1-羟基-N-(2-十四烷氧基苯)-2-萘磺酰胺 | 39163-92-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1-羟基-N-(2-十四烷氧基苯)-2-萘磺酰胺
• 中文别名: 1-羟基-N-(2-十四氧基苯基)-2-萘羧酰胺
• 英文名称: 1-Hydroxyl-N-(2-n-tetradecyloxyphenyl)-2-naphthamide
• 英文别名: 1-hydroxy-N-[2-(tetradecyloxy)phenyl]naphthalene-2-carboxamide；1-hydroxy-N-(2-tetradecoxyphenyl)naphthalene-2-carboxamide
• CAS: 39163-92-3
• 化学式: C₃₁H₄₁NO₃
• 分子量: 475.671
• InChiKey: PDNBNYWQDIQNLS-UHFFFAOYSA-N

物化性质

• 沸点：
  575.38°C (rough estimate)
• 密度：
  1.0728 (rough estimate)
• 稳定性/保质期：
  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  35
• 可旋转键数：
  16
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  58.6
• 氢给体数：
  2
• 氢受体数：
  3

安全信息

• 安全说明：
  S24/25
• 海关编码：
  2924299090

SDS

Name:	1-Hydroxy-N-(2-tetradecyloxyphenyl)-2- naphthalenecarboxamide 98% Material Safety Data Sheet
Synonym:	2-Naphthalenecarboxamide, 1-hydroxy-N-2-(tetradecy
CAS:	39163-92-3

Section 1 - Chemical Product MSDS Name:1-Hydroxy-N-(2-tetradecyloxyphenyl)-2- naphthalenecarboxamide 98% Material Safety Data Sheet
Synonym:2-Naphthalenecarboxamide, 1-hydroxy-N-2-(tetradecy

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
39163-92-3	1-Hydroxy-N-(2-tetradecyloxyphenyl)-2-	98	254-328-6

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

---

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 39163-92-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: beige
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C31H41NO3
Molecular Weight: 475.66

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 39163-92-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Hydroxy-N-(2-tetradecyloxyphenyl)-2-naphthalenecarboxamide - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 39163-92-3: No information available.
Canada
CAS# 39163-92-3 is listed on Canada's NDSL List.
CAS# 39163-92-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 39163-92-3 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  、 1-羟基-N-(2-十四烷氧基苯)-2-萘磺酰胺 在 四甲基胍 作用下， 生成 4-(benzotriazol-1-yl)-1-hydroxy-N-(2-tetradecoxyphenyl)naphthalene-2-carboxamide
  参考文献：
  名称：

  Bergthaller, Peter, Angewandte Chemie, 1991, vol. 103, # 12, p. 1742 - 1743

  摘要：

  DOI：
• 作为产物：
  描述：

  1-羟基-2-萘甲酸苯酯 、 2-十四烷氧基苯胺 生成 1-羟基-N-(2-十四烷氧基苯)-2-萘磺酰胺
  参考文献：
  名称：

  Bergthaller, Peter, Angewandte Chemie, 1991, vol. 103, # 12, p. 1742 - 1743

  摘要：

  DOI：

文献信息

• Silver halide color light sensitive material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04734357A1

  公开（公告）日：1988-03-29

  A silver halide color light-sensitive material is described, which is increased in sensitivity, is adapted to form an image of high contrast, or is accelerated in development by incorporating a small amount of a specific compound which imagewise releases a foggant or a development accelerator. This compound is represented by the formula: Coup-(TIME).sub.n -FA (wherein Coup represents a coupler radical capable of undergoing a coupling reaction with an oxidized product of an aromatic primary amine developing agent; TIME represents a timing group which is eliminated from Coup by the coupling reaction and, thereafter, releases FA; n is 0 or 1; and FA represents a group which is eliminated from Coup in the coupling reaction when n is 0, whereas FA is released from TIME when n is 1. The FA has adsorption properties with respect to silver halide grains and also has a substantial fogging action with respect to the silver halide grains).

