2,3,6,7-四甲基萘-1,4-二羧酸 | 925890-17-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2,3,6,7-四甲基萘-1,4-二羧酸
• 英文名称: 2,3,6,7-Tetramethylnaphthalene-1,4-dicarboxylic acid
• CAS: 925890-17-1
• 化学式: C₁₆H₁₆O₄
• 分子量: 272.29
• InChiKey: OAAOTXWEJJTSPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Polyisophthalate and copolymers thereof having reduced cyclic dimer content, and a process for making the same
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0105016A1

  公开（公告）日：1984-04-04

  A polyisophthalate such as poly(ethylene isophthalate) and copolymers thereof having high intrinsic viscosities as well as reduced ring dimer of ethylene isophthalate, and a process for making the same. A protonic acid catalyst is utilized along with intrinsic viscosity modifying agents during preparation of the polyisophthalate. The polymers produced have very high clarity, improved oxygen and carbon dioxide barrier resistance, high glass transition temperatures, as well as increased molecular weights. They are thus suitable for use as materials in packaging or forming containers, such as bottles.

  一种聚间苯二甲酸酯，如聚（间苯二甲酸乙烯酯）及其共聚物，具有较高的固有粘度和间苯二甲酸乙烯酯的还原环二聚体，以及制造这种聚间苯二甲酸酯的工艺。在制备聚间苯二甲酸乙二醇酯的过程中，使用了质子酸催化剂和固有粘度调节剂。生产出的聚合物具有极高的透明度、更好的氧气和二氧化碳阻隔性、较高的玻璃化温度以及更高的分子量。因此，它们适合用作包装或成型容器（如瓶子）的材料。
• Polyisophthalates and copolymers thereof having high barrier properties
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0105824A1

  公开（公告）日：1984-04-18

  Polyisophthalates, for example, poly(ethyleneisophtha- late), or copolymers thereof, have low glass transition temperatures, even lower than poly(ethylene terephthalate). Unexpectedly, such polyisophthalates have very good barrier properties with regard to oxygen and carbon dioxide penetration. The polyisophthalates can be utilized as packaging materials, for example as films or containers such as bottles for beverages such as intoxicating beverages such as beer, and the like.

  聚异酞酸酯，例如聚（乙烯-异酞酸酯）或其共聚物的玻璃化温度较低，甚至低于聚（对苯二甲酸乙二醇酯）。令人意想不到的是，这种聚异酞酸酯对氧气和二氧化碳的渗透具有很好的阻隔性能。聚间苯二甲酸盐可用作包装材料，例如薄膜或容器，如饮料瓶，如啤酒等烈性饮料。
• Multi-layer polyisophthalate and polyterephthalate articles and process therefor
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0105825A2

  公开（公告）日：1984-04-18

  A multi-layer polyester article, and particularly a beverage bottle having good oxygen and carbon dioxide permeability resistance. At least one layer of the article is made from polyisophthalate and copolymers thereof. The multi-layer articles find particular use as packaging materials, films, and molded containers such as for alcoholic beverages. Various colorants can be added to either one or more of the layers to impart a desired color to the article.

  一种多层聚酯物品，特别是一种具有良好抗氧气和二氧化碳渗透性的饮料瓶。该制品至少有一层是由聚对苯二甲酸酯及其共聚物制成的。这种多层制品可用作包装材料、薄膜和模制容器，如酒精饮料。可在一层或多层中加入各种着色剂，使物品呈现出所需的颜色。
• Production of metal-organic frameworks
  申请人：Commonwealth Scientific and Industrial Research Organisation

  公开号：US10010860B2

  公开（公告）日：2018-07-03

  An apparatus for producing metal organic frameworks, comprising: a tubular flow reactor comprising a tubular body into which, in use, precursor compounds which form the metal organic framework are fed and flow, said tubular body including at least one annular loop.

  一种用于生产金属有机框架的设备，包括：一个管状流动反应器，该反应器由一个管状体组成，使用时，形成金属有机框架的前体化合物被送入该管状体中并在其中流动，所述管状体包括至少一个环形回路。
• Doped metal organic frameworks for reversible H2 storage at ambient temperature
  申请人：Goddard William A.

  公开号：US20090005243A1

  公开（公告）日：2009-01-01

  Metal-organic frameworks (MOFs) are provided. An exemplary MOF includes a plurality of metal clusters, at least one linking ligand, and at least one dopant. Doped MOFs according to embodiments of the present invention have significantly increased H2 uptake capacity, and some embodiments meet the 2010 DOE H2 storage target of 6 wt % at a temperature ranging from −30 to 80° C. and a pressure less than or equal to 100 bar.