三水合高氯酸汞 | 73491-34-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 中文名称: 三水合高氯酸汞
• 中文别名: 高氯酸汞(II)三水合物；高氯酸汞水合物
• 英文名称: Mercury(II) perchlorate trihydrate
• 英文别名: mercury(2+);diperchlorate;trihydrate
• CAS: 73491-34-6
• 化学式: Cl2H6HgO11
• 分子量: 453.54
• InChiKey: DFJWPGPUWHLJIJ-UHFFFAOYSA-L

物化性质

• 密度：
  4 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  -11.99
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  152
• 氢给体数：
  3
• 氢受体数：
  11

安全信息

• TSCA：
  Yes
• 危险等级：
  5.1
• 危险品标志：
  N,T+
• 安全说明：
  S17,S26,S27,S36/37/39,S45
• 危险类别码：
  R8,R33,R36/37/38

SDS

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Section 1: Product Identification
Chemical Name: Mercury (II) perchlorate trihydrate, 99+%
CAS Registry Number: 73491-34-6
Formula: Hg(ClO4)2.3H2O
EINECS Number: none
Chemical Family: metal perchlorate salt
Synonym: Perchloric acid, Mercury(II) salt, trihydrate.

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 73491-34-6 100% 0.025mg/m3 1mg/10m3

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Section 3: Hazards Identification
Emergency Overview: Causes irritation to the eyes, skin and respiratory tract. May affect thyroid and kidney functions.
Primary Routes of Exposure: Ingestion
Eye Contact: Causes irritation of the eyes.
Skin Contact: Causes irritation of the skin. Harmful in contact with skin.
Inhalation: Effects include severe respiratory and gastrointestinal distress and damage the central nervous system.
Toxic if swallowed. Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness
Ingestion:
and convulsions.
Acute Health Affects: Poison. Severe immediate toxicity of the gastrointestinal tract that can be fatal
The chronic effects of mercury poisoning include stomatitis, tremors, physic disturbances, excessive
Chronic Health Affects: salivation, pain on chewing, loss of memory, irritability and depression. Perchlorates reversibly inhibit thyroid
iodine uptake. Kidney function affected.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: Water spray
Spray closed containers with water until fire is out. Avoid contact with combustible material. Fire fighters
Special Fire Fighting Procedures:
should be equipped with a NIOSH approved self-contained breathing apparatus.
Hazardous Combustion and If involved in a fire this material may emit corrosive hydrogen chloride fumes and toxic mercury vapors.
Decomposion Products:
Releases oxygen on heating. May decompose explosively under fire fighting conditions. Do not mix with
Unusual Fire or Explosion Hazards:
combustibles.

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SECTION 6: Accidental Release Measures
Do not mix spilled powder with any combustible materials, such as sawdust. Sweep up the solid and dilute
Spill and Leak Procedures:
with water.

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SECTION 7: Handling and Storage
Store in a tightly sealed container in a cool dry place away from combustible and flammable materials. If the
Handling and Storage:
container is left open, salt may adsorb moisture from the atmosphere

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: white xtl.
Molecular Weight: 399.46 (453.51)
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: ~4
Odor: none
Solubility in Water: soluble

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SECTION 10: Stability and Reactivity
Stability: Hygroscopic
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: Any contact with combustible matter.
Incompatibility: Reducing agents, organic matter, active metals, phosphorus, sulfur, hydrazine, hydroxylamine, strong acids
Decomposition Products: Oxygen, mercury oxide, hydrogen chloride,

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SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available

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SECTION 12: Ecological Information
Avoid release to the environment. Very toxic to aquatic organisms. May cause long-term adverse effects in the
Ecological Information:
aquatic environment.

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Oxidizing solid, Toxic, N.O.S.
Hazard Class (CFR): 5.1
Additional Hazard Class (CFR): 6.1
Packaging Group (CFR): II
UN ID Number (CFR): UN# 3087
Shipping Name (IATA): Oxidizing Solid, Toxic, N.O.S.
Hazard Class (IATA): 5.1
Additional Hazard Class (IATA): 6.1
Packaging Group (IATA): II
UN ID Number (IATA): UN# 3087

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SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound: See Category Code N458.
Second Ingredient: none

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为试剂：
  描述：

  、 calcium carbonate 、 乙醚 、 四氢呋喃 在 三水合高氯酸汞 、 汞 magnesium sulfate 作用下， 以 水 为溶剂， 反应 1.08h， 生成 6,8-二氧杂二环[3.2.1]辛烷-3-酮,(1R)-
  参考文献：
  名称：

  Arylbicyclooctanes as inhibitors of leukotriene biosynthesis

  摘要：

  公式为I：##STR1##的化合物是白三烯生物合成的抑制剂。这些化合物可用作抗哮喘、抗过敏、抗炎和细胞保护剂。它们还可用于治疗心绞痛、脑血管痉挛、肾小球肾炎、肝炎、内毒素血症、葡萄膜炎和移植排斥，并防止动脉粥样硬化斑块的形成。

  公开号：

  US05459271A1