1,3-dimethyl-3-(t-butylperoxy) butyl chloroformate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: 1,3-dimethyl-3-(t-butylperoxy) butyl chloroformate
• 英文别名: 1,3-dimethyl-3-(t-butylperoxy)butyl chloroformate；(4-tert-butylperoxy-4-methylpentan-2-yl) carbonochloridate
• 化学式: C₁₁H₂₁ClO₄
• 分子量: 252.738
• InChiKey: VSRWNXSMMZZTLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-dimethyl-3-(t-butylperoxy) butyl chloroformate 在 二甲胺 作用下， 以 乙醚 为溶剂， 生成 1,3-Dimethyl-3-(t-butylperoxy)butyl N,N-dimethylcarbamate
  参考文献：
  名称：

  Peroxy compounds

  摘要：

  一种新型化合物类别，其化学式为##STR1##其中Z是取代碳酸酯或氨基甲酸酯，D是炔基或烷基，R可能是烷基。

  公开号：

  US04177204A1

文献信息

• Coupled peroxides
  申请人：Pennwalt Corporation

  公开号：US03965145A1

  公开（公告）日：1976-06-22

  A new class of compounds: R--W--R' were R and R' are identical oxy radicals containing peroxide functions such as dialkyl or diaralkyl peroxide, peroxyketal, peroxyester, or monoperoxycarbonate, and W is a carbonyl group, or carbonyl containing group, or an alkylidene or aralkylidene group, or a phosphorus containing group. Examples Di[1,3-dimethyl-3-(t-butylperoxy)butyl]carbonate; Di[1,3-dimethyl-3-(n-butoxycarbonylperoxy)butyl]carbonate; 2,2-Bis[3,3-di(t-butylperoxy)butoxy]propane; Di[1,3-dimethyl-3-(t-butylperoxy)butyl]ethyl phosphate. They are free radical affording compounds useful in crosslinking of polyolefins and unsaturated polymers, and for the polymerization of vinyl monomers and diolefinic monomers.

  一种新的化合物类别：R-W-R'，其中R和R'是相同的含过氧化物功能的氧自由基，例如二烷基或二芳基过氧化物，过氧乙酰甲酸酯，或单过氧碳酸酯，而W是一个羰基基团，或含羰基基团的基团，或一个烷基亚甲基或芳基亚甲基基团，或一个含磷基团。例如：Di[1,3-二甲基-3-(叔丁基过氧)丁基]碳酸酯；Di[1,3-二甲基-3-(正丁氧羰基过氧)丁基]碳酸酯；2,2-双[3,3-二(叔丁基过氧)丁氧基]丙烷；Di[1,3-二甲基-3-(叔丁基过氧)丁基]乙基磷酸酯。它们是自由基供体化合物，在聚烯烃和不饱和聚合物的交联以及乙烯单体和二烯单体的聚合中有用。
• Process for curing polymers using amino or hydrazino peroxides
  申请人：Elf Atochem North America, Inc.

  公开号：US05399630A1

  公开（公告）日：1995-03-21

  This invention relates to novel reactive amino or hydrazino peroxides (hereinafter generally referred to as "AHP's") and derivatives all having a Structure A: ##STR1## in which the definitions of P, R11, R22, X, Q and x, y and z are given in the Summary Of The Invention section, for example, 4,4-di-(t-butylperoxy)pentanohydrazide (I-1), and the use of these novel compounds in curing unsaturated polyester resins, in initiating polymerization of ethylenically unsaturated monomers, for modifying rheology, for crosslinking and curing olefin polymers and elastomers, for producing novel graft and block copolymers, and for producing novel polymers with covalently bound performance additive functions.

  本发明涉及一种新型的反应性氨基或叠氮过氧化物（以下简称“AHP”）及其衍生物，全部具有结构A：##STR1## 其中P、R11、R22、X、Q以及x、y和z的定义在发明摘要部分中给出，例如4,4-二（叔丁基过氧）戊二酰肼（I-1），以及这些新化合物在固化不饱和聚酯树脂、引发乙烯基不饱和单体的聚合、改性流变学、交联和固化烯烃聚合物和弹性体、生产新型接枝和嵌段共聚物以及生产具有共价结合的性能添加剂功能的新型聚合物中的应用。
• Amino or hydrazino peroxides, derivatives and their uses
  申请人：Atochem North America, Inc.

  公开号：US04956416A1

  公开（公告）日：1990-09-11

  This invention relates to novel reactive amino or hydrazino peroxides (hereinafter generally referred to as "AHP's") and derivatives all having a Structure A: (P--R11--X--(--NH--).sub.x --R22--).sub.y --Q].sub.z A in which the definitions of P, R11, R22, X, Q and x, y and z are given in the Summary of The Invention section, for example, 4,4-di-(t-butylperoxy)pentanohydrazide (I-1), and the use of these novel compounds in curing unsaturated polyester resins, in initiating polymerization of ethylenically unsaturated monomers, for modifying rheology, for crosslinking and curing olefin polymers and elastomers, for producing novel graft and block copolymers, and for producing novel polymers with covalently bound performance additive functions.

  本发明涉及新型反应性氨基或肼基过氧化物（以下统称“AHP”）及其衍生物，均具有结构A：（P-R11-X-（-NH-）.sub.x-R22-）.sub.y-Q].sub.z，其中P、R11、R22、X、Q和x、y和z的定义在发明摘要部分中给出，例如4,4-二（叔丁基过氧化）戊二酰肼（I-1），以及在固化不饱和聚酯树脂、引发乙烯基不饱和单体聚合、改性流变学、交联和固化烯烃聚合物和弹性体、生产新型接枝和嵌段共聚物以及生产具有共价结合性能添加剂功能的新型聚合物中使用这些新化合物的方法。
• Peroxy compounds and vulcanizable compositions thereof
  申请人：Pennwalt Corporation

  公开号：US04218548A1

  公开（公告）日：1980-08-19

  A novel class of compounds having the formula ##STR1## where Z is a substituted carbonate or carbamate, D is alkynyl or an alkyl, and the R's may be alkyl.

  一种新型的化合物类，其化学式为##STR1## 其中Z为取代的碳酸酯或氨基甲酸酯，D为炔基或烷基，R可以是烷基。
• Use of amino or hydrazino peroxides in preparing and curing polymers
  申请人：Elf Atochem North America, Inc.

  公开号：US05457162A1

  公开（公告）日：1995-10-10

  This invention relates to novel reactive amino or hydrazino peroxides (hereinafter generally referred to as "AHP's") and derivatives all having a Structure A: ##STR1## in which the definitions of P, R11, R22, X, Q and x, y and z are given in the Summary Of The Invention section, for example, 4,4-di-(t-butylperoxy)pentanohydrazide (I-1), and the use of these novel compounds in curing unsaturated polyester resins, in initiating polymerization of ethylenically unsaturated monomers, for modifying rheology, for crosslinking and curing olefin polymers and elastomers, for producing novel graft and block copolymers, and for producing novel polymers with covalently bound performance additive functions.

  本发明涉及一种新型反应性氨基或双肼过氧化物（以下统称为“AHP”）及其衍生物，均具有结构A：##STR1## 其中P、R11、R22、X、Q和x、y和z的定义在发明摘要部分中给出，例如4,4-二（叔丁基过氧）戊二肼（I-1），以及这些新化合物在固化不饱和聚酯树脂、引发乙烯基不饱和单体的聚合、改性流变学、交联和固化烯烃聚合物和弹性体、生产新型嫁接和嵌段共聚物以及生产具有共价结合性能添加剂功能的新型聚合物中的应用。