2,2'-[Naphthalene-1,2-diylbis(oxymethylene)]bis(oxirane) | 49548-35-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,2'-[Naphthalene-1,2-diylbis(oxymethylene)]bis(oxirane)
• 英文别名: 2-[[1-(oxiran-2-ylmethoxy)naphthalen-2-yl]oxymethyl]oxirane
• CAS: 49548-35-8
• 化学式: C₁₆H₁₆O₄
• 分子量: 272.29
• InChiKey: OGRULRAOMCDCBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• NOVOLAC RESIN AND RESIST FILM
  申请人：DIC Corporation

  公开号：US20180334523A1

  公开（公告）日：2018-11-22

  Provided are a novolac resin having developability, heat resistance, and dry etching resistance, and a photosensitive composition, a curable composition, and a resist film. A novolac resin including, as a repeating unit, a structural moiety represented by Structural Formula (1) or (2): (in the formula, Ar represents an arylene group, R 1 's each independently represent any one of a hydrogen atom, an alkyl group, an alkoxy group, and a halogen atom, m's each independently represent an integer of 1 to 3, and X is any one of a hydrogen atom, a tertiary alkyl group, an alkoxyalkyl group, an acyl group, an alkoxycarbonyl group, a hetero atom-containing cyclic hydrocarbon group, and a trialkylsilyl group) in which at least one of X's present in the resin is any one of a tertiary alkyl group, an alkoxyalkyl group, an acyl group, an alkoxycarbonyl group, a hetero atom-containing cyclic hydrocarbon group, and a trialkylsilyl group.

  提供一种具有可开发性、耐热性和干法蚀刻抗性的新戊醛树脂，以及一种光敏组合物、可固化组合物和抗蚀膜。一种新戊醛树脂包括以下结构单元： （在公式中，Ar代表芳基，R 1 分别独立地代表氢原子、烷基、烷氧基和卤素原子中的任意一种，m分别独立地代表1至3的整数，X代表氢原子、三级烷基、烷氧基烷基、酰基、烷氧羰基、含杂原子的环烃基和三烷基硅基中的任意一种），树脂中至少有一个X是三级烷基、烷氧基烷基、酰基、烷氧羰基、含杂原子的环烃基和三烷基硅基中的任意一种。
• Thermosetting resin composition, electrically insulated coil, electric rotating machine and method for producing same
  申请人：HITACHI, LTD.

  公开号：EP0810249A2

  公开（公告）日：1997-12-03

  A highly thermal-conductive and thermal-resistant electrically insulated coil with less outflow of a thermosetting resin composition can be produced, to provide a small-scale, light-weight rotating machine with high power. The thermosetting resin composition comprising (a) a polyfunctional epoxy resin containing three or more p-(2,3-epoxypropoxy)phenyl groups and a group represented by the Chemical formula 1; or an epoxy resin with a naphthalene backbone, represented by the Chemical formula 3, 4 or 5 or an epoxy resin with an anthracene backbone, such as diglycidyl ether of anthracene diol and triglycidyl ether of anthracene triol; (b) a bifunctional epoxy resin containing two p-(2,3-epoxypropoxy)phenyl groups; (c) an acid anhydride curing agent; and (d) a metal acetonate curing catalyst represented by the Chemical formula 2 at 0.1 to 5 parts by weight per 100 parts by weight of the epoxy resins. In accordance with the present invention, a highly thermal-conductive and thermal-resistant electrically insulated coil with less outflow of the thermosetting resin composition can be produced, to provide a small-scale, light-weight rotating machine armature with high power.

  可以生产出热固性树脂组合物流出量较少的高导热性和耐热性电绝缘线圈，从而提供一种小型、轻质、高功率的旋转机械。 热固性树脂组合物包括 (a) 多官能环氧树脂，含有三个或三个以上对(2,3-环氧丙氧基)苯基和一个化学式 1 所代表的基团；或化学式 3、4 或 5 所代表的以萘为骨架的环氧树脂，或以蒽为骨架的环氧树脂，如蒽二醇二缩水甘油醚和蒽三醇三缩水甘油醚； (b) 含有两个对(2,3-环氧丙氧基)苯基的双官能环氧树脂； (c) 酸酐固化剂；以及 (d) 由化学式 2 表示的金属丙酮酸盐固化催化剂，以每 100 份环氧树脂的重量计， 其含量为 0.1 至 5 份。 根据本发明，可以生产出一种热固性树脂组合物流出量较少的高导热性和耐热性电绝缘线圈，以提供一种具有高功率的小型轻质旋转机器电枢。
• EPOXY RESIN COMPOSITIONS FOR FIBER-REINFORCED COMPOSITE MATERIALS, PROCESS FOR PRODUCTION OF THE MATERIALS AND FIBER-REINFORCED COMPOSITE MATERIALS
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1454936A1

