镉,加合(1:1)银 | 12002-62-9

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 中文名称: 镉,加合(1:1)银
• 英文名称: silver-cadmium
• 英文别名: cadmium;silver
• CAS: 12002-62-9
• 化学式: AgCd
• 分子量: 220.278
• InChiKey: NSAODVHAXBZWGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  银 、 镉 以 neat (no solvent) 为溶剂， 生成 镉,加合(1:1)银
  参考文献：
  名称：

  The thermochemical behavior of some binary shape memory alloys by high temperature direct synthesis calorimetry

  摘要：

  The standard enthalpies of formation of some shape memory alloys have been measured by high temperature direct synthesis calorimetry at 1373 K. The following results (in kJ/mol of atoms) are reported: CoCr (-0.3 +/- 2.9); CuMn (-3.7 +/- 3.2); Cu3Sn (-10.4 +/- 3.1); Fe2Tb (-5.5 +/- 2.4); Fe2Dy (-1.6 +/- 2.9); Fe17Tb2 (-2.1 +/- 3.1); Fe17Dy2 (-5.3 +/- 1.7); FePd3 (-16.0 +/- 2.7); FePt (-23.0 +/- 1.9); FePt3 (-20.7 +/- 2.3); NiMn (-24.9 +/- 2.6); TiNi (-32.7 +/- 1.0); TiPd (-60.3 +/- 2.5). The results are compared with some earlier experimental values obtained by calorimetry and by EMF technique. They are also compared with predicted values on the basis of the semi empirical model of Miedema and co-workers and with ab initio calculations when available. We will also assess the available information regarding the structures of these alloys. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2011.01.152

文献信息

• Absorption spectrum of the trimer silver cluster <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si2.gif" display="inline" overflow="scroll"><mml:mrow><mml:msubsup><mml:mrow><mml:mi mathvariant="normal">Ag</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> and metal nanoparticles in microemulsion
  作者：Sudhir Kapoor、Ravi Joshi、Tulsi Mukherjee

  DOI：10.1016/j.cplett.2004.08.080

  日期：2004.10

  Classical quantum simulation suggests the formation of Ag-3(2+) [Chem. Phys. Lett. 389 (2004) 150]. We present the effect of water pool radii on the transient absorption spectra of initial silver clusters. Experimental evidence for the formation of Ag-3(2+) in micro-emulsion system is reported for the first time. The surface plasmon absorption band of stable silver clusters obtained by bombardment of electron pulses in water-in-oil microemulsions showed absorption maximum at 405 nm. The transmission electron micrograph studies showed the presence of silver nanoparticles having an average size of 10 nm. (C) 2004 Elsevier B.V. All rights reserved.