二(萘-2-基)二乙基亚磷酰胺 | 64919-04-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 二(萘-2-基)二乙基亚磷酰胺
• 英文名称: N-dinaphthalen-2-yloxyphosphanyl-N-ethylethanamine
• CAS: 64919-04-6
• 化学式: C₂₄H₂₄NO₂P
• 分子量: 389.434
• InChiKey: BUVBSDKSQJNKHV-UHFFFAOYSA-N

物化性质

• 沸点：
  519.3±33.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  二(萘-2-基)二乙基亚磷酰胺 在 sulfur 作用下， 以 乙腈 为溶剂， 反应 40.0h， 生成 Diethyl-thiophosphoramidic acid O,O'-dinaphthalen-2-yl ester
  参考文献：
  名称：

  Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use

  摘要：

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.

  DOI：

  10.1134/s1070363206020046
• 作为产物：
  描述：

  N-[diethylamino(naphthalen-2-yloxy)phosphanyl]-N-ethylethanamine 以 1,4-二氧六环 为溶剂， 反应 480.0h， 生成 六乙基亚磷酸胺 、 二(萘-2-基)二乙基亚磷酰胺
  参考文献：
  名称：

  Dismutation of Diamidoarylphosphites

  摘要：

  Some examples of spontaneous dismutation of diamidoarylphosphites in different solvents were studied, and features of the process were revealed.

  DOI：

  10.1080/714040960

文献信息

• Dismutation of Diamidoarylphosphites
  作者：Edward E. Nifantyev、Elena N. Rasadkina、Pavel V. Slitikov、Larisa K. Vasyanina

  DOI：10.1080/714040960

  日期：2003.11.1

  Some examples of spontaneous dismutation of diamidoarylphosphites in different solvents were studied, and features of the process were revealed.
• US7253298B2
  申请人：——

  公开号：US7253298B2

  公开（公告）日：2007-08-07
• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.