  公开（公告）日：2004-09-08

  The present invention relates to an epoxy resin composition for fiber reinforced composite material comprising the following components (1) - (3) as essential components, their mixing ratios meeting the following conditions (I) - (IV), and component (3) being dissolved homogeneously: component (1): epoxy resin that is liquid at room temperature, component (2): aromatic polyamine that is liquid at room temperature, component (3): diaminodiphenylsulfone, condition (I): The proportion of component (1) relative to the entire epoxy resin in the composition is 60-100 wt%, condition (II): The sum of the proportions of components (2) and (3) relative to the entire polyamine in the composition is 70-100 wt%, condition (III): The proportion of component (3) relative to the entire polyamine in the composition is 25-60 wt%, and condition (IV): The stoichiometric ratio of the entire polyamine to the entire epoxy resin in the composition is 0.7-1.3. Another embodiment of the invention relates to an epoxy resin composition for fiber reinforced composite material that contains at least the following components (4) - (6), forms a cured product with a theoretical molecular weight between crosslinking points in the range of 250-350 g/mol, and has an initial viscosity at 80°C of 1-500 MPa·s: (4): aromatic epoxy resin with tri- or higher functionality, (5): aromatic epoxy resin with di- or higher and lower than tri-functionality, and (6): aromatic polyamine, the molecular weight between crosslinking points being defined as the weight of the entire cured epoxy resin divided by the number of crosslinking points contained in the entire cured epoxy resin. The invention also relates to an epoxy resin composition for fiber reinforced composite material that consists of the following components (7) and (8): (7) a polyglycidyl ether of phenol aralkyl resin as represented by the following formula: where R1, R2, R3 and R4 denote a hydrogen atom, an alkyl group having 1-8 carbon atoms, or a halogen atom, and m and n denote an integer of 1-4 and a real number of 0 or more and less than 1, respectively, and (8) polyamine. With the constitution described above, the present invention can provide a liquid epoxy resin composition for low cost production of high performance fiber reinforced composite material, that has a low viscosity at relatively low temperatures, and that after being cured, the cured product is high in glass transition temperature, elastic modulus and toughness while being small in the glass temperature decrease caused by water absorption and also small in the coefficient of linear expansion; and can provide a method to produce fiber reinforced composite material therefrom. Fiber reinforced composite material produced according to the present invention can serve as material for parts of aircraft, including main wing, tail, rotor blade, fairing, cowl, and door; parts of spacecraft, including motor case and main wing; and parts of space satellite body structure. They can also be used preferably as material for automobile chassis and railroad vehicle body structure.

