1,4-bis(trimethylsilyl)-1,3,5-cyclooctatriene

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,4-bis(trimethylsilyl)-1,3,5-cyclooctatriene
• 英文别名: trimethyl-[(1E,3Z,5E)-6-trimethylsilylcycloocta-1,3,5-trien-1-yl]silane
• 化学式: C₁₄H₂₆Si₂
• 分子量: 250.531
• InChiKey: OTDFZPBLDZPVHL-JQEWSGGFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.94
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 正丁基锂 、 1,4-bis(trimethylsilyl)-1,3,5-cyclooctatriene 、 氯化镨 以 四氢呋喃 、 正己烷 为溶剂， 以83%的产率得到[Pr(1,4-bis(trimethylsilyl)cyclooctatetraenyl)]2[Pr2(1,4-bis(trimethylsilyl)cyclooctatetraenyl)2]2Li2(THF)2Cl8
  参考文献：
  名称：

  A Unique Organolanthanide Cluster Containing Bulky Cyclooctatetraenyl Ligands

  摘要：

  The reaction of anhydrous PrCl3 with Li-2(COT'') (COT'' = 1,4-bis(trimethylsilyl)cyclooctatetraenyl) in THF solution afforded an unprecedented cluster- centered Pr/Li multidecker sandwich complex of composition [Pr-2(COT'')](2)-[Pr-2(COT'')(2)](2)Li-2(THF)(2)Cl-8 (1), in which a central cube of eight Cl atoms is capped by two [Pr(COT'')](+) half-sandwich and two [Pr-2(COT'')(2)](2+) sandwich units as well as two [Li(THF)](+) moieties.

  DOI：

  10.1021/om700589r

文献信息

• A Unique Organolanthanide Cluster Containing Bulky Cyclooctatetraenyl Ligands
  作者：Volker Lorenz、Anja Edelmann、Steffen Blaurock、Fritjof Freise、Frank T. Edelmann

  DOI：10.1021/om700589r

  日期：2007.9.1

  The reaction of anhydrous PrCl3 with Li-2(COT'') (COT'' = 1,4-bis(trimethylsilyl)cyclooctatetraenyl) in THF solution afforded an unprecedented cluster- centered Pr/Li multidecker sandwich complex of composition [Pr-2(COT'')](2)-[Pr-2(COT'')(2)](2)Li-2(THF)(2)Cl-8 (1), in which a central cube of eight Cl atoms is capped by two [Pr(COT'')](+) half-sandwich and two [Pr-2(COT'')(2)](2+) sandwich units as well as two [Li(THF)](+) moieties.