5-tert-Butyl-2,2-dimethyl-3,4-dihydro-2H-1-benzopyran-6-ol | 64918-68-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 5-tert-Butyl-2,2-dimethyl-3,4-dihydro-2H-1-benzopyran-6-ol
• 英文别名: 5-tert-butyl-2,2-dimethyl-3,4-dihydrochromen-6-ol
• CAS: 64918-68-9
• 化学式: C₁₅H₂₂O₂
• 分子量: 234.33
• InChiKey: RPQRJHIRYNYOBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• PROPYLENE COPOLYMER, POLYPROPYLENE COMPOSITION AND USES THEREOF, TRANSITION METAL COMPOUND AND OLEFIN POLYMERIZATION CATALYST
  申请人：Ikenaga Shigenobu

  公开号：US20080312461A1

  公开（公告）日：2008-12-18

  A transition metal compound represented by the following formula (2a):

  一个以以下公式（2a）表示的过渡金属化合物：
• Propylene copolymer, polypropylene composition, and uses thereof, transition metal compounds and catalyst for olefin polymerization
  申请人：Ikenaga Shigenobu

  公开号：US20060276607A1

  公开（公告）日：2006-12-07

  The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120° C., and satisfies the following relation 146 exp(−0.022M)≧ Tm ≧125 exp(−0.032M) wherein Tm represents a melting point and M (mol %) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R 1 and R 3 is hydrogen, R 2 and R 4 are selected from a hydrocarbon group and silicon-containing group, R 5 to R 13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R 5 to R 12 may be linked to form a ring. R 14 is an aryl group, and R 13 and R 14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.

  本发明提供一种具有优异的柔韧性、抗冲击性、耐热性和低温热封性能的丙烯/1-丁烯随机共聚物（PBR），以及包含该共聚物的聚丙烯组合物、由该组合物制成的片材、薄膜或拉伸膜以及具有该组合物层的复合膜。该丙烯/1-丁烯随机共聚物含有60到90摩尔％的丙烯单元和10到40摩尔％的1-丁烯单元，三元等规度不小于85％且不大于97.5％，分子量分布（Mw/Mn）为1到3，固有粘度为0.1到12 dl/g，熔点（Tm）为40到120℃，并满足以下关系式146 exp（-0.022M）≥Tm≥125 exp（-0.032M），其中Tm表示熔点，M（摩尔％）表示1-丁烯组分单元的含量。本发明还提供一种过渡金属化合物，可用作烯烃聚合催化剂，以及含有该过渡金属化合物的烯烃聚合催化剂。该过渡金属化合物由以下式（2a）表示：其中R1和R3分别为氢，R2和R4选自烃基和含硅基，R5到R13选自氢、烃基和含硅基，相邻的取代基R5到R12可连接形成环。R14为芳基，R13和R14可连接形成环。M为4族过渡金属，Y为碳原子，Q为卤素等，j为1到4的整数。
• Food container
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0407198A1

  公开（公告）日：1991-01-09

  Disclosed herein is a food container of a resin com­position composed of a polyolefin and an inorganic filler, said resin composition containing (i) a phenolic anti­oxidant and (ii) a slip agent and/or antistatic agent, said phenolic antioxidant being at least one kind selected from β-(4-hydroxy-3-t-butyl-5-alkylphenyl)propionic acid esters, hindered phenols having an isocyanuric acid ester, 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)-2,4,6-­trimethylbenzene, specific phenol compounds, and 6-­hydroxychroman compounds. The food container has a low level of offensive odors and discoloration.

  本发明公开了一种由聚烯烃和无机填料组成的树脂组合物的食品容器，所述树脂组合物含有(i)酚类抗氧化剂和(ii)滑爽剂和/或抗静电剂、所述酚类抗氧化剂至少有一种选自β-(4-羟基-3-叔丁基-5-烷基苯基)丙酸酯、具有异氰尿酸酯的受阻酚、1,3,5-三(3,5-二叔丁基-4-羟基苄基)-2,4,6-三甲基苯、特定酚类化合物和 6-羟基色满化合物。食品容器的异味和褪色程度较低。
• Composition of polypropylene with propylene-butene elastomer
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0716121A1

  公开（公告）日：1996-06-12

  Disclosed is a polypropylene composition comprising (A) polypropylene and (B) a specific propylene-l-butene random copolymer in a specific amount ratio. The propylene-l-butene random copolymer (B) is characterized in that: (1) the copolymer contains 50 to 95 % by mol of constituent units from propylene and 50 to 5 % by mol of constituent units from 1-butene, (2) the intrinsic viscosity, as measured in decahydronaphthalene at 135 °C, is in the range of 0.1 to 12 dl/g, (3) the molecular weight distribution (Mw/Mn), as determined measured by GPC, is not more than 3, and (4) the parameter B value indicating randomness of the copolymerized monomer sequence distribution is in the range of 1.0 to 1.5. Also disclosed is a polypropylene composite film comprising (I) a crystalline polypropylene layer and (II) a layer formed from the polypropylene composition, which is laminated on at least one surface of the crystalline polypropylene layer (I). The polypropylene composition is excellent in heat resistance and low-temperature heat-sealing properties as well as in flexibility and impact resistance. The polypropylene composite film is excellent in not only heat-sealing properties, particularly low-temperature heat-sealing properties, but also transparency, scratch resistance and blocking resistance.