  本发明涉及一种用于纤维增强复合材料的环氧树脂组合物，该组合物由以下组分 (1) - (3) 作为基本成分组成，它们的混合比例满足以下条件 (I) - (IV)，并且组分 (3) 被均匀溶解： 成分（1）：室温下为液态的环氧树脂、 组分（2）：室温下为液态的芳香族多胺、 组分（3）：二氨基二苯砜、 条件 (I)：组分（1）相对于整个环氧树脂的比例为 60-100%、 条件 (II)：组分(2)和(3)相对于组合物中整个多胺的比例之和为 70-100 wt%、 条件 (III)：组分（3）相对于组合物中整个多胺的比例为 25-60 wt%，以及 条件（IV）：组合物中整个多胺与整个环氧树脂的化学计量比为 0.7-1.3。 本发明的另一个实施方案涉及一种用于纤维增强复合材料的环氧树脂组合物，该组合物至少含有以下组分（4）-（6），形成的固化产物在交联点之间的理论分子量在 250-350 g/mol 范围内，且在 80°C 时的初始粘度为 1-500 MPa-s： (4) 具有三官能度或更高官能度的芳香族环氧树脂、 (5) 具有二官能度或更高但低于三官能度的芳香族环氧树脂，以及 (6) 芳香族多胺、 交联点之间的分子量定义为整个固化环氧树脂的重量除以整个固化环氧树脂所含交联点的数量。本发明还涉及一种用于纤维增强复合材料的环氧树脂组合物，该组合物由以下组分 （7）和（8）组成： (7) 由下式表示的苯酚芳基树脂聚缩水甘油醚： 其中 R1、R2、R3 和 R4 分别表示氢原子、具有 1-8 个碳原子的烷基或卤素原子，m 和 n 分别表示 1-4 的整数和 0 或大于等于 1 的实数；以及 (8) 多胺。 根据上述构成，本发明可以提供一种用于低成本生产高性能纤维增强复合材料的液态环氧树脂组合物，该组合物在相对较低的温度下具有较低的粘度，固化后的固化物具有较高的玻璃化转变温度、弹性模量和韧性，同时吸水引起的玻璃化温度降低较小，线膨胀系数也较小；本发明还可以提供一种用其生产纤维增强复合材料的方法。 根据本发明生产的纤维增强复合材料可用作飞机部件的材料，包括主翼、尾翼、旋翼、整流罩、整流罩和舱门；航天器部件，包括发动机壳体和主翼；以及太空卫星主体结构部件。它们还可优先用作汽车底盘和铁路车辆车身结构的材料。
• CURING AGENT COMPOSITION FOR EPOXY RESINS, EPOXY RESIN COMPOSITION AND USE THEREOF
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1440991A1

  公开（公告）日：2004-07-28

  An epoxy resin composition comprising an epoxy resin (A), a curing agent (B) and a curing accelerator (C), wherein the curing agent (B) is a phenol compound having two or more functional groups or a compound obtained by esterification of the phenol compound or a mixture of these compounds, and the curing accelerator (C) is a salt of a phosphazenium compound represented by a formula (I): (wherein R1s each represent a hydrogen atom, a linear, branched or cyclic alkyl group having 1 to 10 carbon atoms or an aryl or aralkyl group having 6 to 10 carbon atoms and may be all the same or different from one another; and Z- represents a halogen anion, hydroxy anion, alkoxy anion, aryloxy anion or carboxy anion).

  一种环氧树脂组合物，由环氧树脂(A)、固化剂(B)和固化促进剂(C)组成，其中固化剂(B)是具有两个或两个以上官能团的苯酚化合物或由苯酚化合物酯化得到的化合物或这些化合物的混合物，固化促进剂(C)是由式(I)表示的磷铵化合物的盐： (其中 R1s 分别代表氢原子、具有 1 至 10 个碳原子的直链、支链或环状烷基或具有 6 至 10 个碳原子的芳基或芳烷基，它们可以相同或不同；Z- 代表卤素阴离子、羟基阴离子、烷氧基阴离子、芳氧基阴离子或羧基阴离子）。
• ANTIREFLECTION FILM FOR SEMICONDUCTOR CONTAINING CONDENSATION TYPE POLYMER
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1757986A1

  公开（公告）日：2007-02-28

  There is provided an anti-reflective coating forming composition comprising a polymer having a pyrimidinetrione structure, imidazolidinedione structure, imidazolidinetrione structure or triazinetrione structure and a solvent. The anti-reflective coating obtained from the composition has a high preventive effect for reflected light, causes no intermixing with photoresists, and can use in lithography process by use of a light having a short wavelength such as ArF excimer laser beam (wavelength 193 nm) or F2 excimer laser beam (wavelength 157 nm), etc.

  本发明提供了一种抗反射涂层成型组合物，该组合物由具有嘧啶三酮结构、咪唑烷二酮结构、咪唑烷三酮结构或三嗪三酮结构的聚合物和溶剂组成。由该组合物制得的防反射涂层对反射光有很好的防止效果，不会与光刻胶混合，并可在光刻工艺中使用 ArF 准分子激光束（波长 193 nm）或 F2 准分子激光束（波长 157 nm）等短波长光。