三氟-镍酸钾盐 | 13845-06-2

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱金属盐
• 中文名称: 三氟-镍酸钾盐
• 英文名称: potassium trifluoronickelate
• 英文别名: Nickel potassium fluoride；potassium;nickel(2+);trifluoride
• CAS: 13845-06-2
• 化学式: F₃Ni*K
• 分子量: 154.784
• InChiKey: GFHFDGDZKAYMPS-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -11.99
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  镍 在 KF 作用下， 以 氢氟酸 为溶剂， 以63%的产率得到三氟-镍酸钾盐
  参考文献：
  名称：

  Electrosynthesis of transition metal fluoro complexes by the dissolution of a sacrificial metal anode

  摘要：

  A general method for the electrosynthesis of anionic fluoro complexes of transition metals has been developed by the oxidation of sacrificial metal anodes in 20% HF medium at room temperature and at an applied potential of 2-8 V. Some mixed-valent complexes, e.g. Fe2F5.2H2O and Fe2F5.7H2O, have also been obtained by the same method. K2[MnF5].H2O was obtained by subsequent electrolytic oxidation of the Mn(II) fluoro complex obtained in situ in the first step. The method is rapid and gives a good yield with high purity.

  DOI：

  10.1016/s0277-5387(00)81335-2

文献信息

• Hydrothermal crystal growth of perovskite-type fluorides
  作者：Shigeyuki S¯omiya、Shin -Ichi Hirano、Masahiro Yoshimura、Kazumichi Yanagisawa

  DOI：10.1007/bf02402800

  日期：1981.3
• Chakravorti; Subrahmanyam; Bandyopadhyay, Journal of the Indian Chemical Society, 1990, vol. 67, # 10, p. 835 - 836
  作者：Chakravorti、Subrahmanyam、Bandyopadhyay

  DOI：——

  日期：——
• Babel, D.; Herdtweck, E., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Babel, D.、Herdtweck, E.

  DOI：——

  日期：——
• Electrosynthesis of transition metal fluoro complexes by the dissolution of a sacrificial metal anode
  作者：M.C. Chakravorti、Gampa.V.B. Subrahmanyam、D. Bandyopadhyay

  DOI：10.1016/s0277-5387(00)81335-2

  日期：1991.1

  A general method for the electrosynthesis of anionic fluoro complexes of transition metals has been developed by the oxidation of sacrificial metal anodes in 20% HF medium at room temperature and at an applied potential of 2-8 V. Some mixed-valent complexes, e.g. Fe2F5.2H2O and Fe2F5.7H2O, have also been obtained by the same method. K2[MnF5].H2O was obtained by subsequent electrolytic oxidation of the Mn(II) fluoro complex obtained in situ in the first step. The method is rapid and gives a good yield with high purity.