8-ethynylfluoranthene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8-ethynylfluoranthene
• 化学式: C₁₈H₁₀
• 分子量: 226.277
• InChiKey: IBUCBVCVXONATF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  8-(1-chloroethenyl)fluoranthene 1000.0 ℃ 、1.33 Pa 条件下， 生成 8-ethynylfluoranthene
  参考文献：
  名称：

  Migration of redundant ethynyl substituents along polycyclic aromatic hydrocarbon peripheries. Consequences for polycyclic aromatic hydrocarbon build up

  摘要：

  The formation of cyclopenta[cd]pyrene (5) and benzo[ghi]fluoranthene (6) upon FVT of 3,9-bisethynylphenanthrene (1) and 8-ethynylfluoranthene (2), respectively, suggests that redundant ethynyl substituents, which cannot give five- and/or six-membered ring formation via ethynyl ethylidene carbene equilibration followed by carbene C-H insertion, can migrate along the PAH periphery at high temperatures. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01685-7

文献信息

• Migration of redundant ethynyl substituents along polycyclic aromatic hydrocarbon peripheries. Consequences for polycyclic aromatic hydrocarbon build up
  作者：Martin Sarobe、Leonardus W. Jenneskens、Arjan Kleij、Maria Petroutsa

  DOI：10.1016/s0040-4039(97)01685-7

  日期：1997.10

  The formation of cyclopenta[cd]pyrene (5) and benzo[ghi]fluoranthene (6) upon FVT of 3,9-bisethynylphenanthrene (1) and 8-ethynylfluoranthene (2), respectively, suggests that redundant ethynyl substituents, which cannot give five- and/or six-membered ring formation via ethynyl ethylidene carbene equilibration followed by carbene C-H insertion, can migrate along the PAH periphery at high temperatures. (C) 1997 Elsevier Science Ltd.