2,3-dimethyl-1,10-phenanthroline | 76130-57-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2,3-dimethyl-1,10-phenanthroline
• CAS: 76130-57-9
• 化学式: C₁₄H₁₂N₂
• 分子量: 208.263
• InChiKey: BEHYHCBDZZQSBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  铌 、 2,3-dimethyl-1,10-phenanthroline 在 KSCN 作用下， 以 硫酸 为溶剂， 生成
  参考文献：
  名称：

  Lobanov, F. N.; Zatonskaya, V. M.; Gibalo, I. M., Russian Journal of Inorganic Chemistry, 1980, vol. 25, p. 1651 - 1653

  摘要：

  DOI：

文献信息

• ORGANIC LIGHT-EMITTING DIODE MATERIALS
  申请人：President and Fellows of Harvard College

  公开号：US20180212158A1

  公开（公告）日：2018-07-26

  Described herin are molecules for use in organic light emitting diodes. Example molecules comprise at least one acceptor moiety A, at least one donor moiety D, and optionally one or more bridge moieties B. Each moiety A is covalently attached to either the moiety B or the moeity D, each moiety D is covalently attached to either the moeity B or the moeity A, and each B is covalently attached to at least one moiety A and at least one moiety D. Values and preferred values of moieties A, D and B are defined herein.

  本文描述了用于有机发光二极管的分子。示例分子包括至少一个受体基团A，至少一个给体基团D，以及可选地一个或多个桥接基团B。每个基团A与基团B或基团D中的任一基团共价连接，每个基团D与基团B或基团A中的任一基团共价连接，每个基团B与至少一个基团A和至少一个基团D共价连接。这里定义了基团A、D和B的值和首选值。
• Process for the catalytic reduction of nitro-aromatic compounds
  申请人：Montedison S.p.A.

  公开号：EP0091383A1

  公开（公告）日：1983-10-12

  The present invention describes a process for the catalytic reduction of nitro-aromatic compounds by transfer of hydrogen from alcohols to nitro-aromatic compounds, said reduction being catalyzed by iridium complexes and characterized in that a primary or secondary alcohol having the formula (I) or a glycol: is made to react with a nitro-aromatic compound having the formula (II): wherein: R and R', possibly linked to each other according to homo- or heterocycles, represent indifferently either a hydrogen atom or a possibly substituted hydrocarbylic group having up to 30 carbon atoms; Ar represents an aryl or hetero-aryl group, also substituted with inert groups; x and y, either equal to or different from each other, represent an integer chosen from 1 and 2, in the presence of a complex catalyst of iridium chosen from among those having formulae (III) and (IV): and wherein: Chel represents a kelating bi-toothed nitrogeneous compound; L-L represents a molecule of a diolefine, preferably not conjugated; L represents a mono-olefine molecule; X- represents an anion chosen from among: Cl-, Br-, I-, PF6-, BR4-, ClO4-, B(C6H5)4-, OH-, wherein R and R' have the significance already given to them; Y is a halogen, preferably Cl, Br or I; and optionally with a compound chosen from mineral alkaline compounds, at a temperature comprised between about 20°C and the boiling temperature of the reaction mass. The compounds thus obtained consist of the derivatives of the partial or total hydrogenation of the nitro-aromatic starting compounds constituted by anilines or aryl-amines in general, by the aryl-hydroxyl-amines, by the aryl-hydrazo compounds and by the aryl-azo compounds, and can be used as intermediates for organic syntheses in general, in the field of fine chemistry.

  本发明描述了一种通过将氢从醇转移到硝基芳香族化合物而催化还原硝基芳香族化合物的工艺，所述还原由铱络合物催化，其特征在于，具有式（I）的伯醇或仲醇或乙二醇与具有式（II）的硝基芳香族化合物反应： 与具有式（II）的硝基芳香化合物反应： 其中 R 和 R'，可根据同环或杂环相互连接，无一例外地代表氢原子或可能被取代的碳原子数不超过 30 个的烃基； Ar 代表芳基或杂芳基，也可被惰性基团取代； x和y，彼此相等或不同，代表选自 1 和 2 的整数，在有选自式（III）和（IV）的铱络 合催化剂存在的情况下： 和 其中 Chel 代表酮化双齿硝基化合物； L-L 代表二烯烃分子，最好不是共轭的； L 代表单烯烃分子； X- 代表一种阴离子，选自以下几种阴离子Cl-、Br-、I-、PF6-、BR4-、ClO4-、B(C6H5)4-、OH-、 其中 R 和 R'具有上述含义； Y 是卤素，最好是 Cl、Br 或 I；可选择与选自矿物碱性化合物的化合物一起，在约 20°C 至反应物沸腾温度之间的温度下进行。 这样得到的化合物是由苯胺或芳基胺、芳基羟基胺、芳基氢氮化合物和芳基偶氮化合物构成的硝基芳香族起始化合物部分或全部氢化的衍生物，可用作精细化工领域一般有机合成的中间体。
• Catalyst compositions and process for preparing olefin/CO copolymers
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0254343A1

