1-萘磺酸,3-重氮基-3,4-二氢-4-羰基-,苯基酯 | 110673-14-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1-萘磺酸,3-重氮基-3,4-二氢-4-羰基-,苯基酯
• 英文名称: phenyl naphthoquinone-1,2-(diazide-2)-4-sulfonate
• 英文别名: phenyl (3E)-3-diazo-4-oxonaphthalene-1-sulfonate
• CAS: 110673-14-8
• 化学式: C₁₆H₁₀N₂O₄S
• 分子量: 326.332
• InChiKey: UAZVBWMIZXRKHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-萘磺酸,3-重氮基-3,4-二氢-4-羰基-,苯基酯 以 solid matrix 为溶剂， 生成
  参考文献：
  名称：

  1,2-萘醌二叠氮化物-（2）-n-磺酸衍生物的合成及光化学

  摘要：

  1,2-萘醌二叠氮化物-（2）-6-和-7-磺酸酯（7c，7d）首次从1-萘胺-6-和-7-磺酸（1c ，1d）分别通过Bucherer反应，亚硝化，还原，重氮化，磺酰氯，酯化。用这种方法不能成功地合成相应的8-磺酸酯73。在光解过程中，1,2-萘醌二叠氮化物-（2）-6-和-7-磺酸苯基酯（7c，7d）以已知的5相同的方式形成相应的（苯氧基磺酰基）-茚满羧酸（10c，10d）。 -磺酸衍生物10b。与这些异构体不同的是，对4-磺酸酯进行光解在图7a中，另外发生光化学诱导的酯裂解（λ＜320nm）。

  DOI：

  10.1016/s0040-4020(01)85611-8
• 作为产物：
  描述：

  1,2-萘氧二唑-4-磺酸 生成 1-萘磺酸,3-重氮基-3,4-二氢-4-羰基-,苯基酯
  参考文献：
  名称：

  ZAKRZEWSKI, ANDRZJ;KARTAWIK, MARIAN;PLACHOSKA, TERESA;GOLATA, EDWARD

  摘要：

  DOI：

文献信息

• Single Pot Process For The Preparation Of Diazonaphthoquinonesulfonyl Ester
  申请人：Reddy Venkat Vummadi

  公开号：US20070049742A1

  公开（公告）日：2007-03-01

  The present invention provides a single pot process for the preparation of diazonaphthoquinonesulfonyl ester, a useful organic material for micro electronic and dye industry. This study pertains to the one pot preparation of diazonaphthoquinonesulfonyl esters using the corresponding diazonaphthoquinine sulfonic acid or its sodium salt, diphosgene or triphosgene, variety of hydroxy compounds and tertiary organic base in an organic solvent medium.

  本发明提供了一种单锅法制备二氮基萘醌磺酰酯的方法，这是微电子和染料工业中有用的有机材料。本研究涉及使用相应的二氮基萘醌磺酸或其钠盐、二膦酰氯或三膦酰氯、各种羟基化合物和三级有机碱在有机溶剂介质中进行单锅制备二氮基萘醌磺酰酯的方法。
• Reduction processes in the fast atom bombardment mass spectrometry of sulfonyl esters of diazonaphthalenones
  作者：James N. Kyranos、Bertrand M. Du Sorbier、John Wronka、Paul Vouros、Daniel P. Kirby

  DOI：10.1002/oms.1210230604

  日期：1988.6

  AbstractOrthoquinone diazides, which are widely used in microlithography, have attracted considerable attention, especially in terms of their application in the production of high‐contrast resists. Previous electron impact mass spectrometric results have confirmed that the primary fragmentation process of these compounds is the elimination of N2 to form an indenoketene ion. This is analogous to the photodecomposition pathway which makes them effective in the lithographic process. Those results also revealed the occurrence of an alternative process, which involves a two‐hydrogen reduction of the intermediate species formed prior to conversion to the ketene. The present study investigates the behaviour of the orthoquinone diazides when there is an abundance of protons available to form the reduction product. Several different types of diazonaphthalenone sulfonyl esters, ranging in complexity from the monosubstituted phenol esters to disubstituted dihydroxybenzophenones, were examined using fast atom bombardment mass spectrometry. Although reduction was the primary process in the hydrogen‐rich matrices, the extent of reduction was characteristic of the particular isomer as well as the matrix used.
• Baumbach, B.; Bendig, J.; Nagel, T., Journal fur praktische Chemie (Leipzig 1954), 1991, vol. 333, # 4, p. 625 - 635
  作者：Baumbach, B.、Bendig, J.、Nagel, T.、Dubsky, B.

  DOI：——

  日期：——
• WO2007/26374
  申请人：——

  公开号：——

  公开（公告）日：——