2,4,6-tricyclohexyl-1,3,5-triazine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2,4,6-tricyclohexyl-1,3,5-triazine
• 化学式: C₂₁H₃₃N₃
• 分子量: 327.513
• InChiKey: TZGFZOQDCZOHEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,3,5-三嗪 、 环己烷 在 [双(三氟乙酰氧基)碘]苯 、 N-甲基对甲苯磺酰胺 作用下， 以 二氯甲烷 为溶剂， 反应 36.0h， 以90%的产率得到2,4,6-tricyclohexyl-1,3,5-triazine
  参考文献：
  名称：

  Metal-Free Radical-Mediated C(sp³)–H Heteroarylation of Alkanes

  摘要：

  Herein we disclose a metal-free, N/O-centered radical-promoted Minisci reaction, in which the coupling of various heteroarenes with simple alkanes proceeds under mild conditions. The reaction conditions are neutral; no extra acid is added to preactivate N-heteroarenes in the Minisci reaction. The N-/O-centered radicals are generated directly from amide (TsNHMe) or alcohol (CF3CH2OH) under visible-light irradiation. This green and eco-friendly synthetic process may find potential use in medicinal chemistry.

  DOI：

  10.1021/acs.orglett.0c02475

文献信息

• Epoxy resins cured with mixed methylene bridged poly(cyclohexyl-aromatic)amine curing agents
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0554823A1

  公开（公告）日：1993-08-11

  This invention pertains to epoxy resins having increased chemical resistance to solvents, and good cured mechanical properties which are prepared by curing the epoxy resins with a curing agent comprising a mixture of methylene bridged poly(cyclohexyl-aromatic)amines. The methylene bridged poly(cyclohexyl-aromatic)amine curing agents are the residue obtained from the distillation of a mixture of poly(cyclohexyl-aromatic)amines formed by the hydrogenation of crude methylenedianiline or crude di(4-amino-3-methylcyclohexyl)methane.

  本发明涉及耐溶剂化学性更强、固化机械性能良好的环氧树脂，其制备方法是用一种由亚甲基桥联聚（环己基芳香族）胺混合物组成的固化剂固化环氧树脂。亚甲基桥联聚（环己基芳香族）胺固化剂是由粗亚甲基苯胺或粗二（4-氨基-3-甲基环己基）甲烷加氢形成的聚环己基芳香族胺混合物蒸馏后的残渣。
• Hydrogenation of methylenedianiline homologs and epoxy resins cured with same
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP1445272A2

  公开（公告）日：2004-08-11

  This invention relates to improved polyepoxide resins cured with a mixture of methylene bridged poly(cycloaliphatic-aromatic)amines and a process for preparing such polyepoxide resins as well as to the methylene bridged poly(cycloaliphatic-aromatic)amine compositions and a method of making them. The improvement resides in using a curative (herein referred to as "Heavy MPCA") comprised of the partially hydrogenated condensation product of formaldehyde and aniline or methyl substituted aniline containing a substantial amount (from 35 to 85% by weight, preferably 40 to 60% by weight) of oligomers in the form of 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14 and 15 aniline or methyl substituted aniline derivatives.

  本发明涉及用亚甲基桥联聚(环脂族-芳香族)胺混合物固化的改进型聚环氧树脂和制备这种聚环氧树脂的工艺，以及亚甲基桥联聚(环脂族-芳香族)胺组合物及其制造方法。改进之处在于使用了一种由甲醛和苯胺或甲基取代苯胺的部分氢化缩合产物组成的固化剂（此处称为 "重型 MPCA"），该固化剂含有大量（按重量计从 35% 到 85%，最好是按重量计从 40% 到 60%）以 3、4、5、6、7、8、9、10、11、12、13、14 和 15 苯胺或甲基取代苯胺衍生物形式存在的低聚物。
• POLYMERZUSAMMENSETZUNG MIT PHOSPHONATFLAMMSCHUTZMITTEL
  申请人：Chemische Fabrik Budenheim KG

  公开号：EP3837311A1

  公开（公告）日：2021-06-23
• ELECTRON TRANSPORT MATERIAL AND ORGANIC LIGHT EMITTING DEVICE
  申请人：Wong Ken-Tsung

  公开号：US20130153863A1

  公开（公告）日：2013-06-20

  An organic light emitting device is provided. The organic light emitting device includes a first electrode layer, a second electrode layer and a light emitting material layer. The second electrode layer is disposed opposite to the first electrode layer. The light emitting material layer is disposed between the first electrode layer and the second electrode layer, and includes an organic light emitting material and an electron transport material, wherein the electron transport material includes a compound represented by a formula (1) below: in which a group A represents an aromatic ring, a is 1, and a group B represents a nitrogen containing five-membered heterocyclic group and derivatives thereof, and has at least one nitrogen atom connected to a meta-position of the group A.
• GOLF BALL COMPOSITIONS
  申请人：Acushnet Company

  公开号：US20160059083A1

  公开（公告）日：2016-03-03

  Disclosed herein are polyurethane golf ball compositions. The compositions are prepared by adding a UV absorber to a polyol prior to reacting the polyol with an isocyanate to form a prepolymer, or by adding the UV absorber to the prepolymer, which is then reacted with a curing agent to form the polyurethane.