1,1-二氯-1,2,2,3,3,4,4,4-八氟丁烷 | 355-23-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: 1,1-二氯-1,2,2,3,3,4,4,4-八氟丁烷
• 英文名称: 1,1-dichloro-octafluoro-butane
• 英文别名: 1,1-Dichlor-octafluor-butan；1,1-Dichloro-1,2,2,3,3,4,4,4-octafluorobutane
• CAS: 355-23-7
• 化学式: C₄Cl₂F₈
• 分子量: 270.937
• InChiKey: IWGGDBDXRJTYRH-UHFFFAOYSA-N

物化性质

• 沸点：
  60-62 °C
• 密度：
  1.633 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  三氯七氟丁烷 在 三氟化锑 、 三氯化锑 作用下， 生成 1,1-二氯-1,2,2,3,3,4,4,4-八氟丁烷
  参考文献：
  名称：

  Highly Halogenated Alkanes Derived from Fluorine-containing Alcohols

  摘要：

  DOI：

  10.1021/ja01616a078

文献信息

• METHOD FOR PRODUCING TETRAFLUOROMETHANE
  申请人：SHOWA DENKO K.K.

  公开号：US20200407295A1

  公开（公告）日：2020-12-31

  A method for producing tetrafluoromethane as follows is unlikely to damage a reaction apparatus and can produce tetrafluoromethane safely, inexpensively, and stably. To a raw material liquid containing a fluorinated hydrocarbon represented by chemical formula C p H q Cl r F s (wherein p is an integer of 3 to 18, q is an integer of 0 to 3, r is an integer of 0 to 9, and s is an integer of 5 to 30) and having no carbon-carbon unsaturated bond, fluorine gas is introduced, and concurrently a reaction inducer is introduced in a gas state, giving tetrafluoromethane. The reaction inducer is reacted with fluorine gas to induce a reaction of forming tetrafluoromethane from the fluorinated hydrocarbon and the fluorine gas and is at least one reaction inducer selected from a hydrocarbon gaseous at normal temperature and pressure and hydrogen gas.

  以下是一种制备四氟甲烷的方法，该方法不太可能损坏反应设备，并且可以安全、廉价、稳定地生产四氟甲烷。将含有化学式CpHqClrFs（其中p为3至18的整数，q为0至3的整数，r为0至9的整数，s为5至30的整数）的氟化碳氢化合物作为原料液引入氟气，同时以气态引入反应诱导剂，生成四氟甲烷。反应诱导剂与氟气反应，诱导氟化碳氢化合物和氟气形成四氟甲烷的反应，并且至少包括一种在常温常压下为气态的烃类和氢气。
• FLUORINE-CONTAINING POLYMER HAVING HETEROAROMATIC RING
  申请人：Komatsu Yuzo

  公开号：US20090105400A1

  公开（公告）日：2009-04-23

  There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further a fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.

  提供了一种含氟聚合物，其具有带有杂环芳香环的离子基，并且可用作由稳定的含氟杂环芳香环化合物组成的材料，还提供了一种具有杂环芳香环的含氟聚合物，可用作上述聚合物或固化剂的起始材料。此外，还提供了一种具有杂环芳香环（如咪唑）的含氟聚合物及其聚合物盐，以及包含该聚合物、聚合物盐和纳米填料的聚合物组合物。
• PROCESS FOR PREPARING HETEROAROMATIC RING COMPOUND HAVING N-Rf GROUP
  申请人：Komatsu Yuzo

  公开号：US20100222598A1

  公开（公告）日：2010-09-02

  There is provided a preparation process in which a N—H group of a heteroaromatic ring compound having a N—H group in its ring is converted directly to a N—Rf group at a high reaction efficiency without using a catalyst. The preparation process is a process for preparing a compound comprising a heteroaromatic ring structure having a N—Rf group (—Rf is a fluorine-containing organic group) in its ring and is characterized in that the heteroaromatic ring compound having a N—H group in its ring is allowed to react with fluoroalkene in the absence of an alkali metal.

  提供了一种制备过程，其中在不使用催化剂的情况下，将具有其环中的N-H基团的杂环芳香化合物的N-H基团直接转化为高反应效率的N-Rf基团。该制备过程是制备具有其环中的N-Rf基团（-Rf是含氟有机基团）的杂环芳香环结构化合物的过程，并且其特征在于，在没有碱金属的情况下，将具有其环中的N-H基团的杂环芳香化合物与氟代烯烃发生反应。
• PROCESS FOR PREPARING END-MODIFIED VINYLIDENE FLUORIDE ELASTOMER
  申请人：Komatsu Yuzo

  公开号：US20100292408A1

  公开（公告）日：2010-11-18

  The present invention provides a preparation process for converting to a vinylidene fluoride elastomer having a group having sulfinic acid, sulfinic acid derivative, sulfonic acid or sulfonic acid derivative at one end or both ends of its trunk chain, and the preparation process provides a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR 1 R 2 —CR 3 R 4 —SO 2 H, wherein R 1 to R 4 may be the same or different and each is hydrogen atom or fluorine atom, by allowing a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR 1 R 2 —CR 3 R 4 —X 1 , wherein R 1 to R 4 are as defined above, X 1 is bromine atom or iodine atom, to react with a sulfur compound represented by the formula: (M 1 ) n H 2−n S 2 O 4 , wherein M 1 is a monovalent or divalent metal ion or ammonium ion, n is an integer of 0 to 2.

  本发明提供了一种制备过程，用于将乙烯基氟弹性体转化为一种具有末端链上具有磺酸、磺酸衍生物、磺酸或磺酸衍生物基团的乙烯基氟弹性体，该制备过程通过使具有以下末端链的乙烯基氟弹性体在一端或两端具有以下末端基团的乙烯基氟弹性体与以下公式表示的硫化合物反应而提供了一种乙烯基氟弹性体：—CR1R2—CR3R4—SO2H，其中R1到R4可能相同或不同，且每个为氢原子或氟原子，其中X1为溴原子或碘原子，其中M1为一价或二价金属离子或铵离子，n为0至2的整数。
• Expandable olefin polymer composition, expanded products made therefrom and method of making the expanded products
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0001791A2

  公开（公告）日：1979-05-16

  A thermoplastic synthetic resin such as polyethylene or ethylene-vinyl acetate copolymer resin containing 0.1 to 10 wt. % of a specific additive selected from specific classes of compounds, namely saturated higher fatty acid amidas, saturated higher aliphatic amines and complete esters of saturated higher fatty acids is found to be very suitable for production of expanded articles and can be easily formed into expanded articles with little shrinkage after expansion, free from creases on the surface or cracks on the cell walls, and having excellent characteristics such as good closed cellular characteristic, high compressive strength, low density. etc.

  一种热塑性合成树脂，如聚乙烯或乙烯-醋酸乙烯共聚物树脂，含有 0.1 至 10 wt.%的特定添加剂，这些添加剂选自特定类别的化合物，即饱和高级脂肪酸酰胺、饱和高级脂肪族胺和饱和高级脂肪酸完全酯，这种添加剂非常适合用于生产发泡制品，而且可以很容易地制成发泡制品，发泡后收缩率小，表面无皱褶，细胞壁无裂纹，具有良好的封闭细胞特性、高抗压强度、低密度等优异特性。