异丙基仲丁基过氧二碳酸酯 | 78350-78-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 中文名称: 异丙基仲丁基过氧二碳酸酯
• 英文名称: Isopropyl-sec-butylperoxydicarbonate
• 英文别名: butan-2-yl propan-2-yloxycarbonyloxy carbonate
• CAS: 78350-78-4
• 化学式: C₉H₁₆O₆
• 分子量: 220.22
• InChiKey: AKUHVUBQELUSIY-UHFFFAOYSA-N

物化性质

• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• [EN] (STABILISED) PEROXIDE COMPOSITIONS PHLEGMATISED WITH A SPECIFIC UNSATURATED PHLEGMATISING AGENT<br/>[FR] COMPOSITIONS DE PEROXYDE (STABILISEES) FLEGMATISEES AU MOYEN D'UN FLEGMATISANT INSATURE SPECIFIQUE
  申请人：AKZO NOBEL NV

  公开号：WO2004000799A1

  公开（公告）日：2003-12-31

  The invention relates to peroxide compositions that are phlegmatised with a specific unsaturated phlegmatising agent. The phlegmatised peroxide compositions are optionally stabilised. In addition, the invention relates to the safe handling of these peroxide compositions and the use of these peroxide compositions in polymerisation processes..

  本发明涉及一种使用特定不饱和糊化剂糊化的过氧化物组合物。糊化的过氧化物组合物可以选择稳定。此外，本发明涉及这些过氧化物组合物的安全处理以及在聚合过程中使用这些过氧化物组合物。
• Compositions for producing polymers of high refractive index and low yellowness
  申请人：PPG INDUSTRIES, INC.

  公开号：EP0224123A2

  公开（公告）日：1987-06-03

  The yellowness of polymerizates formed from polymerizable compositions containing bisphenol bis(allylic carbonate)-functional material is reduced by inclusion of one or more cyclohexenic compounds in the polymerizable compositions.

  在含有双酚双（烯丙基碳酸酯）官能团材料的可聚合组合物中加入一种或多种环己烯化合物，可降低由可聚合组合物形成的聚合物的黄度。
• Golf balls having a foam layer of a cross-linked thermoplastic composition
  申请人：Acushnet Company

  公开号：US10391363B2

  公开（公告）日：2019-08-27

  Golf balls having an inner core made of a foamed composition are provided. The core assembly preferably includes a foam inner core (center) and surrounding outer core layer. A cross-linked thermoplastic, preferably an ethylene acid copolymer ionomer, is used to form the foam composition. The core layers have different hardness gradients and specific gravity values. The ethylene acid copolymer is reacted with a metallic acrylate salt and peroxide free-radical initiator to form the cross-linked polymer. The foamed, cross-linked composition helps provide the inner core with good resiliency, thermal stability, and durability. Non-foamed thermoplastics or thermosets such as polybutadiene rubber may be used to form the outer core layer. The ball further includes a cover that may be multi-layered.

  高尔夫球的内芯由发泡组合物制成。球芯组件最好包括泡沫内芯（中心）和周围的外芯层。交联热塑性塑料，最好是乙烯酸共聚物离聚物，用于形成泡沫组合物。芯层具有不同的硬度梯度和比重值。乙烯酸共聚物与金属丙烯酸盐和过氧化物自由基引发剂反应，形成交联聚合物。发泡交联组合物有助于为内芯提供良好的回弹性、热稳定性和耐用性。非发泡热塑性塑料或热固性塑料（如聚丁二烯橡胶）可用于形成外芯层。球还包括一个可以是多层的外层。
• Polymer foams
  申请人：FINA TECHNOLOGY, INC.

  公开号：US10745537B2

  公开（公告）日：2020-08-18

  A polymeric composition may include a polyolefin or styrenic polymer, a metallic acrylate salt, and an acid neutralizer.

  聚合物组合物可包括聚烯烃或苯乙烯聚合物、金属丙烯酸盐和酸中和剂。
• Polymerizable composition based on allyl carbonate monomers, polymerized product obtainable from said composition and uses thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：US11046812B2

  公开（公告）日：2021-06-29

  The present invention relates to a polymerizable composition based on allyl carbonate monomers comprising: —from 40% to 90% of a first reactive component (component A) comprising at least 50% by weight of diethylene glycol bis(allyl carbonate); from 10% to 60% of a second reactive component (component B) consisting of at least one compound having general formula (II) or having general formula (III) from 0.4 to 10.0 phm (parts by weight per 100 parts of the total weight of components A and B) of at least one peroxide radical initiator. The present invention also relates to the polymerized products that can be obtained from the above composition, their preparation process and their use as organic glass.

  本发明涉及一种基于碳酸烯丙酯单体的可聚合组合物，该组合物包含： -40%至 90%的第一反应组分（组分 A），其中包含至少 50% （按重量计）的二甘醇双（碳酸烯丙酯）； 10%至 60%的第二活性组分（组分 B），由至少一种具有通式 (II) 的化合物组成 或具有通式(III) 0.4 至 10.0 phm（每 100 份组分 A 和 B 的总重量的重量份数）的至少一种过氧自由基引发剂。本发明还涉及可从上述组合物中获得的聚合产物、其制备工艺及其作为有机玻璃的用途。