四溴氢金(III)水合物 | 17083-68-0

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 中文名称: 四溴氢金(III)水合物
• 英文名称: tetrabromoauric acid
• 英文别名: hydrogen tetrabromoaurate(III)；HAuBr4；Tetrabromogold(III)-saeure；bromoauric acid；Hydrogentetrabromoaurate(III)hydrate；tribromogold;hydrobromide
• CAS: 17083-68-0
• 化学式: AuBr₄*H
• 分子量: 517.59
• InChiKey: ISCGOTZIVSCDBJ-UHFFFAOYSA-K

物化性质

• 熔点：
  27°C
• 沸点：
  27℃ [CRC10]
• 溶解度：
  溶于水、乙醇
• 稳定性/保质期：

  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  -11.87
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 储存条件：
  存放于阴凉干燥处。

SDS

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Section 1: Product Identification
Chemical Name: Hydrogen tetrabromoaurate (III) hydrate (99.9%-Au)
CAS Registry Number: 17083-68-0
Formula: HAuBr4.XH2O
EINECS Number: 241-139-9
Chemical Family: metal acid halide
Synonym: Aurate(1-), tetrabromo-, hydrogen, (SP-4-1)-

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 17083-68-0 100% no data no data

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Section 3: Hazards Identification
Corrosive to skin, eyes, and respiratory tract. Exposure to gold compounds may damage kidney function and
Emergency Overview:
reduce blood cell count.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Causes burns to the eyes.
Skin Contact: Causes burns to the skin.
Inhalation: Dust is corrosive to the nose, mucous membranes and respiratory tract.
Causes burns to the gastrointestinal system. Gold compounds may lead to dermatitis, metallic taste, and
Ingestion:
convulsions.
Corrosive to eyes, skin and respiratory tract, May impair kidney and bone marrow functions and cause
Acute Health Affects:
abdominal cramps, vomiting bloody diarrhea, weakness and convulsions.
Chronic Health Affects: Prolonged exposure to gold compounds may lead to reduced red and white blood cell generation.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: none required
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic bromine and hydrobromic acid fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite, or other suitable
Spill and Leak Procedures:
inert material and swept up.

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SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry place in a tightly sealed container.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: Material may form a fine dust. Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Material may form a fine dust. Handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: black xtl
Molecular Weight: 517.61
Melting Point: no data
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: no data
Odor: none
Solubility in Water: very soluble

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SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: active metals and strong bases
Decomposition Products: hydrogen bromide, bromine, and gold salts

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SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data
Mutagenic Effects: No data
Tetratogenic Effects: No data

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SECTION 12: Ecological Information
Ecological Information: No information available

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Corrosive solids, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN #1759
Shipping Name (IATA): Corrosive solids, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN #1759

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SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: None

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  四溴氢金(III)水合物 在 poly(vinylpyrrolidone) 、 silver nitrate 作用下， 以 乙二醇 为溶剂， 生成 金
  参考文献：
  名称：

  乙二醇中金纳米颗粒光化学生成的分子机理：支持歧化机理。

  摘要：

  发现用大体积的溴离子代替四氯金酸中的氯离子在乙二醇的光化学还原中抑制了金纳米颗粒的形成。然而，发现向溴化物或氯化物金酸溶液中添加银离子可提高金纳米颗粒的形成速率。发现这些结果是由先前提出的机制所解释的（Eustis，S。； Hsu，H.-Y。； El-Sayed，MAJ Phys.Chem.B 2005，109，4811），其涉及氯金配合物的歧化。产生自由的金原子和氯离子。庞大的溴离子的空间效应抑制了歧化反应电子转移过程中所需的Au-Au键的形成。Ag +离子的添加​​导致形成不溶的卤化银，

  DOI：

  10.1021/jp062972k
• 作为产物：
  描述：

  金 在 HBr 、 Br₂ 作用下， 生成 四溴氢金(III)水合物
  参考文献：
  名称：

  Ito, Yukari; Asaji, Tetsuo; Ikeda, Ryuichi, Berichte der Bunsen-Gesellschaft, 1988, vol. 92, p. 885 - 891

