ferrous dodecyl sulfate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 英文名称: ferrous dodecyl sulfate
• 英文别名: Dodecyl sulfate;iron(2+)
• 化学式: 2C₁₂H₂₅O₄S*Fe
• 分子量: 586.635
• InChiKey: SZDJTAYLPADNLJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.38
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ferrous dodecyl sulfate 在 二甲胺 作用下， 以 水 为溶剂， 生成 iron oxide
  参考文献：
  名称：

  Mesoscopic Structures of Nanocrystals:  Collective Magnetic Properties Due to the Alignment of Nanocrystals

  摘要：

  Maghemite nanocrystals, deposited by slow evaporation on HOPG (highly oriented pyrolytic graphite) substrate, form mesoscopic structures which strongly depend on the nanocrystal coating. When the coating consists of citrate ions and octanoic acid, tubelike structures are formed when the deposition process takes place under an applied magnetic field. Conversely, dense films are formed when the nanocrystals are coated with propanoic acid and dodecanoic acid. The magnetic behaviors markedly differ with the organization of nanocrystals and are attributed to the change in the anisotropy of the organized structures. Nanocrystals organized in tubes behave as nanowires.

  DOI：

  10.1021/jp035665c
• 作为产物：
  描述：

  sodium dodecyl-sulfate 、 iron(II) chloride 以 水 为溶剂， 生成 ferrous dodecyl sulfate
  参考文献：
  名称：

  Control of the Size of Cobalt Ferrite Magnetic Fluid

  摘要：

  Cobalt and iron(II) dodecyl sulfate, Co(DS)(2) and Fe(DS)(2), are used to make nanosize magnetic particles. The size of the particles is controlled by the surfactant concentration. The average size of the particles, determined by transmission electron microscopy and from simulation of Langevin curves, varies from 2 to 5 nm, with 30-35% polydispersity in the size distribution. The magnetic studies are performed on particles having 2, 3, and 5 nm diameter, respectively. These particles are characterized by a superparamagnetic behavior. The saturation magnetization decreases with the particle size and is explained in terms of an increase in the noncollinear structure at the interface. For 5 nm particles, a cubic magnetocrystalline anisotropy is observed. On decreasing the size of the particles, the surface anisotropy strongly increases.

  DOI：

  10.1021/jp9524136

文献信息

• Synthesis of a Bolm's 2,2′-Bipyridine Ligand Analogue and Its Applications
  作者：Eva Bednářová、Martin Dračínský、Štefan Malatinec、Ivana Císařová、Frédéric Lamaty、Martin Kotora

  DOI：10.1002/adsc.201800452

  日期：2018.8.6

  The newly prepared bipyridine (S,S)‐2 was then tested as a chiral ligand in metal‐catalyzed enantioselective reactions. Out of the studied reactions the most promising results were obtained in epoxide ring opening (82% yield, 98% ee) and Mukaiyama aldol reaction (>96% yield, 99/1 dr, 92% ee). In the case of Mukaiyama‐aldol reaction as well as in the Michael addition, novel ligand 2 proved its robustness

  开发了一种新的伯尔姆2,2'-联吡啶配体类似物的合成方法，该方法基于1-卤代炔与腈的催化[2 + 2 + 2]环三聚。整个合成过程的关键步骤是将取代的2-溴吡啶与相应的联吡啶进行均二聚，对此进行了研究和优化。然后将新制备的联吡啶（S，S）-2作为手性配体在金属催化的对映选择性反应中进行测试。在所研究的反应中，最有希望的结果是在环氧化物开环（82％收率，98％ee）和Mukaiyama aldol反应（> 96％收率，99/1 dr，92％ee）中获得的。在Mukaiyama-aldol反应以及迈克尔加成反应中，新的配体2 证明了与Bolm配体相比它的耐用性，因为它对用过的试剂的纯度较不敏感。
• Palladium-Loaded Cucurbit[7]uril-Modified Iron Oxide Nanoparticles for C−C Cross-Coupling Reactions
  作者：Farah Benyettou、Laurence Motte、Hassan Traboulsi、Javed Mazher、Renu Pasricha、John-Carl Olsen、Ali Trabolsi、Erwan Guenin

