1-氮杂荧蒽 | 206-56-4

• 分子结构分类: 有机化合物 - 生物碱及其衍生物 - 1 -氮杂荧蒽
• 中文名称: 1-氮杂荧蒽
• 英文名称: Indeno<1,2,3ij>isoquinoline
• 英文别名: indeno[1,2,3-ij]isoquinoline；Indeno[1,2,3-ij]isochinolin；1-azafluoranthene；1-Aza-fluoranthen；2-azatetracyclo[7.6.1.05,16.010,15]hexadeca-1,3,5(16),6,8,10,12,14-octaene
• CAS: 206-56-4
• 化学式: C₁₅H₉N
• 分子量: 203.243
• InChiKey: XQNXAFHTOWJFTR-UHFFFAOYSA-N

物化性质

• 沸点：
  385.5±11.0 °C(Predicted)
• 密度：
  1.309±0.06 g/cm3(Predicted)
• 保留指数：
  2134;2104.5;348.17;348.47;346.69;347.57

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  1-氮杂荧蒽 在 chromium(VI) oxide 、 sodium amalgam 、 乙醇 、 硝酸 、 溶剂黄146 作用下， 生成 4,9-dinitro-indeno[1,2,3-ij]isoquinoline
  参考文献：
  名称：

  956. 2-氮杂荧蒽的合成与性质

  摘要：

  DOI：

  10.1039/jr9580004743
• 作为产物：
  描述：

  2,3-dihydro-indeno[1,2,3-ij]isoquinoline 在 palladium on activated charcoal 、 二氧化碳 、 甲基萘 作用下， 生成 1-氮杂荧蒽
  参考文献：
  名称：

  956. 2-氮杂荧蒽的合成与性质

  摘要：

  DOI：

  10.1039/jr9580004743

文献信息

• MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICES AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE MATERIAL
  申请人：IWAKUMA Toshihiro

  公开号：US20120319099A1

  公开（公告）日：2012-12-20

  A material for organic electroluminescence devices comprising a compound in which a heterocyclic group having nitrogen is bonded to an arylcarbazolyl group or a carbazolylalkylene group and an organic electroluminescence device comprising an anode, a cathode and an organic thin film layer comprising at least one layer and disposed between the anode and the cathode, wherein at least one layer in the organic thin film layer comprises the material for organic electroluminescence devices described above. The material can provide an organic electro-luminescence device emitting bluish light with a high purity of color. The organic electroluminescence device uses the material.

  一种用于有机电致发光器件的材料，包括一种化合物，其中含有氮的杂环基与芳基咔唑基或咔唑基烷基结合，以及包括至少一层的有机薄膜层的有机电致发光器件，该有机薄膜层位于阳极和阴极之间，并且至少一层在有机薄膜层中包含上述有机电致发光器件的材料。该材料可以提供发出高纯度蓝光的有机电致发光器件。该有机电致发光器件使用该材料。
• TRIPHENYLENE SILANE HOSTS
  申请人：Zeng Lichang

  公开号：US20130119353A1

  公开（公告）日：2013-05-16

  Novel aryl silicon and aryl germanium host materials, and in particular host materials containing triphenylene and pyrene fragments, are described. These compounds improve OLED device performance when used as hosts in the emissive layer of the OLED.

  本文描述了一些新型芳基硅和芳基锗宿主材料，尤其是含有三苯基和芘片段的宿主材料。当这些化合物被用作OLED发射层中的宿主时，可以提高OLED器件的性能。
• Material for organic electroluminescent devices and organic electroluminescent devices made by using the same
  申请人：Iwakuma Toshihiro

  公开号：US20050127823A1

  公开（公告）日：2005-06-16

  A material for electroluminescent devices which comprises a compound in which a heterocyclic group having nitrogen is bonded to carbazolyl group and an organic electroluminescent device having at least one organic thin film layer which is sandwiched between the cathode and the anode and contains the above material in at least one layer, are provided. The material can provide organic electroluminescent devices emitting bluish light with a high purity of color. The organic electroluminescence device uses the material.

  提供了一种用于电致发光装置的材料，其中包括一种化合物，其中含有氮的杂环基与卡巴索基基团结合，并且至少包含一层上述材料的有机薄膜层被夹在阴极和阳极之间的有机电致发光装置。该材料能够提供发射高纯度蓝色光的有机电致发光装置。该有机电致发光装置使用该材料。
• HOST MATERIALS FOR OLEDS
  申请人：Universal Display Corporation

  公开号：US20140117343A1

  公开（公告）日：2014-05-01

  Novel aryl silicon and aryl germanium host materials, and in particular host materials containing triphenylene and pyrene fragments, are described. These compounds improve OLED device performance when used as hosts in the emissive layer of the OLED.

  本文介绍了一种新型芳基硅和芳基锗主体材料，尤其是含有三苯基和芘片段的主体材料。当这些化合物用作OLED发射层中的主体时，可以改善OLED器件的性能。
• Derivatives of compounds containing a carbonyl group conjugated to an aromatic moiety and electrophilic methods of fabrication thereof
  申请人：International Business Machines Corporation

  公开号：EP0409003A2

  公开（公告）日：1991-01-23

  Derivatives of compounds containing a carbonyl group conjugated to an aromatic moiety and methods of fabrication thereof consisting of a thioether, an ester, an ether, a phosphate and a silylether. Electrons are supplied to the carbonyl group con­jugated to an aromatic moiety to form a reduced material. The reduced material is contacted with an electrophile which attacks and chemically combines with the carbonyl group conjugated to an aromatic moiety. The parent material can be regenerated by hydrolysis of the derivative. A silyl derivative can be selectively formed on a polyimide material surface which can act as a barrier to an RIE etch of the polyimide material. After etch the polyimide material is regenerated from the silyl derivative.

  由硫醚、酯、醚、磷酸酯和硅醚组成的含有与芳香基共轭的羰基的化合物衍生物及其制造方法。向与芳香基共轭的羰基提供电子以形成还原材料。还原型材料与亲电子体接触，亲电子体会攻击与芳香基团共轭的羰基并与之发生化学结合。母体材料可通过水解衍生物再生。硅烷基衍生物可选择性地在聚酰亚胺材料表面形成，作为聚酰亚胺材料 RIE 蚀刻的屏障。蚀刻后，聚酰亚胺材料可从硅烷衍生物中再生。

表征谱图