N-methyldibenzo[b,d]furan-2-amine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: N-methyldibenzo[b,d]furan-2-amine
• 英文别名: N-methyldibenzofuran-2-amine
• 化学式: C₁₃H₁₁NO
• 分子量: 197.236
• InChiKey: DJSTUOHFSUQLCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  25.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二苯并呋喃 、 N-methyl-O-tosylhydroxylamine 在 air 作用下， 反应 36.0h， 以69%的产率得到N-methyldibenzo[b,d]furan-2-amine
  参考文献：
  名称：

  无金属直接芳烃 C−H 胺化

  摘要：

  通过形成 CN 键合成芳胺是制备功能材料、活性药物成分和生物活性产品的重要工具。通常，这种化学连接只能通过过渡金属催化的反应、光化学或电化学来实现。在这里，我们报告了在良性条件下使用羟胺衍生物进行的无金属芳烃 C-H 胺化。即使在存在各种官能团的情况下，胺化试剂 TsONHR 和芳烃底物之间的电荷转移相互作用也能实现芳烃的化学选择性胺化。氧气对于有效转化至关重要，其对电子转移步骤的加速作用已通过实验证明。此外，

  DOI：

  10.1002/adsc.202100236

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：EP4016659A1

  公开（公告）日：2022-06-22

  Provided are OLEDs and related electronic devices that utilize these OLED devices. The OLED includes an emissive region that includes a sensitizer and an acceptor, where the sensitizer has a lowest excitation energy state ET1, and is capable of harvesting triplet excitons; where the acceptor is capable of receiving energy from the sensitizer and functioning as a fluorescent emitter at room temperature; where the acceptor has a first moiety and a second moiety, the first moiety having a lowest singlet excitation energy state ES1A and a lowest triplet excitation energy state ET1A, and the second moiety having a lowest singlet excitation energy state ES1B and a lowest triplet excitation energy state ET1B; and where ES1A < ES1B, ET1A > ET1B, and ET1 > ES1A.

  本文提供了有机发光二极管和利用这些有机发光二极管器件的相关电子设备。OLED 包括一个发射区，该发射区包括敏化剂和受体，其中敏化剂具有最低激发能态 ET1，能够收集三重激子；受体能够接收来自敏化剂的能量，并在室温下作为荧光发射器工作；其中受体具有第一基团和第二基团，第一基团具有最低单态激发能态 ES1A 和最低三重态激发能态 ET1A，第二基团具有最低单态激发能态 ES1B 和最低三重态激发能态 ET1B；并且 ES1A ET1B 和 ET1 > ES1A。
• Tricyclic compounds with antiviral activity
  申请人：Booth John Richard

  公开号：US20050075332A1

  公开（公告）日：2005-04-07

  The present invention provides a compound of the formula (I) and pharmaceutically acceptable salts having useful antiviral activity against viruses of the herpes family. In said formula, X═O, (CH 2 ) m , S, SO, SO 2 , NH, NR 8 , or a chemical bond; Y═O, (CH 2 ) m , S, SO, SO 2 , NH, NR 8 ; Z=NH, O, NR 8 , S, SO, SO 2 . The remaining substituents are described in the specification.
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Yabunouchi Nobuhiro

  公开号：US20120074395A1

  公开（公告）日：2012-03-29

  Provided is an organic EL device, including: an anode; a cathode; and an organic thin-film layer provided between the anode and the cathode, in which: the organic thin-film layer has a light emitting layer containing a host material and a light emitting material, and a hole transporting layer; and the hole transporting layer has a first hole transporting layer and a second hole transporting layer in the stated order from the anode; the first hole transporting layer contains a specific amine compound; and the second hole transporting layer contains a specific amine compound; or the hole transporting layer has a layer containing a specific electron acceptable compound and a first hole transporting layer; and the first hole-transporting layer contains a specific amine compound. The organic EL device has a reduced driving voltage, high luminous efficiency, and excellent practicality.
• US6800656B2
  申请人：——

  公开号：US6800656B2

  公开（公告）日：2004-10-05
• A Metal‐Free Direct Arene C−H Amination
  作者：Tao Wang、Marvin Hoffmann、Andreas Dreuw、Edina Hasagić、Chao Hu、Philipp M. Stein、Sina Witzel、Hongwei Shi、Yangyang Yang、Matthias Rudolph、Fabian Stuck、Frank Rominger、Marion Kerscher、Peter Comba、A. Stephen K. Hashmi

  DOI：10.1002/adsc.202100236

  日期：2021.6.8

  The synthesis of aryl amines via the formation of a C−N bond is an essential tool for the preparation of functional materials, active pharmaceutical ingredients and bioactive products. Usually, this chemical connection is only possible by transition metal-catalyzed reactions, photochemistry or electrochemistry. Here, we report a metal-free arene C−H amination using hydroxylamine derivatives under benign

  通过形成 CN 键合成芳胺是制备功能材料、活性药物成分和生物活性产品的重要工具。通常，这种化学连接只能通过过渡金属催化的反应、光化学或电化学来实现。在这里，我们报告了在良性条件下使用羟胺衍生物进行的无金属芳烃 C-H 胺化。即使在存在各种官能团的情况下，胺化试剂 TsONHR 和芳烃底物之间的电荷转移相互作用也能实现芳烃的化学选择性胺化。氧气对于有效转化至关重要，其对电子转移步骤的加速作用已通过实验证明。此外，