  摘要：

  DOI：
• 作为试剂：
  描述：

  碘苯二乙酸 、 环辛烷 在 四溴氢金(III)水合物 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 3.0h， 生成 环辛基乙酸酯
  参考文献：
  名称：

  饱和烃的金催化直接 C(sp3)-H 乙酰氧基化

  摘要：

  在此通讯中，我们报告了我们对开发金催化的 C(sp 3 )-H 键直接乙酰氧基化的研究。我们通过使用高价碘试剂 PhI(OAc) 2与简单的金盐 (HAuBr 4 ) 作为催化剂来实现这一点。通过比较环辛烷和金刚烷的反应性，我们判断反应是通过氢化物转移进行的。通过对源自与 CH 裂解步骤相关的环辛烷和金刚烷的 C-H 键裂解的阴离子、自由基和阳离子的相对能量的计算研究，进一步证实了这一点。

  DOI：

  10.1002/cctc.202100804

文献信息

• Efficient extraction of gold from water by liquid–liquid extraction or precipitation using hydrophobic ionic liquids
  作者：Stéphanie Boudesocque、Aminou Mohamadou、Laurent Dupont

  DOI：10.1039/c4nj01115e

  日期：——

  Tetrahalogenoaurate anions have been successfully removed from water using betaine derivative cationic ionic liquids, by precipitation using hydrophilic ionic liquids or by liquid–liquid extraction with hydrophobic ionic liquids.

  四卤金酸盐阴离子已成功通过使用甜菜碱衍生阳离子离子液体沉淀或使用亲水性离子液体沉淀，或通过疏水性离子液体液-液萃取从水中去除。
• Unsaturated gold(III) tetraaza complexes: Synthesis, structures, and properties
  作者：V. A. Afanas’eva、I. V. Mironov、L. A. Glinskaya、R. F. Klevtsova

  DOI：10.1134/s1070328410010021

  日期：2010.1

  Data on the synthesis and physicochemical study of polychelate gold(III) tetraaza complexes containing two five-membered and one or two six-membered unsaturated chelate rings were generalized.

  概括了有关含有两个五元和一个或两个六元不饱和螯合环的多螯合金（III）四氮杂配合物的合成和理化研究的数据。
• Halogen impact into new oxonium benzo-crown ether complexes with tetrachloro- and tetrabromoaurates(iii)
  作者：Sergei M. Pluzhnik-Gladyr、Victor Ch. Kravtsov、Marina S. Fonari、Gerbert L. Kamalov

  DOI：10.1039/c4dt00017j

  日期：——

  Five oxonium tetrahalogenaurate(III) (Hal = Cl, Br) benzo-crown ether (BCE) complexes are prepared and reported. The new compounds are [(H3O)(B18C6)0.58(4′-Cl-B18C6)0.42][AuCl4] 1, [(H3O)(B18C6)][AuCl4] 2, [(H3O)(4′-Br-B18C6)][AuCl4] 3, [(H3O)(4′-Br-B18C6)][AuBr4] 4, and [(H3O)(B18C6)][AuBr4] 5. The reaction medium, distinctive from the previously used aqua regia, allowed avoiding the unwanted nitration of initial macrocycles. The compositions and structures for 1, 3, 4, and 5 were proved by single crystal X-ray crystallography. The complete conversion of tetrachloroaurate(III) to the tetrabromoaurate(III) salts resulted in complex 4 isomorphous and isostructural to 3. All compounds form the laminated structures with alternation of cationic and anionic layers. The robustness of the anionic sheets is sustained by the halogen–halogen interactions and makes crucial impact on extraction of stoichiometric products in the case of tetrabromoaurate(III) salts.

