4-[(E)-2-(4-Azetidin-1-yl-phenyl)-vinyl]-benzonitrile

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4-[(E)-2-(4-Azetidin-1-yl-phenyl)-vinyl]-benzonitrile
• 英文别名: 4-[(E)-2-[4-(azetidin-1-yl)phenyl]ethenyl]benzonitrile
• 化学式: C₁₈H₁₆N₂
• 分子量: 260.338
• InChiKey: LTNODKHSRCOHDK-NSCUHMNNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  27
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-[(E)-2-(4-Azetidin-1-yl-phenyl)-vinyl]-benzonitrile 以 乙腈 为溶剂， 生成 4-[(Z)-2-(4-Azetidin-1-yl-phenyl)-vinyl]-benzonitrile
  参考文献：
  名称：

  Ipichev, Yurii V.; Zachariasse, Klaas A., Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1997, vol. 101, # 3, p. 625 - 635

  摘要：

  DOI：

文献信息

• Dye loaded zeolite material containing devices
  申请人：Calzaferri Gion

  公开号：US20060001004A1

  公开（公告）日：2006-01-05

  The present invention provides a dye loaded zeolite material comprising: a) at least one zeolite crystal having straight through uniform channels each having a channel axis parallel to, and a channel width transverse to, a c-axis of crystal unit cells; b) closure molecules having an elongated shape and consisting of a head moiety and a tail moiety, the tail moiety having a longitudinal extension of more than a dimension of the crystal unit cells along the c-axis and the head moiety having a lateral extension that is larger than said channel width and will prevent said head moiety from penetrating into a channel; c) a channel being terminated, in generally plug-like manner, at least at one end thereof located at a surface of the zeolite crystal by a closure molecule hose tail moiety penetrates into said chanel and whose head moiety substantially occludes said channel end while projecting over said surface; and d) an essentially linear arrangement of luminescent dye molecules enclosed within a terminated channel adjacent to at least one closure molecule and exhibiting properties related to supramolecular organization.

  本发明提供了一种负载染料的沸石材料，该材料包括a) 至少一个沸石晶体具有直通均匀的通道，每个通道的通道轴线平行于晶体单元格的c轴，通道宽度横向于晶体单元格的c轴； b) 封闭分子具有细长形状，由头部分子和尾部分子组成，尾部分子的纵向延伸大于晶体单元格沿c轴的尺寸，头部分子的横向延伸大于所述通道宽度，并将阻止所述头部分子渗入通道；c) 至少在位于沸石晶体表面的一端，通过封闭分子以类似塞子的方式终止通道，封闭分子的尾部分子穿入所述通道，而头部分子在突出所述表面的同时基本上堵塞了所述通道末端；以及 d) 发光染料分子基本上呈线性排列，封闭在邻近至少一个封闭分子的终止通道内，并表现出与超分子结构有关的特性。
• DYE LOADED ZEOLITE MATERIAL
  申请人：Universitaet Bern

  公开号：EP1335879A1

  公开（公告）日：2003-08-20
• Dye loaded zeolite material
  申请人：——

  公开号：US20040026662A1

  公开（公告）日：2004-02-12

  The present invention provides a dye loaded zeolite material comprising: a) at least one zeolite crystal having straight through uniform channels each having a channel axis parallel to, and a channel width transverse to, a c-axis of crystal unit cells; b) closure molecules having an elongated shape and consisting of a head moiety and a tail moiety, the tail moiety having a longitudinal extension of more than a dimension of the crystal unit cells along the c-axis and the head moiety having a lateral extension that is larger than said channel width and will prevent said head moiety from penetrating into a channel; c) a channel being terminated, in generally plug-like manner, at least at one end thereof located at a surface of the zeolite crystal by a closure molecule hose tail moiety penetrates into said chanel and whose head moiety substantially occludes said channel end while projecting over said surface; and d) an essentially linear arrangement of luminescent dye molecules enclosed within a terminated channel adjacent to at least one closure molecule and exhibiting properties related to supramolecular organization.
• US6932919B2
  申请人：——

  公开号：US6932919B2

  公开（公告）日：2005-08-23
• US7372012B2
  申请人：——

  公开号：US7372012B2

  公开（公告）日：2008-05-13