trinitrogen

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• 英文名称: trinitrogen
• 英文别名: azane
• 化学式: N₃
• 分子量: 42.0201
• InChiKey: XSOHCQBMTDEBAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.49
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  trinitrogen 生成 hexanitrogen
  参考文献：
  名称：

  Trautz, M., Zeitschrift für Elektrochemie, 1919, vol. 25, p. 300

  摘要：

  DOI：
• 作为产物：
  描述：

  迭氮酸 以 gaseous matrix 为溶剂， 生成 trinitrogen
  参考文献：
  名称：

  The 193 (and 248) nm photolysis of HN₃: Formation and internal energy distributions of the NH (a ¹Δ, b ¹∑⁺, A ³Π, and c ¹Π) states

  摘要：

  The UV photolysis of HN3 at 193 nm was investigated in detail in the bulk phase at 300 K. NH radicals in the X, a, b, A, and c states were found to be formed with quantum yields ≤0.0019, 0.4, 0.017, 0.000 15, and 0.000 61, respectively. Relative rotational and vibrational populations were measured for all states except for NH(X). Average translational energies were estimated for NH(a,v=0 and 1) and NH(b,v=0). The 248 nm photolysis of HN3 was reinvestigated with respect to processes forming NH radicals other than NH(a). The observed energy distributions differ for both laser wavelengths and for high and low lying NH states. The distribution can be better described by a simple impulsive than by a statistical model. Some conclusions are drawn concerning the upper HN3 potential surfaces involved.

  DOI：

  10.1063/1.454691

文献信息

• Newman, F. H., Philosophical Magazine (1798-1977), 1922, vol. 43, p. 457
  作者：Newman, F. H.

  DOI：——

  日期：——
• Browne, A. W.; Lundell, G. E. F., Journal of the American Chemical Society, 1909, vol. 31, p. 445
  作者：Browne, A. W.、Lundell, G. E. F.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: N: MVol.1, 1.9, page 282 - 282
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: N: MVol.1, 1.6.1, page 257 - 270
  作者：

  DOI：——

  日期：——
• Thomson, J. J., Philosophical Magazine (1798-1977), <hi>1912</hi>, vol. 24, p. 241
  作者：Thomson, J. J.

  DOI：——

  日期：——