tert-Butylsulfenyl isopropylsulfonyl thioanhydride

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: tert-Butylsulfenyl isopropylsulfonyl thioanhydride
• 英文别名: tert-butylsulfenic isopropylsulfonic thioanhydride；2-Methyl-2-(propan-2-ylsulfonyldisulfanyl)propane
• 化学式: C₇H₁₆O₂S₃
• 分子量: 228.401
• InChiKey: LGNXJJUDUHFAQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  93.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  tert-butyl hydrodisulfide 在 吡啶 、 异丙基磺酰氯 作用下， 以 乙醚 为溶剂， 反应 5.0h， 以22%的产率得到tert-Butylsulfenyl isopropylsulfonyl thioanhydride
  参考文献：
  名称：

  Synthesis and Decomposition of Some Dialkyl Oxide Derivatives of Organotrisulfides

  摘要：

  The isolation or detection of sulfenic sulfonic thioanhydrides 1 (e.g., 6), sulfenyl vic-disulfoxides 4 (e.g., 9, 14), and sulfinic thioanhydrides 5 (e.g., 20) has been carried out by oxidative procedures at various temperatures. The decomposition of these compounds has been investigated and is shown to be consistent with the mechanism proposed for the decomposition of trisulfide monoxides.

  DOI：

  10.1021/jo950826x

文献信息

• From symmetrical tetrasulfides to trisulfide dioxides <i>via</i> photocatalysis
  作者：Kai Gong、Yilin Zhou、Xuefeng Jiang

  DOI：10.1039/d1gc03242a

  日期：——

  achieved symmetrical tetrasulfides. Stern–Volmer analysis and radical quenching experiments demonstrated the occurrence of a single electron transfer between the photocatalyst and sulfinic acid. Bioactive molecules such as the antihypertensive drug captopril, allicin derivatives, amino acids and terpenes were efficiently and reversibly linked through sulfur–sulfur covalent bonds. Furthermore, flow-setup syntheses

  已经建立了涉及光催化的直接策略，用于从容易获得的对称四硫化物获取三氧化二硫。Stern-Volmer 分析和自由基猝灭实验证明了光催化剂和亚磺酸之间发生了单电子转移。抗高血压药物卡托普利、大蒜素衍生物、氨基酸和萜烯等生物活性分子通过硫硫共价键高效可逆地连接。此外，在克规模上成功实现了二氧化三硫化物的流动设置合成，表明所开发的协议在实际工业应用中具有巨大潜力。
• The Chemistry of Alkylsulfenyl Alkylsulfinyl Thioanhydrides. The Mechanism of Decomposition
  作者：Gerard Derbesy、David N. Harpp

  DOI：10.1021/jo00119a025

  日期：1995.7

  The decomposition mechanism of alkylsulfenyl alkylsulfinyl thioanhydrides has been investigated. Although the product mixture is complex in most cases, a detailed decomposition study as well as a careful analysis of the products allows for a proposal for a general mechanism which is interesting and not simple. We find, however, that the decomposition process is consistent with that of related systems.
• Synthesis and Decomposition of Some Dialkyl Oxide Derivatives of Organotrisulfides
  作者：Gérard Derbesy、David N. Harpp

  DOI：10.1021/jo950826x

  日期：1996.1.1

  The isolation or detection of sulfenic sulfonic thioanhydrides 1 (e.g., 6), sulfenyl vic-disulfoxides 4 (e.g., 9, 14), and sulfinic thioanhydrides 5 (e.g., 20) has been carried out by oxidative procedures at various temperatures. The decomposition of these compounds has been investigated and is shown to be consistent with the mechanism proposed for the decomposition of trisulfide monoxides.