1-羟基-2-萘甲酸铵 | 464874-99-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1-羟基-2-萘甲酸铵
• 英文名称: ammonium 1-hydroxy-2-naphthoate
• 英文别名: azanium;2-carboxynaphthalen-1-olate
• CAS: 464874-99-5
• 化学式: C₁₁H₇O₃*H₄N
• 分子量: 205.213
• InChiKey: BRSZOBVATMATPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.99
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  氯化镥(III) 、 1-羟基-2-萘甲酸铵 、 水 以 水 为溶剂， 生成
  参考文献：
  名称：

  摘要：

  Complexes of lanthanide(III) (La-Lu) and Y(III) with 1-hydroxy-2-naphthoic acid were obtained as crystalline compounds with a general formula Ln[C10H6(OH)COO](3).nH(2)O: n=6 for La-Tm and Y, n=2 for Yb and n=0 for Lu. IR spectra of the prepared complexes were recorded, and their thermal decomposition in air were investigated. Spectroscopic data suggest that in the coordination of metal-organic ligand only oxygen atoms from the carboxylate group take part. When heated, the complexes decompose to the oxides Ln(2)O(3), CeO2, Pr6O11 and Tb4O7 with intermediate formation of Ln(C11H7O3)(C11H6O3).

  DOI：

  10.1023/a:1016198724272

文献信息

• [EN] NOVEL PHARMACEUTICAL<br/>[FR] NOUVEAU PRODUIT PHARMACEUTIQUE
  申请人：SMITHKLINE BEECHAM PLC

  公开号：WO2003053963A1

  公开（公告）日：2003-07-03

  A 5-[4-[2-(N-methyl-N-(2-pyridyl)amino)ethoxy]benzyl]thiazolidine-2,4-dione 1-hydroxy-2-naphthoic acid salt whose IR, Raman, X-ray powder diffraction and Solid State13C NMR spectral characteristics are disclosed.
• ——
  作者：A. Kula

  DOI：10.1023/a:1016198724272

  日期：——

  Complexes of lanthanide(III) (La-Lu) and Y(III) with 1-hydroxy-2-naphthoic acid were obtained as crystalline compounds with a general formula Ln[C10H6(OH)COO](3).nH(2)O: n=6 for La-Tm and Y, n=2 for Yb and n=0 for Lu. IR spectra of the prepared complexes were recorded, and their thermal decomposition in air were investigated. Spectroscopic data suggest that in the coordination of metal-organic ligand only oxygen atoms from the carboxylate group take part. When heated, the complexes decompose to the oxides Ln(2)O(3), CeO2, Pr6O11 and Tb4O7 with intermediate formation of Ln(C11H7O3)(C11H6O3).