  本发明公开了一种聚丙烯组合物，该组合物由(A)聚丙烯和(B)特定量比的丙烯-l-丁烯无规共聚物组成。丙烯-l-丁烯无规共聚物（B）的特征在于(1) 以摩尔计，该共聚物含有 50%至 95%的丙烯组成单元和 50%至 5%的 1-丁烯组成单元， (2) 在 135 °C 的十氢萘中测得的本征粘度范围为 0.(3) 由 GPC 测定的分子量分布 (Mw/Mn) 不超过 3，以及 (4) 表示共聚单体序列分布随机性的参数 B 值在 1.0 至 1.5 的范围内。还公开了一种聚丙烯复合膜，包括 (I) 结晶聚丙烯层和 (II) 由聚丙烯组合物形成的层，该层层叠在结晶聚丙烯层 (I) 的至少一个表面上。聚丙烯组合物具有优异的耐热性、低温热封性、柔韧性和抗冲击性。聚丙烯复合薄膜不仅热封性能优异，特别是低温热封性能优异，而且透明度、抗划伤性和抗阻塞性也很好。
• ETHYLENE COPOLYMER AND ETHYLENE/$g(a)-OLEFIN COPOLYMER COMPOSITION AND PROPYLENE POLYMER COMPOSITION BOTH CONTAINING THE ETHYLENE COPOLYMER
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1241191A1

  公开（公告）日：2002-09-18

  The present invention relates to an ethylene-based copolymer useful as a modifier for resins, e.g., polypropylene, and an ethylene/α-olefin copolymer composition containing the same ethylene-based copolymer. The ethylene-based copolymer [I] of the present invention is characterized by: (a-1) having temperature (Tm) at the maximum peak in the endothermic curve, measured by a differential scanning calorimeter (DSC), of 40 to 90°C, (a-2) containing the component soluble in decane at normal temperature at 1 to 70% by weight, and (a-3) containing the component soluble in decane at normal temperature which comprises (i) a recurring unit derived from ethylene and (ii) a recurring unit derived from an α-olefin of 4 or more carbon atoms, and in which a content of (i) the recurring unit derived from ethylene is 50 to 75% by mole. The ethylene-based copolymer composition [II] of the present invention is characterized by containing the ethylene-based copolymer which satisfies the following conditions (b-1) to (b-3): (b-1) having temperature (Tm) at the maximum peak in the endothermic curve of the component soluble in decane at 64°C, measured by a differential scanning calorimeter (DSC), of 40 to 90°C, (b-2) containing the component soluble in decane at 64°C which contains the component soluble in decane at normal temperature at 1 to 70% by weight, and (b-3) containing the component soluble in decane at normal temperature which comprises (i) a recurring unit derived from ethylene and (ii) a recurring unit derived from an α-olefin of 4 or more carbon atoms, and in which a content of (i) the recurring unit derived from ethylene is 50 to 75% by mole.

  本发明涉及一种可用作树脂（如聚丙烯）改性剂的乙烯基共聚物，以及一种含有相同乙烯基共聚物的乙烯/α-烯烃共聚物组合物。 本发明的乙烯基共聚物[I]的特征是： (a-1) 用差示扫描量热仪（DSC）测得的内热曲线最大峰值处的温度（Tm）为 40 至 90℃、 (a-2) 所含成分在常温下可溶于癸烷，溶解度为 1%至 70%（按重量计），以及 (a-3) 含有在常温下可溶于癸烷的组分，该组分包括(i) 源自乙烯的循环单元和(ii) 源自 4 个或更多碳原子的 α-烯烃的循环单元，以及 其中(i) 由乙烯衍生的递归单元的含量为 50%至 75%（以摩尔计）。本发明的乙烯基共聚物组合物[II]的特点是含有满足以下条件（b-1）至（b-3）的乙烯基共聚物： (b-1) 用差示扫描量热仪（DSC）测量，溶于癸烷的组分在 64℃时的内热曲线最大峰值处的温度（Tm）为 40 至 90℃、 (b-2) 含有在 64℃时可溶于癸烷的组分，其中含有在常温下可溶于癸烷的组分的重量比为 1%至 70%，以及 (b-3) 含有在常温下可溶于癸烷的组分，该组分包括(i) 源自乙烯的循环单元和(ii) 源自 4 个或更多碳原子的 α-烯烃的循环单元，以及 其中(i) 由乙烯衍生的递归单元的含量为 50%至 75%（以摩尔计）。