4-cyanophenyl 4'-[4''-(pentyl)benzoyloxy]benzoate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-cyanophenyl 4'-[4''-(pentyl)benzoyloxy]benzoate
• 英文别名: 4-cyanophenyl 4-(4-pentylbenzoyloxy)-benzoate；[4-(4-Cyanophenoxy)carbonylphenyl] 4-pentylbenzoate
• 化学式: C₂₆H₂₃NO₄
• 分子量: 413.473
• InChiKey: GSYXNIFGHGWZCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  31
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  76.4
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  对羟基苯甲酸苄酯 在 吡啶 、 草酰氯 、 palladium 10% on activated carbon 、 氢气 、 N,N-二甲基甲酰胺 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 6.0h， 生成 4-cyanophenyl 4'-[4''-(pentyl)benzoyloxy]benzoate
  参考文献：
  名称：

  Synthesis of Fluorosubstituted Three Ring Esters and Their Dielectric Properties

  摘要：

  Laterally substituted by fluorine atoms 4-cyanophenyl 4-(4-pentylbenzoyloxy)-benzoates have been prepared and their phase transition temperatures, enthalpies and dielectric properties upon frequency were evaluated. The novel compounds exhibit a broad range of nematic mesophase, large positive dielectric anisotropy changing sign at low frequency. They are convenient components of LC mixtures for dual frequency addressing devices.

  DOI：

  10.1080/15421400902817361

文献信息

• Chemoselective Hydrolysis of Ester Bonds in the Presence of Baker's Yeast
  作者：Ewa Białecka-Florjańczyk、Ewa Majewska

  DOI：10.1080/00397910903068196

  日期：2010.4.12

  The catalytic effect of baker's yeast on the hydrolysis of aliphatic esters in p-acetoxybenzoates is described. The chemoselective character of this reaction enables the selective protection of the hydroxyl group in p-hydroxybenzoic acid derivatives.
• Liquid crystal composition, liquid crystal element, reflective display material, and light-controlling material
  申请人：Takaku Koji

  公开号：US20070278449A1

  公开（公告）日：2007-12-06

  The present invention provides a dual frequency addressable smectic A liquid crystal composition having a crossover frequency, wherein the smectic A phase is induced by mixing of at least a first nematic liquid crystal compound or composition and a second nematic liquid crystal compound or composition.
• US7713437B2
  申请人：——

  公开号：US7713437B2

  公开（公告）日：2010-05-11
• Synthesis of Fluorosubstituted Three Ring Esters and Their Dielectric Properties
  作者：Dorota Ziobro、Jerzy Dziaduszek、Marek Filipowicz、Roman Dąbrowski、Joanna Czub、Stanisław Urban

  DOI：10.1080/15421400902817361

  日期：2009.5.29

  Laterally substituted by fluorine atoms 4-cyanophenyl 4-(4-pentylbenzoyloxy)-benzoates have been prepared and their phase transition temperatures, enthalpies and dielectric properties upon frequency were evaluated. The novel compounds exhibit a broad range of nematic mesophase, large positive dielectric anisotropy changing sign at low frequency. They are convenient components of LC mixtures for dual frequency addressing devices.