  DOI：10.1002/chem.201705082

  日期：2018.2.16

  Cucurbit[7]uril modified iron oxide nanoparticles (CB[7]NPs) were loaded with palladium to form nano‐catalysts (Pd@CB[7]NPs) that, with microwave heating, catalysed Suzuki–Miyaura, Sonogashira, and Mizoroki–Heck cross‐coupling reactions. Reactions were run in environmentally benign 1:1 ethanol/water solvent under convenient aerobic conditions. In a preliminary screening, conversions and yields were

  将Cucurbit [7]尿素修饰的氧化铁纳米颗粒（CB [7] NPs）与钯混合形成纳米催化剂（Pd @ CB [7] NPs），并通过微波加热催化Suzuki–Miyaura，Sonogashira和Mizoroki–颈交叉耦合反应。反应在方便的有氧条件下于环境友好的1：1乙醇/水溶剂中进行。在初步筛选中，转化率和产率始终很高，周转频率（TOF）为64至7360 h -1。可以用磁铁回收纳米催化剂，并重复使用几次（Suzuki–Miayura反应重复6次），而不会损失活性。
• Magnetic nano-organocatalysts: impact of surface functionalization on catalytic activity
  作者：E. Nehlig、L. Motte、E. Guénin

  DOI：10.1039/c5ra20644h

  日期：——

  Nano-organocatalysts were synthesized using controlled click chemistry and studied in aldolization and Michael addition reactions. It was shown that small modifications of the nanosurface can have a drastic effect on the catalysis.

  使用控制的点击化学方法合成了纳米有机催化剂，并在醛缩和Michael加成反应中进行了研究。结果表明，纳米表面的微小修饰可以对催化产生巨大影响。
• Control of the Size of Cobalt Ferrite Magnetic Fluid
  作者：N. Moumen、M. P. Pileni

  DOI：10.1021/jp9524136

  日期：1996.1.1

  Cobalt and iron(II) dodecyl sulfate, Co(DS)(2) and Fe(DS)(2), are used to make nanosize magnetic particles. The size of the particles is controlled by the surfactant concentration. The average size of the particles, determined by transmission electron microscopy and from simulation of Langevin curves, varies from 2 to 5 nm, with 30-35% polydispersity in the size distribution. The magnetic studies are performed on particles having 2, 3, and 5 nm diameter, respectively. These particles are characterized by a superparamagnetic behavior. The saturation magnetization decreases with the particle size and is explained in terms of an increase in the noncollinear structure at the interface. For 5 nm particles, a cubic magnetocrystalline anisotropy is observed. On decreasing the size of the particles, the surface anisotropy strongly increases.
• SSG or SFM state in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si0009.gif" overflow="scroll"><mml:msub><mml:mrow><mml:mi>CoFe</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub></mml:math> nano-agglomerates fabricated by micro-emulsion method
  作者：Jana Poltierová Vejpravová、Václav Tyrpekl、Stanislav Daniš、Daniel Nižňanský、Vladimír Sechovský

  DOI：10.1016/j.jmmm.2009.12.044

  日期：2010.7

  We report on magnetic properties of CoFe2O4 nano-agglomerates obtained by micro-emulsion technique under specific conditions. The samples form a unique morphology as observed by transmission electron microscopy and scanning electron microscopy investigations. Concerning magnetic properties, they exhibit a considerable coercivity of almost 1T at 2K, which continuously decreases up to the characteristic temperature, T-g = 350 K. The temperature dependence of the zero-field cooled (ZFC) and field cooled (FC) magnetization, respectively, is furcated at the T-g, and the temperature dependencies of the a.c. susceptibility exhibit a frequency-dependent maximum at similar to T-g. The observed behavior is discussed in terms of the super-spin-glass (SSG) and the super-ferromagnetic (SFM) regime considering the morphology of the nano-agglomerates. (C) 2010 Elsevier B.V. All rights reserved.