bis(n-butylxanthato)cadmium(II)

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(n-butylxanthato)cadmium(II)
• 英文别名: cadmium butylxanthate
• 化学式: 2C₅H₉OS₂*Cd
• 分子量: 410.926
• InChiKey: AISJSNGCIVXKEO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.63
• 重原子数：
  9.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  bis(n-butylxanthato)cadmium(II) 以 氨 为溶剂， 生成 cadmium(II) sulphide
  参考文献：
  名称：

  Synthesis of size tuneable cadmium sulphide nanoparticles from a single source precursor using ammonia as the solvent

  摘要：

  Size tuneable cadmium sulphide nanoparticles of a few nanometres in size were prepared by thermolysis of a single source precursor of cadmium xanthates with variable carbon chain length (Cd(ROCS(2))(2), where R denotes -C(2)H(5), -C(4)H(9), -C(8)H(17) and -C(12)H(25), respectively) in an ammonia solution. The particle size, morphology and crystallinity of these nanoparticles were characterized using X-ray powder diffractometry, transmission electron microscopy, and nitrogen adsorption/desorption techniques. The results show that hexagonal CdS nanoparticles can be produced by thermolysis of cadmium alkyl xanthate in an ammonia solution at a temperature as low as 100 degrees C. The size of CdS particles (between 5.60 nm and 3.71 nm) decreases with increasing length of carbon chain in the precursor, as further confirmed by UV-visible and fluorescence spectrophotometric measurements. The size tuning mechanism of CdS from cadmium alkyl xanthate is also discussed. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2011.08.062
• 作为产物：
  描述：

  丁基黄原酸钾 、 cadmium(II) chloride 以 水 为溶剂， 以87%的产率得到bis(n-butylxanthato)cadmium(II)
  参考文献：
  名称：

  用作镉和硫化锌薄膜前体的双（O-烷基黄原）Cd（II）和双（O-烷基黄原）Zn（II）配合物的合成，X射线单晶结构表征和热分析

  摘要：

  这项工作研究了一系列O-烷基黄原酸锌和镉前体配合物的分子结构的调节，以提高ZnS和CdS材料的产量。几个之二的结构（O-alkylxanthato）镉（II）配合物（8 - 13）和双（O-烷基xanthato）锌（II）复合物（18和19）是基于单晶X射线衍射数据的报道。通过旋涂这些金属配合物，然后将其热分解为相应的金属硫化物，可制得CdS和ZnS膜。通过旋涂双（O-烷基黄原）镉（II）前体来沉积CdS薄膜（7 – 13）在玻璃基板上，然后在300°C下退火60分钟。通过旋涂双（O-烷基黄原）锌（II）沉积ZnS薄膜（14 – 20），然后在200°C下退火60分钟。分子配合物和固态材料的表征使用了一系列技术，包括单晶X射线衍射，pXRD，EDS和XPS，DSC和TGA，UV-vis和PL光谱学以及电子显微镜。这些技术提供了有关烷基链长对制造金属硫化物薄膜所需的热条件以及薄膜性质（例如薄

  DOI：

  10.1021/acs.inorgchem.1c01110

文献信息

• Synthesis of size tuneable cadmium sulphide nanoparticles from a single source precursor using ammonia as the solvent
  作者：Wei-Min Zhang、Zhong-Xi Sun、Wei Hao、Da-Wei Su、David J. Vaughan

  DOI：10.1016/j.materresbull.2011.08.062

  日期：2011.12

  Size tuneable cadmium sulphide nanoparticles of a few nanometres in size were prepared by thermolysis of a single source precursor of cadmium xanthates with variable carbon chain length (Cd(ROCS(2))(2), where R denotes -C(2)H(5), -C(4)H(9), -C(8)H(17) and -C(12)H(25), respectively) in an ammonia solution. The particle size, morphology and crystallinity of these nanoparticles were characterized using X-ray powder diffractometry, transmission electron microscopy, and nitrogen adsorption/desorption techniques. The results show that hexagonal CdS nanoparticles can be produced by thermolysis of cadmium alkyl xanthate in an ammonia solution at a temperature as low as 100 degrees C. The size of CdS particles (between 5.60 nm and 3.71 nm) decreases with increasing length of carbon chain in the precursor, as further confirmed by UV-visible and fluorescence spectrophotometric measurements. The size tuning mechanism of CdS from cadmium alkyl xanthate is also discussed. (C) 2011 Elsevier Ltd. All rights reserved.
• Prisyazhnyuk, A. I.; Seifullina, I. I.; Martynenko, A. P., Ukrainskij Khimicheskij Zhurnal, <hi>1987</hi>, vol. 53/4, p. 4 - 8
  作者：Prisyazhnyuk, A. I.、Seifullina, I. I.、Martynenko, A. P.、Dzhambek, O. I.

  DOI：——

  日期：——
• Synthesis, X-ray Single-Crystal Structural Characterization, and Thermal Analysis of Bis(O-alkylxanthato)Cd(II) and Bis(O-alkylxanthato)Zn(II) Complexes Used as Precursors for Cadmium and Zinc Sulfide Thin Films
  作者：Ali A.K. Bakly、David Collison、Ruben Ahumada-Lazo、David J. Binks、Matthew Smith、James Raftery、George F. S. Whitehead、Paul O’Brien、David J. Lewis

  DOI：10.1021/acs.inorgchem.1c01110

  日期：2021.5.17

  O-alkylxanthato zinc and cadmium precursor complexes to enhance production of ZnS and CdS materials. The structures of several bis(O-alkylxanthato) cadmium(II) complexes (8–13) and bis(O-alkyl xanthato)zinc(II) complexes (18 and 19) are reported based on single crystal X-ray diffraction data. CdS and ZnS films were produced by the spin-coating of these metal complexes followed by their thermal decomposition

  这项工作研究了一系列O-烷基黄原酸锌和镉前体配合物的分子结构的调节，以提高ZnS和CdS材料的产量。几个之二的结构（O-alkylxanthato）镉（II）配合物（8 - 13）和双（O-烷基xanthato）锌（II）复合物（18和19）是基于单晶X射线衍射数据的报道。通过旋涂这些金属配合物，然后将其热分解为相应的金属硫化物，可制得CdS和ZnS膜。通过旋涂双（O-烷基黄原）镉（II）前体来沉积CdS薄膜（7 – 13）在玻璃基板上，然后在300°C下退火60分钟。通过旋涂双（O-烷基黄原）锌（II）沉积ZnS薄膜（14 – 20），然后在200°C下退火60分钟。分子配合物和固态材料的表征使用了一系列技术，包括单晶X射线衍射，pXRD，EDS和XPS，DSC和TGA，UV-vis和PL光谱学以及电子显微镜。这些技术提供了有关烷基链长对制造金属硫化物薄膜所需的热条件以及薄膜性质（例如薄