1-Ethenyl-4-({3-[(naphthalen-1-yl)sulfanyl]propyl}sulfanyl)naphthalene | 244301-24-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-Ethenyl-4-({3-[(naphthalen-1-yl)sulfanyl]propyl}sulfanyl)naphthalene
• 英文别名: 1-ethenyl-4-(3-naphthalen-1-ylsulfanylpropylsulfanyl)naphthalene
• CAS: 244301-24-4
• 化学式: C₂₅H₂₂S₂
• 分子量: 386.6
• InChiKey: JMXSUAOKNZHTEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Optical article and process for forming article
  申请人：LUCENT TECHNOLOGIES INC.

  公开号：EP0945762A1

  公开（公告）日：1999-09-29

  The optical article of the invention, e.g., holographic recording medium or polymeric waveguide, is formed by mixing a matrix precursor and a photoactive monomer, and curing the mixture to form the matrix in situ. The reaction by which the matrix precursor is polymerized during the cure is independent from the reaction by which the photoactive monomer is polymerized during writing of data. In addition, the matrix polymer and the polymer resulting from polymerization of the photoactive monomer are compatible with each other. Use of a matrix precursor and photoactive monomer that polymerize by independent reactions substantially prevents cross-reaction between the photoactive monomer and the matrix precursor during the cure and inhibition of subsequent monomer polymerization. Use of a matrix precursor and photoactive monomer that result in compatible polymers substantially avoids phase separation. And in situ formation allows fabrication of articles with desirable thicknesses.

  本发明的光学产品，例如全息记录介质或聚合物波导，是通过混合基质前体和光活性单体，并固化混合物以在原位形成基质而形成的。基质前体在固化过程中的聚合反应与光活性单体在写入数据过程中的聚合反应无关。此外，基质聚合物和光活性单体聚合产生的聚合物是相互兼容的。使用通过独立反应聚合的基质前体和光活性单体，可有效防止光活性单体和基质前体在固化过程中发生交叉反应，并抑制后续单体聚合。使用可产生相容聚合物的基质前体和光活性单体，可有效避免相分离。原位形成可制造出具有理想厚度的产品。
• Process and composition for rapid mass production of holographic recording article
  申请人：——

  公开号：US20030044691A1

  公开（公告）日：2003-03-06

  A rapid mass production of the high performance holographic recording articles including the process and composition are described. To prepare a high performance holographic recording article based on two-component urethane matrix system, for example, polyols and all the additives must be virtually free of moisture contents. Deaeration must be carried out, once isocyanate and polyols including catalysts and all other ingredients are mixed together, to eliminate all entrapped air that is introduced into the mixture during mixing. The deaeration takes time, and the urethane reaction must not be allowed to take place until all air bubbles are evacuated from the isocyanate-polyols mixture. The rapid mass production of this invention overcomes such process limitations and results in a high-volume production of the high performance holographic recording articles.

  本文介绍了一种快速批量生产高性能全息记录制品的方法，包括工艺和成分。例如，要制备基于双组分聚氨酯基质系统的高性能全息记录制品，多元醇和所有添加剂必须几乎不含水分。异氰酸酯和多元醇（包括催化剂）以及所有其他成分混合在一起后，必须进行脱气，以消除在混合过程中进入混合物的所有夹带空气。脱气需要时间，在异氰酸酯-多元醇混合物中的气泡全部排出之前，不得进行聚氨酯反应。本发明的快速批量生产克服了这些工艺限制，可大批量生产高性能全息记录产品。
• Blue-sensitized holographic media
  申请人：——

  公开号：US20030083395A1

  公开（公告）日：2003-05-01

  Blue-sensitized holographic media suitable for recording with a blue laser is disclosed. The blue-sensitized holographic media provides greater dynamic range and a higher sensitivity than a green-sensitized holographic media, thereby providing more rapid hologram writing times.

  本发明公开了适用于用蓝色激光记录的蓝色敏化全息介质。与绿色感光全息介质相比，蓝色感光全息介质具有更大的动态范围和更高的灵敏度，从而提供更快的全息图写入时间。
• Novel exceptional high reflective index photoactive compound for optical applications
  申请人：——

  公开号：US20030224250A1

  公开（公告）日：2003-12-04

  A novel liquid photoreactive asymmetric acrylate compound containing sulfur, aromatic moieties, and optionally bromine, and having high dynamic range sensitivity is disclosed. The acrylate compound is a monomer for a photoimageable system. In one embodiment, when about 2-8% by weight of the acrylate compound is dissolved in a two-component urethane matrix system and incorporated in an optical article formed by reacting the two-component urethane matrix system, the optical article shows a sensitivity of about 4 or more and a shrinkage during the formation of the optical article of about 0.05% versus a sensitivity of 2.26 and a shrinkage of 0.13% when tribromophenyl acrylate, a commercial monomer, was used.

  本发明公开了一种新型液态光活性不对称丙烯酸酯化合物，该化合物含有硫、芳香族和可选溴，具有高动态范围灵敏度。该丙烯酸酯化合物是光成像系统的单体。在一个实施例中，当约 2-8%（重量）的丙烯酸酯化合物溶解在双组分聚氨酯基质体系中，并加入到通过双组分聚氨酯基质体系反应形成的光学制品中时，光学制品的灵敏度约为 4 或更高，在光学制品形成过程中的收缩率约为 0.05%，而使用商用单体丙烯酸三溴苯酯时，灵敏度为 2.26，收缩率为 0.13%。
• Process for forming an optical article
  申请人：Akonia Holographics, LLC

  公开号：EP0945762B1

  公开（公告）日：2013-04-24