  本文描述了一种银卤化物彩色感光材料，通过加入少量的特定化合物，可以增加其灵敏度、适用于高对比度的图像形成，或者加速显影过程。该化合物的化学式为：Coup-(TIME).sub.n -FA，其中Coup代表一个偶联试剂基团，能够与芳香族一级胺显影剂的氧化产物发生偶联反应；TIME代表一个计时基团，通过偶联反应从Coup中消除，并随后释放FA；n为0或1；FA代表在n为0时从Coup中消除的基团，而在n为1时从TIME中释放的基团。FA对银卤化物颗粒具有吸附特性，并且对银卤化物颗粒具有显著的起雾作用。
• Silver halide color photographic light-sensitive material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04628024A1

  公开（公告）日：1986-12-09

  A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer and a compound represented by the following general formula (I): ##STR1## wherein COUP represents a coupler residue capable of being subjected to a coupling reaction with an oxidation product of an aromatic primary amine developing agent; TIME represents a timing group which is released upon the coupling reaction and subsequently releases ##STR2## Z represents a monocyclic or condensed heterocyclic ring consisting of a nitrogen atom and a carbon atom; L represents a divalent linking group; R.sup.1 represents a hydrogen atom or an alkoxycarbonyl group; R.sup.2 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a thioacyl group or a thiocarbamoyl group; R.sup.3 represents a hydrogen atom; R.sup.2 and R.sup.3 may be bonded each other to form a hydrazone structure; a part of L and R.sup.1 may be bonded each other to form a hydrazone structure; and n represents 0 or 1. The silver halide color photographic light-sensitive material containing the compound capable of imagewise releasing a fogging agent represented by the general formula (I) is improved in stability during preservation and has a high contrast and sensitivity. A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.

  一种银卤化物彩色摄影感光材料，包括支撑物上的银卤化物乳液层和下列一般式（I）所代表的化合物：##STR1##其中COUP代表能够与芳香族原始胺显影剂的氧化产物进行偶联反应的偶联剩基；TIME代表在偶联反应中释放并随后释放##STR2##的定时组；Z代表由一个氮原子和一个碳原子组成的单环或缩合杂环；L代表二价连结基；R.sup.1代表氢原子或烷氧羰基基团；R.sup.2代表氢原子、烷基、芳基、杂环基、酰基、磺酰基、烷氧羰基基团、氨基甲酰基基团、磺酰胺基基团、硫代酰基或硫代氨基甲酰基基团；R.sup.3代表氢原子；R.sup.2和R.sup.3可以结合形成肼酮结构；L和R.sup.1的一部分可以结合形成肼酮结构；n代表0或1。含有能够像图像地释放由一般式（I）所代表的雾化剂的化合物的银卤化物彩色摄影感光材料在保存期间具有较高的稳定性、对比度和灵敏度。还公开了使用该银卤化物彩色摄影感光材料形成彩色图像的方法。
• Silver halide color light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0118087A2

  公开（公告）日：1984-09-12

  A silver halide color light-sensitive material is described, which is increased in sensitivity, is adapted to form an image of high contrast, or is accelerated in development by incorporating a small amount of a specific compound which imagewise releases a foggant or a development accelerator. This compound is represented by the formula: Coup-(TIME)n-FA (wherein Coup represents a coupler radical capable of undergoing a coupling reaction with an oxidized product of an aromatic primary amine developing agent; TIME represents a timing group which is eliminated from Coup by the coupling reaction and, thereafter, releases FA; n is 0 or 1; and FA represents a group which is eliminated from Coup in the coupling reaction when n is 0, whereas FA is released from TIME when n is 1. The FA has adsorption properties with respect to silver halide grains and also has a substantial fogging action with respect to the silver halide grains).

  描述了一种卤化银彩色感光材料，通过加入少量特定的化合物，在图像上释放出雾剂或显影加速剂，从而提高感光度，形成高对比度的图像，或加速显影。这种化合物的化学式如下Coup-(TIME)n-FA （其中 Coup 代表能与芳香族伯胺显影剂的氧化产物发生偶联反应的偶联基；TIME 代表通过偶联反应从 Coup 中消除并随后释放出 FA 的定时基团；n 为 0 或 1；FA 代表当 n 为 0 时在偶联反应中从 Coup 中消除的基团，而当 n 为 1 时从 TIME 中释放出 FA。）
• US4066403A
  申请人：——

  公开号：US4066403A

  公开（公告）日：1978-01-03
• US4199363A
  申请人：——

  公开号：US4199363A

  公开（公告）日：1980-04-22