Chromium;cobalt;iron;molybdenum;nickel

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Chromium;cobalt;iron;molybdenum;nickel
• 英文别名: chromium;cobalt;iron;molybdenum;nickel
• 化学式: Co₀Cr₀Fe₀Mo₀Ni₀
• 分子量: 222.934
• InChiKey: IUXLMVJVLRVTOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  铬 、 钴 、 铁粉 、 镍 、 钼 以 melt 为溶剂， 生成 Chromium;cobalt;iron;molybdenum;nickel
  参考文献：
  名称：

  Precipitation phase and twins strengthening behaviors of as-cast non-equiatomic CoCrFeNiMo high entropy alloys

  摘要：

  DOI：

  10.1016/j.jallcom.2022.165584

文献信息

• Effect of Mo and aging temperature on corrosion behavior of (CoCrFeNi)100-Mo high-entropy alloys
  作者：Wenrui Wang、Jieqian Wang、Zhihui Sun、Jiangtao Li、Laifeng Li、Xin Song、Xiaodong Wen、Lu Xie、Xiao Yang

  DOI：10.1016/j.jallcom.2019.152139

  日期：2020.1

  spectroscopy in 3.5% NaCl solution indicate that the corrosion resistance of the alloys gradually increases with increasing aging temperature and Mo content. However, the corrosion resistance of (CoCrFeNi)97Mo3 alloy aged at 900 °C decreased suddenly. XPS analysis reveals that the main components of the passive film are Cr2O3 and MoO3, and the intensity of Cr2O3 and MoO3 in the passive film tends to increase

  摘要 本工作研究了Mo添加剂和时效温度对3.5% NaCl溶液中显微组织和腐蚀行为的影响。(CoCrFeNi)100-xMox(x = 1, 2, 3) 合金在 700 °C 和 900 °C 时效时的微观结构包括单一 FCC 固溶体结构。当Mo含量从1%增加到2%时，在3.5% NaCl溶液中的极化曲线和电化学阻抗谱表明，合金的耐腐蚀性能随着时效温度和Mo含量的增加而逐渐增加。然而，(CoCrFeNi)97Mo3 合金在 900 °C 时效时的耐蚀性突然下降。XPS分析表明钝化膜的主要成分是Cr2O3和MoO3，钝化膜中 和MoO3的强度随着Mo从1%增加到2%有增加的趋势，可以提高钝化膜的稳定性。第一性原理计算用于理解Cl-对钝化膜点蚀机制的影响。
• Formation of ordered/disordered nanoparticles in FCC high entropy alloys
  作者：Tao-Tsung Shun、Cheng-Hsin Hung、Che-Fu Lee

  DOI：10.1016/j.jallcom.2009.12.071

  日期：2010.3

  This study comprises the microstructure characterization of four as-cast CoCrFeNiAl(0.3), CoCrFeNiTi(0.3), CoCrFeNiMo(0.3) and CoCrFeNiAl(0.3)Mo(0.1) FCC high entropy alloys. Massive nanoparticles are observed in the CoCrFeNiAl(0.3), CoCrFeNiTi(0.3) and CoCrFeNiAl(0.3)Mo(0.1) alloys, whereas no nanoparticle is found in the CoCrFeNiMo(0.3) alloy. These nanoparticles are multi-elemental solid solutions instead of inter-metallic compounds, and the crystal structure possesses both the ordered L1(2) and the disordered FCC structures. It is suggested that the formation of nanoparticles is dominated by the effects of the high mixing entropy, the sluggish cooperative diffusion of atoms, and the relatively negative mixing enthalpies of the atomic pairs between Al (or Ti) and other compositional elements. Furthermore, the formation of L1(2) ordered nanoparticles should fulfill the criteria of alloy composition having both more than 25 at.% of Ni (Ni could be partially substituted by Co) and at least 6.25 at.% of Al or Ti. (C) 2009 Elsevier B.V. All rights reserved.