1-溴-4-[1,2-二溴-2-(4-溴苯基)乙基]苯 | 5405-28-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 中文名称: 1-溴-4-[1,2-二溴-2-(4-溴苯基)乙基]苯
• 英文名称: 1,2-di(4-bromophenyl)-1,2-dibromoethane
• 英文别名: 4,α,4',α'-tetrabromo-bibenzyl；4,α,4',α'-Tetrabrom-bibenzyl；α,α',4,4'-Tetrabrom-bibenzyl；4,4'-Dibrom-stilben-dibromid；1-Bromo-4-[1,2-dibromo-2-(4-bromophenyl)ethyl]benzene
• CAS: 5405-28-7
• 化学式: C₁₄H₁₀Br₄
• 分子量: 497.849
• InChiKey: QDTHKFDPVVIAGR-UHFFFAOYSA-N

物化性质

• 熔点：
  235-245 °C (decomp)
• 沸点：
  435.1±40.0 °C(Predicted)
• 密度：
  2.047±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-溴-4-[1,2-二溴-2-(4-溴苯基)乙基]苯 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 2.0h， 以84%的产率得到二(4-溴苯基)乙炔
  参考文献：
  名称：

  Synthesis of new aryl and hetaryl dibromides and diiodides, the monomers for preparation of polyarylene ethynylenes

  摘要：

  Dibromides and diiodides with quinoxaline, phenylimidazole, and hexa- or pentaphenylarylene fragments were synthesized from dihalotolans obtained from chloral. Oligoarylene ethynylenes were synthesized by the reaction of the monomers with equimolar amounts of diethynyl aromatic compounds in the presence of the Pd-II complex. Oligomers with imidazole and hexa(penta)arylbenzene cycles are soluble in amide organic solvents and their reduced viscosities do not exceed 0.09 dL g(-1).

  DOI：

  10.1007/bf01431613
• 作为产物：
  描述：

  4,4'-二溴-反-芪 在 溴 、 sodium bromide 作用下， 以 甲醇 为溶剂， 生成 1-溴-4-[1,2-二溴-2-(4-溴苯基)乙基]苯
  参考文献：
  名称：

  Electrophilic bromination of aromatic conjugated olefins. II. Mechanism of the dual-path additions in stilbene bromination. Evidence from multiple substituent effects for carbonium ion intermediates

  摘要：

  DOI：

  10.1021/jo00943a019

文献信息

• Equilibria and UV-Spectral Characteristics of BrCl, BrCl2−, and Br2Cl− Species in 1,2-Dichloroethane − Stereoselectivity and Kinetics of the Electrophilic Addition of these Species to Alkenes
  作者：Cinzia Chiappe、Federica Del Moro、Marco Raugi

  DOI：10.1002/1099-0690(200109)2001:18<3501::aid-ejoc3501>3.0.co;2-f

  日期：2001.9

  the products of bromochlorination of several aryl-substituted olefins with BrCl, with Br2 in the presence of an excess of Bu4N+Cl− (Br2/Cl−), and with BrCl in the presence of an excess of Bu4N+Cl− (BrCl/Cl−) were investigated in DCE at different temperatures. The kinetics and product distribution data for the reactions with Br2/Cl− or BrCl/Cl− are interpreted on the basis of a mechanism involving a product-

  紫外/可见分光光度测量已用于确定 25 °C 下 1,2-二氯乙烷 (DCE) 中 Bu4N+Br2Cl− 和 Bu4N+BrCl2− 物种的平衡常数和吸收光谱。来自 Br2 和 Cl2 的 BrCl 以及来自 Bu4N+Cl- 和 Cl2 的 Bu4N+Cl3- 物质的形成常数和吸收光谱也在该溶剂中在 25 °C 下测定。几种芳基取代烯烃与 BrCl、在过量 Bu4N+Cl− (Br2/Cl−) 存在下使用 Br2 以及在过量 Bu4N+Cl− 存在下使用 BrCl 溴氯化的动力学和产物(BrCl/Cl−) 在不同温度下在 DCE 中进行研究。与 Br2/Cl− 或 BrCl/Cl− 反应的动力学和产物分布数据根据涉及氯化物对烯烃-卤素（Br2 或 BrCl）π 的产物和速率决定亲核攻击的机制进行解释复杂的。与 BrCl 亲电加成相关的数据解释为 1:1 烯烃-BrCl π 络合物的初始
• 807. Quantitative aspects of radical addition. Part III. Relative rate ratios for the addition of trichloromethyl radicals to substituted stilbenes, phenantherene, and trans-β-methylstyrene
  作者：J. I. G. Cadogan、P. W. Inward

  DOI：10.1039/jr9620004170

  日期：——
• Synthesis of new aryl and hetaryl dibromides and diiodides, the monomers for preparation of polyarylene ethynylenes
  作者：A. L. Rusanov、M. L. Keshtov、M. M. Begretov、I. A. Khotina、A. K. Mikitaev

  DOI：10.1007/bf01431613

  日期：1996.5

  Dibromides and diiodides with quinoxaline, phenylimidazole, and hexa- or pentaphenylarylene fragments were synthesized from dihalotolans obtained from chloral. Oligoarylene ethynylenes were synthesized by the reaction of the monomers with equimolar amounts of diethynyl aromatic compounds in the presence of the Pd-II complex. Oligomers with imidazole and hexa(penta)arylbenzene cycles are soluble in amide organic solvents and their reduced viscosities do not exceed 0.09 dL g(-1).
• Steric structure of some 1,2-diaryl-substituted ethanes
  作者：B. A. Arbuzov、V. E. Kataev、A. P. Timosheva、S. G. Vul'fson、A. N. Vereshchagin

  DOI：10.1007/bf00953852

  日期：1987.1
• Wislicenus,W.; Elvert, Chemische Berichte, 1908, vol. 41, p. 4131
  作者：Wislicenus,W.、Elvert

  DOI：——

  日期：——