丁基(三甲基)锗烷 | 1000-46-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 丁基(三甲基)锗烷
• 英文名称: Butyl-trimethyl-german
• 英文别名: Trimethyl-butylgerman；Butyltrimethylgerman；Butyl(trimethyl)germane
• CAS: 1000-46-0
• 化学式: C₇H₁₈Ge
• 分子量: 174.81
• InChiKey: GLHGUMFMUJLNRO-UHFFFAOYSA-N

物化性质

• 沸点：
  118 °C

计算性质

• 辛醇/水分配系数(LogP)：
  3.12
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-碘丁烷 、 四丁基氟化铵 、 trimethylgermanium,trimethylsilicon 在 水 作用下， 以 六甲基磷酰三胺 为溶剂， 生成 丁基(三甲基)锗烷
  参考文献：
  名称：

  Generation and reactions of metal-free trialkylgermyl anions from silylgermane and digermane

  摘要：

  Metal-free trimethylgermyl anions were prepared by cleavage of the Ge-Si bond of (trimethylsilyl)trimethylgermane and the Ge-Ge bond of hexamethyldigermane with tetrabutylammonium fluoride (TBAF) in hexamethylphosphoric triamide (HMPA). The reactions of metal-free germyl anions produced by a catalytic or one-equivalent amount of TBAF with organic halides carbonyl compounds, and alpha,beta-unsaturated ketones were examined.

  DOI：

  10.1016/0022-328x(95)00315-h

文献信息

• The first example of Ge-Ge and Sn-Sn bond cleavage by arylmagnesium halides
  作者：K. S. Nosov、A. V. Lalov、M. P. Egorov、O. M. Nefedov

  DOI：10.1007/bf01431147

  日期：1996.11
• Auf dem wege zu einem stabilen germaethen Ge = C<1: Sterisch überladene digermylsilylmethane tBu2SiXCY(GeMe3)2 und struktur der germaethenquelle tBu2SiFCLi(GeMe3)2 · 2THF
  作者：Nils Wiberg、Hae-Sook Hwang-Park、Patrizia Mikulcik、Gerhard Müller

  DOI：10.1016/0022-328x(95)05967-t

  日期：1996.4

  Sterically overloaded digermylsilylmethanes (t)Bu(2)SiX-CY(GeMe(3))(2) (X - H, Me, F, Br, Y = H, Br, Li) 7-16 are accessible via (t)Bu(2)SiH-CH(GeMe(3))(2) 7 (from (1)Bu(2)SiHF and LiCH(GeMe(3))(2)). The compounds are distinguished by hindered rotation about the SiC single bond shown, 7-16 enter into many reactions: (i) electrophilic substitution of Y = H by Li started with MeLi/TH, or of Y = Li by Br, EMe(3), R started with Br-2, Me(3)SnCl, Me(3)GeCl, Me(3)SiO(CH2)(4)Cl, or of X = H by Br started with Br-2; (ii) homophilic substitution of Y = Br by H started with (t)Bu(3)SiNa; (iii) nucleophilic substitution of X = F, Br by R started with MeLi, (II)BuLi. The latter reactions are possible only when Y = Li, and probably proceed over the silaethen t(B)u(2)Si=C(GeMe(3))(2) as reaction intermediate. (t)Bu(2)SiF-CLi(GeMe(3))2, a potential precursor of the hitherto unknown germaethene Me(2)Ge=C(GeMe(3))(SiMe(t)Bu(2)), forms an adduct Li(THF)(4)(+) [(t)Bu(2)SiFC(GeMe(3))(2)](-) in THF and an adduct (t)Bu(2)SiF-CLi(GeMe(3))(2) . 2THF after evaporation of THF. The structure of the latter compound shows a distorted tetrahedral geometry of the central Si and C atom with the Li atom being bonded to the latter. In addition, Li is coordinated by two molecules of THF in a slightly distorted trigonal-planar geometry. A short F...Li contact is not observed. (Crystals of (t)Bu(2)SiF-CLi(GeMe(3))(2) . 2THF are orthorhombic, space group Pca2(1), with a = 20.739(3), b = 16.185(5), c = 17.642(4) Angstrom, V = 5921.4 Angstrom(3), Z = 8, D-calc = 1.256 g cm(-3). R = 0.057 for 527 refined parameters and 4144 observed data.) (t)Bu(2)SiF-CLi(GeMe(3))(2) . TMEDA is supposed to have a similar structure. (t)Bu(2)SiH-CLi(GeMe(3))(2) . OP(NMe(2))(3) and (t)Bu(2)SiMe-CLi(GeMe(3))(2) . OEt(2) have different structures.
• Reaction of bis(trimethylsilyl)acetonitrile, (trimethylgermyl)(trimethylsilyl)acetonitrile, and bis(trimethylgermyl)acetonitrile anions with aldehydes
  作者：Sumie. Inoue、Yoshiro. Sato

  DOI：10.1021/om00137a023

  日期：1986.6.1
• INOUE, SUMIE;SATO, YOSHIRO, ORGANOMETALLICS, 1986, 5, N 6, 1197-1201
  作者：INOUE, SUMIE、SATO, YOSHIRO

  DOI：——

  日期：——
• Generation and reactions of metal-free trialkylgermyl anions from silylgermane and digermane
  作者：Kunio Mochida、Hiroyasu Suzuki、Michihiko Nanba、Tsuyoshi Kugita、Yasuo Yokoyama

  DOI：10.1016/0022-328x(95)00315-h

  日期：1995.9

  Metal-free trimethylgermyl anions were prepared by cleavage of the Ge-Si bond of (trimethylsilyl)trimethylgermane and the Ge-Ge bond of hexamethyldigermane with tetrabutylammonium fluoride (TBAF) in hexamethylphosphoric triamide (HMPA). The reactions of metal-free germyl anions produced by a catalytic or one-equivalent amount of TBAF with organic halides carbonyl compounds, and alpha,beta-unsaturated ketones were examined.