1,2-naphthalenedithiol

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2-naphthalenedithiol
• 英文别名: naphthalene-1,2-dithiol；napthylenethiol；Naphthalenedithiole
• 化学式: C₁₀H₈S₂
• 分子量: 192.306
• InChiKey: KYAHXDQYSVFOOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-naphthalenedithiol 在 氨 、 sulfur 作用下， 以 二氯甲烷 为溶剂， 以92 mg的产率得到naphtho[1,2-f]pentathiepin
  参考文献：
  名称：

  Cyclic polysulfides fused to polyaromatics

  摘要：

  Pentathiepins fused to naphthalene and phenanthrene have been synthesized by a simple method. Ring size depends on the stability of generated products related to steric and electronic factors. Sometimes, delocalized pi-electron of polyarornatics shows synergistic effect on the stabilization of polysulfur rings. The structures of two polysulfides were also studied by X-ray crystallography and phenanthrene bearing C2S5 ring showed different solid-state properties than corresponding phenanthrene bearing C2S3 ring. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.11.026
• 作为产物：
  描述：

  1-奈硫酚 生成 1,2-naphthalenedithiol
  参考文献：
  名称：

  Cyclic polysulfides fused to polyaromatics

  摘要：

  Pentathiepins fused to naphthalene and phenanthrene have been synthesized by a simple method. Ring size depends on the stability of generated products related to steric and electronic factors. Sometimes, delocalized pi-electron of polyarornatics shows synergistic effect on the stabilization of polysulfur rings. The structures of two polysulfides were also studied by X-ray crystallography and phenanthrene bearing C2S5 ring showed different solid-state properties than corresponding phenanthrene bearing C2S3 ring. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.11.026

文献信息

• RESIST COMPOSITION, METHOD FOR FORMING RESIST PATTERN, POLYPHENOLIC COMPOUND FOR USE IN THE COMPOSITION, AND ALCOHOLIC COMPOUND THAT CAN BE DERIVED THEREFROM
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US20160145231A1

  公开（公告）日：2016-05-26

  A resist composition containing a compound represented by the general formula (1) or (2), a method for forming a resist pattern using the composition, a polyphenolic compound for use in the composition, and an alcoholic compound that can be derived therefrom are described.

  描述了一种包含由通式（1）或（2）表示的化合物的光刻胶组合物，使用该组合物形成光刻胶图案的方法，用于该组合物的多酚化合物，以及可以由其衍生的醇化合物。
• Immobilized Cobalt Bis(benzenedithiolate) Complexes: Exceptionally Active Heterogeneous Electrocatalysts for Dihydrogen Production from Mildly Acidic Aqueous Solutions
  作者：Shawn C. Eady、Molly M. MacInnes、Nicolai Lehnert

  DOI：10.1021/acs.inorgchem.7b01589

  日期：2017.10.2

  V versus platinum. Controlled-potential electrolysis studies performed in 0.5 M H2SO4 at −0.5 V versus SHE show impressive initial rate constants of over 500 s–1 under bulk electrolysis conditions; however, steady catalyst deactivation over an 8 h period is observed, with turnover numbers reaching 9.1 × 106. Electrolysis studies reveal that halide substitution is a central factor in improving the turnover

  制备了一系列具有不同苯二硫代酸酯（一般缩写：bdt 2–）环取代（S 2 C 6 X 4 2–）的钴双（苯二硫代）钴配合物，并将其吸附在由（a）氧化石墨烯（RGO）组成的廉价电极上电沉积在掺氟氧化锡（FTO）和（b）高度有序的热解石墨（HOPG）上。催化剂吸附的电极通过X射线光电子能谱表征。随着卤化物取代的增加，TBA [Co（S 2 C 6 H 4）2从2.7×10 –11 mol cm –2]显着提高了整个配体系列的催化剂负载量（1）到TBA [Co（S 2 C 6 Cl 4）2 ]（3）]增加到6.22×10 –10 mol cm -2，并增加苯二硫代盐配体的环大小[最高达3.10×10 –9 mol cm –2用于TBA [Co（S 2 C 10 H 6）2 ]（6）]。对固定在HOPG上的配合物进行电催化分析会引起还原电流响应，表明存在三氟乙酸的弱酸性水溶液（pH 2-4）时产生二氢，相对于SHE，过电势约为0
• COMPOUND AND COLOR CONVERSION FILM COMPRISING THE SAME
  申请人：LG CHEM, LTD.

  公开号：US20200087324A1

  公开（公告）日：2020-03-19

  The present specification relates to a compound, and a color conversion film, a backlight unit, and a display device, including the same.

  本规范涉及一种化合物，以及包括该化合物的颜色转换膜、背光单元和显示装置。
• COMPOUND, MATERIAL FOR FORMING UNDERLAYER FILM FOR LITHOGRAPHY, UNDERLAYER FILM FOR LITHOGRAPHY AND PATTERN FORMING METHOD
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20150376202A1

  公开（公告）日：2015-12-31

  The material for forming an underlayer film for lithography of the present invention contains a compound having a structure represented by the following general formula (1). (in formula (1), each X independently represents an oxygen atom or a sulfur atom, R 1 represents a single bond or a 2n-valent hydrocarbon group having 1 to 30 carbon atoms, the hydrocarbon group may have a cyclic hydrocarbon group, a double bond, a hetero atom or an aromatic group having 6 to 30 carbon atoms, R 2 represents a linear, branched or cyclic alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, or a hydroxyl group, m is an integer of 0 to 3, n is an integer of 1 to 4, p is 0 or 1, and q is an integer of 1 to 100.)

  本发明的光刻下层膜材料包含具有以下一般式（1）所代表结构的化合物。（在式（1）中，每个X独立地代表氧原子或硫原子，R1代表一个单键或具有1至30个碳原子的2n-价碳氢基团，碳氢基团可能具有一个环状碳氢基团，一个双键，一个杂原子或具有6至30个碳原子的芳香族基团，R2代表具有1至10个碳原子的直链、支链或环状烷基基团，具有6至10个碳原子的芳基基团，具有2至10个碳原子的烯基基团，或一个羟基，m是0到3的整数，n是1到4的整数，p是0或1，q是1到100的整数。）
• METHOD FOR PURIFYING COMPOUND OR RESIN
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US20170001972A1

  公开（公告）日：2017-01-05

  The method according to the present invention is a method for purifying a compound represented by a specific formula (1) or a resin having a structure represented by a specific formula (2), the method including a step of bringing a solution (A) including an organic solvent optionally immiscible with water, and the compound or the resin into contact with an acidic aqueous solution.

  根据本发明的方法是一种用于纯化由特定化学式（1）表示的化合物或具有特定化学式（2）表示的结构的树脂的方法，该方法包括将含有有机溶剂（可选择与水不相容）的溶液（A）与该化合物或树脂接触酸性水溶液的步骤。