  制备并报告了五种氧鎓四卤化金(III)（卤 = Cl, Br）苯并冠醚（BCE）复合物。新化合物为[(H3O)(B18C6)0.58(4′-Cl-B18C6)0.42][AuCl4] 1，[( )(B18C6)][AuCl4] 2，[( )(4′-Br-B18C6)][AuCl4] 3，[( )(4′-Br-B18C6)][AuBr4] 4，和[( )(B18C6)][AuBr4] 5。与之前使用的王水反应介质不同，该介质避免了初始大环的不必要硝化。通过单晶X射线晶体学证明了1、3、4和5的组成和结构。四氯金(III)转化为四溴金(III)盐的完全反应导致复合物4与3同晶型和同结构。所有化合物形成层状结构，带有阳离子和阴离子层的交替。阴离子层的稳定性通过卤素–卤素相互作用得以维持，并对四溴金(III)盐的化学计量产品提取产生重要影响。
• Shape-Controlled Synthesis of Trimetallic Nanoclusters: Structure Elucidation and Properties Investigation
  作者：Xi Kang、Lin Xiong、Shuxin Wang、Haizhu Yu、Shan Jin、Yongbo Song、Tao Chen、Liwei Zheng、Chensong Pan、Yong Pei、Manzhou Zhu

  DOI：10.1002/chem.201603893

  日期：2016.11.21

  by alloying with [AuI(PPh3)Br]. The structures of the trimetallic NCs were determined by X‐ray crystallography and further confirmed by both DFT and far‐IR measurements. The shape‐preserved [Pt1Au6.4Ag17.6(SPhMe2)18] NC is in a tristratified arrangement—[Pt(center)@Au/Ag(shell)@Ag(exterior)]—and is indeed the first X‐ray crystal structure of thiolated trimetallic NCs. On the other hand, the resulting

  具有精确原子排列的形状受控的金属纳米团簇（NC）的合成对于定制性能至关重要。在这项工作中，我们通过在合金化过程中改变掺杂剂来成功控制合金NC的形状。当使用[Au I SR]作为掺杂剂时，球形[Pt 1 Ag 24（SPhMe 2）18 ] NC的形状得以保持。相反，通过与[Au I（PPh 3）Br]合金化，Pt 1 Ag 24的形状变为棒状。三金属NC的结构通过X射线晶体学确定，并通过DFT和远红外测量进一步证实。保形[Pt 1Au 6.4 Ag 17.6（SPhMe 2）18 ] NC是三层结构的[Pt（中心）@ Au / Ag（壳）@Ag（外部）]，并且确实是硫代三金属NC的第一个X射线晶体结构。 。另一方面，所得的棒状NC（[Pt 2 Au 10 Ag 13（PPh 3）10 Br 7 ]）显示出高量子产率（QY ＝ 14.7％），这与微弱发光的Pt 1 Ag形成鲜明对比。24（QY
• Macrocyclic Receptor for Precious Gold, Platinum, or Palladium Coordination Complexes
  作者：Wenqi Liu、Allen G. Oliver、Bradley D. Smith

  DOI：10.1021/jacs.8b04155

  日期：2018.6.6

  Two macrocyclic tetralactam receptors are shown to selectively encapsulate anionic, square-planar chloride and bromide coordination complexes of gold(III), platinum(II), and palladium(II). Both receptors have a preorganized structure that is complementary to its precious metal guest. The receptors do not directly ligate the guest metal center but instead provide an array of arene π-electron donors

  两种大环四内酰胺受体显示出选择性地封装金 (III)、铂 (II) 和钯 (II) 的阴离子、方形平面氯化物和溴化物配位络合物。两种受体都具有与其贵金属客体互补的预先组织的结构。受体不直接连接客体金属中心，而是提供一系列与带正电金属相互作用的芳烃 π 电子供体和与外部带负电配体相互作用的氢键供体。这种独特的超分子识别模式通过六个 X 射线晶体结构来说明，这些晶体结构显示了 AuCl4-、AuBr4-、PtCl4-2 或 Pd2Cl6-2 的受体封装。在有机溶液中，1:1 的缔合常数与在固态中识别的特定超分子特征相关。