原子或可水解基团；R.sup.2代表氢原子或含有1至50个碳原子的烷基；Z代表成像染料基团；A代表必要的原子基团以形成芳香环；Ball代表芳香环上的有机固定基团，当存在两个Ball基团时，它们可以相同或不同；m代表1或2的整数；X代表含有1至8个原子的二价有机基团，X与亲核基团（Nu）一起能够形成一个5至12个成员环，该环与由氧化形成的电子亲合中心（标有*的碳原子）一起；Nu代表亲核基团；n代表1或2的整数。该热显影彩色感光材料可以通过成像曝光和热显影程序轻松提供清晰稳定的彩色图像。还公开了一种使用该热显影彩色感光材料形成彩色图像的方法。