tetrabutylammonium naphthalene-1-sulfinate

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: tetrabutylammonium naphthalene-1-sulfinate
• 英文别名: tetrabutylammonium 1-naphthalenesulfinate；naphthalene-1-sulfinate;tetrabutylazanium
• 化学式: C₁₀H₇O₂S*C₁₆H₃₆N
• 分子量: 433.699
• InChiKey: SRUTYIVLLZBCLK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.08
• 重原子数：
  30
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  59.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  萘-1-亚磺酸 、 四丁基氢氧化铵 以 甲醇 、 水 为溶剂， 生成 tetrabutylammonium naphthalene-1-sulfinate
  参考文献：
  名称：

  [EN] PHOTOINITIATORS HAVING TRIARYLSULFONIUM AND ARYLSULFINATE IONS
  [FR] PHOTO-INITIATEUR POSSEDANT DES IONS TRIARYLSULFONIUM ET ARYLSULFINATE

  摘要：

  提供了包括用于自由基聚合反应的光引发剂体系的组合物。更具体地，光引发剂包括芳基亚磺酸盐离子和三芳基砜离子。还提供了包括光引发剂的光聚合组合物的聚合方法。此外，还披露了三芳基砜芳基亚磺酸盐。

  公开号：

  WO2005034885A1

文献信息

• PHOTOINIATORS HAVING TRIARYLSULFONIUM AND ARYLSULFINATE IONS
  申请人：KALGUTKAR S. Rajdeep

  公开号：US20060111463A1

  公开（公告）日：2006-05-25

  Compositions are provided that include a photoinitiator system for free radical polymerization reactions. More specifically, the photoinitiator includes an arylsulfinate ion and a triarylsulfonium ion. Polymerization methods are also provided those include the photoinitiator in a photopolymerizable composition. Additionally, triarylsulfonium arylsulfinate salts are disclosed.

  提供了一种包含光引发自由基聚合反应的光引发剂体系的组合物。具体而言，光引发剂包括芳基磺酸盐离子和三芳基磺酸盐离子。还提供了在光聚合组合物中使用光引发剂的聚合方法。此外，还披露了三芳基磺酸盐芳基磺酸盐。
• ARYLSULFINATE SALTS IN INITIATOR SYSTEMS FOR POLYMERIC REACTIONS
  申请人：Kalgutkar S. Rajdeep

  公开号：US20060111462A1

  公开（公告）日：2006-05-25

  Compositions are provided that that can be used as an initiator system for free radical polymerization reactions. More specifically, the initiator systems include an electron acceptor and an electron donor. The electron donors are arylsulfinate salts having a cation that contains at least one carbon atom and either a positively charged nitrogen atom or a positively charged phosphorus atom. Methods of polymerization are also provided that can be used to prepare polymeric material with the initiator systems. The initiator systems can be thermal initiator systems, photoinitiator systems, or combinations thereof.

  提供了可用作自由基聚合反应起始剂系统的组合物。更具体地说，该起始剂系统包括一个电子受体和一个电子给体。电子给体是含有至少一个碳原子和一个带正电氮原子或带正电磷原子的阳离子的芳基磺酰盐。还提供了可以使用该起始剂系统制备聚合材料的聚合方法。该起始剂系统可以是热起始剂系统、光引发剂系统或两者的组合。
• Arylsulfinate salts in initiator systems for polymeric reactions
  申请人：Kalgutkar S. Rajdeep

  公开号：US20050070622A1

  公开（公告）日：2005-03-31

  Compositions are provided that that can be used as an initiator system for free radical polymerization reactions. More specifically, the initiator systems include an electron acceptor and an electron donor. The electron donors are arylsulfinate salts having a cation that contains at least one carbon atom and either a positively charged nitrogen atom or a positively charged phosphorus atom. Methods of polymerization are also provided that can be used to prepare polymeric material with the initiator systems. The initiator systems can be thermal initiator systems, photoinitiator systems, or combinations thereof.

  提供了可用作自由基聚合反应的引发剂体系的组合物。更具体地，引发剂体系包括一个电子受体和一个电子给体。电子给体是含有至少一个碳原子和一个带正电荷的氮原子或磷原子的芳基磺酸盐阳离子。还提供了用于制备聚合材料的聚合方法。引发剂体系可以是热引发剂体系、光引发剂体系或两者的组合。
• Photoiniators having triarylsulfonium and arylsulfinate ions
  申请人：Kalgutkar S. Rajdeep

  公开号：US20050070621A1

  公开（公告）日：2005-03-31

  Compositions are provided that include a photoinitiator system for free radical polymerization reactions. More specifically, the photoinitiator includes an arylsulfinate ion and a triarylsulfonium ion. Polymerization methods are also provided those include the photoinitiator in a photopolymerizable composition. Additionally, triarylsulfonium arylsulfinate salts are disclosed.

  提供了一种包括光引发自由基聚合反应的光引发剂系统的组合物。更具体地，该光引发剂包括芳基磺酸盐离子和三芳基磺鎓离子。还提供了一种包括光引发剂在光聚合组合物中的聚合方法。此外，还披露了三芳基磺鎓芳基磺酸盐。
• Arylsulfinate salts in photoinitiator systems for polymerization reactions
  申请人：Kalgutkar S. Rajdeep

  公开号：US20050070624A1

  公开（公告）日：2005-03-31

  Compositions are provided that include an electron donor and a sensitizing compound. More specifically, the electron donor is an arylsulfinate salt. Methods of polymerization are also provided that can be used to prepare polymeric material from a photopolymerizable composition that includes ethylenically unsaturated monomers and a photoinitiator system. The photoinitiator system includes an electron donor and a sensitizing compound.

  提供了包括电子供体和敏化化合物的组合物。更具体地，电子供体是芳基亚磺酸盐。还提供了聚合的方法，可以用于从光聚合组合物中制备聚合材料，该组合物包括乙烯基不饱和单体和光引发剂体系。光引发剂体系包括电子供体和敏化化合物。