  公开（公告）日：1988-01-27

  1. Novel catalyst compositions characterized in that they are based upon: a) a palladium compound, b) a quaternary phosphonium salt of an acid with a pKa of less than 2, with the proviso that the acid is not a hydrohalogenic acid or a mixture of such a salt and acid, and c) either a phosphorus bidentate ligand of the general formula R¹R²-P-R-P-R³R⁴, wherein R¹, R², R³ and R⁴ are hydrocarbyl groups which may or may not be substituted with polar groups and R represents a bivalent organic bridging group containing at least two carbon atoms in the bridge, or a nitrogen bidentate ligand of the general formula wherein X and Y are similar or dissimilar bridging groups, each containing three or four atoms in the bridge at least two of which are carbon atoms.

  1.新型催化剂组合物，其特征在于： a) 钯化合物、 b) 一种 pKa 小于 2 的酸的季鏻盐，但该酸不是氢卤酸或这种盐和酸的混合物，以及 c) 通式为 R¹R²-P-R-P-R³R⁴的磷双叉配体，其中 R¹、R²、R³ 和 R⁴ 为可能被或可能不被极性基团取代的烃基，R 代表桥中至少含有两个碳原子的二价有机桥基，或通式为氮双叉配体。 其中 X 和 Y 是相似或不相似的桥基，每个桥基含有三个或四个原子，其中至少两个是碳原子。
• Porphyric insecticides
  申请人：The Board of Trustees for the University of Illinois

  公开号：EP0326835A1

  公开（公告）日：1989-08-09

  Insecticidal compositions comprising one or more compounds' selected from the group consisting of delta-aminolevulinic acid, inducers of delta aminolevulinic acid, and enhancers of delta-aminolevulinic acid conversion to photodynamic tetrapyrroles; and methods of making and using same.

  包含一种或多种选自δ-氨基乙酰丙酸、δ-氨基乙酰丙酸诱导剂和δ-氨基乙酰丙酸转化为光动力四吡咯的增强剂的化合物的杀虫组合物；以及其制造和使用方法。
• Process to obtain new mixed copper aminoacidate complexes from phenanthrolines and their alkyl derivatives to be used as anticancerigenic agents
  申请人：UNIVERSIDAD NACIONAL AUTONOMA DE MEXICO

  公开号：EP0434445A2

  公开（公告）日：1991-06-26

  This invention refers to a process to obtain new mixed copper aminoacidates from phenanthrolines and their alkyl derivates of an aromatic type to be used as anticancerigenic, agents preferably with a therapeutic use for the treatment of liquid and solid cancerigenic tumours such as leukemia. The complexes obtained are of the [Cu (N-N) (N-O)]⁺⁻ NO₃ type in which the N-N ligand corresponds to 4, 7-dimethyl-1, 10 phenanthroline and the N-O ligand preferably correponds to one of the aminoacidates such as tyrosine-alaninate, treoninate, triptophanate, valinate, isoleucinate, cisteinate, diglycinate, phenylalaninate, glycinate, hystidinate, serinate, tyrosinate, aspartate, alaninate and phenylalaninate. The process is characterized because it includes the following steps: making an aqueous solution based on an aliphatic alcohol and 4, 7-dimethyl-1, 10 phenanthroline react with a copper complex preferably CuNO₃5H₂O at room temperature, and immediately after making the obtained product react in an aqueous aminoacidate solution adjusting a slightly alkaline pH.

  本发明涉及一种从菲罗啉及其芳香族烷基衍生物中获得新的混合氨基酸铜的工艺，该工艺可用作抗癌剂，优选用于治疗液态和固态致癌肿瘤，如白血病。所获得的配合物为[Cu (N-N) (N-O)]⁺- NO₃型，其中 N-N 配体对应于 4，7-二甲基-1，10-菲罗啉，N-O 配体最好对应于氨基酸盐之一，如酪氨酸丙氨酸盐、曲安酸盐、三色氨酸盐、氨酸、三色氨酸、缬氨酸、异亮氨酸、肌氨酸、二甘氨酸、苯丙氨酸、甘氨酸、胱氨酸、丝氨酸、酪氨酸、天门冬氨酸、丙氨酸和苯丙氨酸。该工艺的特点是包括以下步骤：在室温下，使基于脂肪醇和 4，7-二甲基-1，10-菲罗啉的水溶液与铜络合物（最好是 CuNO₃5H₂O）反应，然后立即使得到的产物在调节 pH 值为微碱性的氨基酸水溶液中反应。