1,1,1,3,5,5,5-七甲基-3-三硅氧烷醇乙酸酯 | 72403-64-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 1,1,1,3,5,5,5-七甲基-3-三硅氧烷醇乙酸酯
• 英文名称: 3-acetoxy-1,1,1,3,5,5,5-heptamethyltrisiloxane
• 英文别名: Acetoxy-methyl-bis-trimethylsilyloxy-silan；1,3,3,3-tetramethyl-1-trimethylsiloxy-1-acetoxy-disiloxane；1,3,3,3-Tetramethyl-1-trimethylsilyloxy-1-acetoxy-disiloxane；[methyl-bis(trimethylsilyloxy)silyl] acetate
• CAS: 72403-64-6
• 化学式: C₉H₂₄O₄Si₃
• 分子量: 280.544
• InChiKey: PUDBXKHEIBPXCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.82
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  双三甲基硅氧基甲基硅烷 、 溶剂黄146 在 palladium diacetate 作用下， 以 氘代苯 为溶剂， 反应 8.0h， 以78%的产率得到1,1,1,3,5,5,5-七甲基-3-三硅氧烷醇乙酸酯
  参考文献：
  名称：

  钯催化甲硅烷基酯的有效途径

  摘要：

  [化学式：见正文]据报道，一步一步的高选择性催化途径可制得甲硅烷基酯。在适度的反应条件下，在Pd（OAc）2存在下，将具有Si-H官能度的市售硅烷转化为甲硅烷基或甲硅烷氧基酯。发现该方案同样适用于在一个框架中修饰多个硅中心，并以高收率得到相应的聚甲硅烷基酯。还进行了Pd（OAc）2与Pd在碳上的催化效率的比较。

  DOI：

  10.1021/ol005507t

文献信息

• An Efficient Pd-Catalyzed Route to Silyl Esters
  作者：Moni Chauhan、Bhanu P. S. Chauhan、Philip Boudjouk

  DOI：10.1021/ol005507t

  日期：2000.4.1

  highly selective catalytic route to silyl esters is reported. Commercially available silanes with Si-H functionality were converted to silyl or siloxy esters in the presence of Pd(OAc)2 under mild reaction conditions. This protocol was found to be equally applicable for the modification of multiple silicon centers in one framework and lead to the corresponding polysilyl esters in high yields. A comparison

  [化学式：见正文]据报道，一步一步的高选择性催化途径可制得甲硅烷基酯。在适度的反应条件下，在Pd（OAc）2存在下，将具有Si-H官能度的市售硅烷转化为甲硅烷基或甲硅烷氧基酯。发现该方案同样适用于在一个框架中修饰多个硅中心，并以高收率得到相应的聚甲硅烷基酯。还进行了Pd（OAc）2与Pd在碳上的催化效率的比较。
• [EN] PROCESS FOR THE PRODUCTION OF HYDROCARBYL SILYL CARBOXYLATE COMPOUNDS<br/>[FR] PROCEDE SERVANT A PREPARER DES COMPOSES D'HYDROCARBYLE SILYLE CARBOXYLATE
  申请人：SIGMA COATINGS BV

  公开号：WO2004056837A1

  公开（公告）日：2004-07-08

  A process for the production of hydrocarbyl silyl carboxylates of formula (I)is described. Wherein n represents a number of dihydrocarbylsiloxane units from 0 to 1000, by reaction of a carboxylic acid of formula (II) with a hydrocarbyl silyl compound of formula (III) the reaction being carried out in the presence of a silaphilic catalyst.

  本发明描述了一种制备式(I)的烃基硅烷羧酸酯的方法。其中n代表二烷基硅氧烷单位数，范围从0到1000，通过将式(II)的羧酸与式(III)的烃基硅化合物反应，在硅亲和催化剂的存在下进行反应。
• Process for the production of hydrocarbyl silyl carboxylate compounds
  申请人：Plehiers Mark

  公开号：US20050222446A1

  公开（公告）日：2005-10-06

  A process for the production of hydrocarbyl silyl carboxylatcs of formula (I)is described. Wherein n represents a number of dihydrocarbylsiloxane units ftom 0 to 1000, by reaction of a carboxylic acid of formula (II) with a hydrocarbyl silyl compound of formula (III) the reaction being carried out in the presence of a silaphilic catalyst.

  本文描述了一种制备式(I)的烃基硅酰羧酸盐的方法，其中n代表0至1000个二烃基硅氧烷单元的数量，通过将式(II)的羧酸与式(III)的烃基硅化合物在硅亲和催化剂存在下反应来实现。
• Synthesis, stabilization, and applications of nanoscopic siloxane–metal particle conjugates
  作者：Bhanu P.S Chauhan、Jitendra Rathore、Rajesh Sardar、Pankaj Tewari、Umar Latif

  DOI：10.1016/s0022-328x(03)00612-0

  日期：2003.11

  This account reports the new directions in the synthesis and characterization of polysiloxane-encapsulated metal nanoparticles and their applications to catalysis. These materials are prepared by sequestering metal ions with hydropolysiloxanes followed by chemical reduction to yield the corresponding zerovalent metal nanoparticles. The size and processability of such particles depends on the metal to polysiloxane ratios. Our method enables routine formation of stable nanometallic reservoirs in organic solvents avoiding particle aggregation during the storage as well as nucleation and growth process. Catalytic activity of nanoparticles vs metal complexes compares favorably for silaesterification reactions. We also demonstrate the utility of such reservoirs in grafting the surface properties of nanosized silver particles by ligand exchange reactions with thiols and phosphine oxide surfactants. (C) 2003 Elsevier B.V. All rights reserved.
• Reactivity of Ir-NSiN Complexes: Ir-Catalyzed Dehydrogenative Silylation of Carboxylic Acids
  作者：Alejandro Julián、Karin Garcés、Ralte Lalrempuia、E. A. Jaseer、Pilar García-Orduña、Francisco J. Fernández-Alvarez、Fernando J. Lahoz、Luis A. Oro

  DOI：10.1002/cctc.201701488

  日期：2018.3.7

  precursor for the preparation of Ir(NSiN) complexes (NSiN=fac‐bis‐(pyridine‐2‐yloxy)methylsilyl). The reaction of [Ir(μ‐Cl)(cod)]2 with bis‐(pyridine‐2‐yloxy)methylsilane enabled the synthesis of [Ir(H)(Cl)(NSiN)(η2‐cod)] with an uncommon η2‐coordination mode for the cod ligand. The application of Ir–NSiN species as catalysts precursors for the dehydrogenative silylation of carboxylic acids was also explored

  这项工作描述了的[Ir（μ-Cl）的（COD）]的电位从研究的结果2（COD = 1,5-环辛二烯）作为对于Ir（NSiN）络合物（NSiN =的制备金属前驱FAC -双（吡啶-2-基氧基）甲基甲硅烷基）。物[Ir（μ-Cl）的（COD）]的反应2与双- （吡啶-2-基氧基）甲基硅烷的启用的[Ir（H）（Cl）的（NSiN）（η合成2 -cod）]与罕见η 2 -coordination模式的鳕鱼配体。还研究了Ir-NSiN物种作为羧酸脱氢甲硅烷基化反应的催化剂前体的应用。这些催化研究的结果表明，辅助配体对Ir-NSiN物种的催化活性具有明显的影响。因此，而[Ir（H）（CF 3SO 3）（NSiN）（coe）]的催化活性较差，与三氟乙酸酯配体的相关配合物[Ir（H）（CF 3 CO 2）（NSiN）（coe）]被证明是高活性催化剂前体。