2,4,6-三氧代-1,3,5-三嗪-1,3,5(2H,4H,6H)-三丙腈 | 2904-28-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 2,4,6-三氧代-1,3,5-三嗪-1,3,5(2H,4H,6H)-三丙腈
• 英文名称: tris(2-cyanoethyl) isocyanurate
• 英文别名: 1,3,5-tris(2-cyanoethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione；Tris-(β-cyano-ethyl)-isocyanurat；Tri-(2-cyano-aethyl)-isocyanurat；Tris-(2-cyano-ethyl)-isocyanurat；3,3',3''-(2,4,6-trioxo-[1,3,5]triazinane-1,3,5-triyl)-tris-propionitrile；2,4,6-Trioxo-1,3,5-tris-β-cyanoethyl-perhydro-1,3,5-triazin；1,3,5-Tris-(2-cyan-ethyl)-2,4,6-trioxo-hexahydro-s-triazin；Isocyanursaeure-tris-<2-cyan-ethylester>；Tris-(β-cyano-aethyl)-isocyanurat；3,3',3''-(2,4,6-Trioxo-1,3,5-triazinane-1,3,5-triyl)tripropanenitrile；3-[3,5-bis(2-cyanoethyl)-2,4,6-trioxo-1,3,5-triazinan-1-yl]propanenitrile
• CAS: 2904-28-1
• 化学式: C₁₂H₁₂N₆O₃
• mdl: MFCD00224436
• 分子量: 288.266
• InChiKey: UUBUCLKOQKIWKA-UHFFFAOYSA-N

物化性质

• 熔点：
  224-225 °C(Solv: acetonitrile (75-05-8))
• 沸点：
  610.1±50.0 °C(Predicted)
• 密度：
  1.362±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  132
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 海关编码：
  2933699090
• 储存条件：
  存储条件：室温、密封、干燥

反应信息

• 作为反应物：
  描述：

  2,4,6-三氧代-1,3,5-三嗪-1,3,5(2H,4H,6H)-三丙腈 、 盐酸 以99%的产率得到
  参考文献：
  名称：

  KUCHARSKI, M.;ROKASZEWSKI, E., ZESZ. NAUK. PRZESZOW. CHEM., 1984, N 1, 49-54

  摘要：

  DOI：
• 作为产物：
  描述：

  丙烯腈 、 氰尿酸 在 四丁基溴化铵 作用下， 以 正庚烷 为溶剂， 反应 9.0h， 以95.76%的产率得到2,4,6-三氧代-1,3,5-三嗪-1,3,5(2H,4H,6H)-三丙腈
  参考文献：
  名称：

  一种固化剂中间体N,N,N-三(3’-氰丙基)-1,3,5-三嗪的制备方法

  摘要：

  本发明提供了一种固化剂中间体N,N,N‑三(3’‑氰丙基)‑1,3,5‑三嗪的制备方法，以氰尿酸、丙烯腈为原料，在催化剂和溶剂存在的条件下反应制得固化剂中间体N,N,N‑三(3’‑氰丙基)‑1,3,5‑三嗪。本发明合成固化剂中间体N,N,N‑三(3’‑氰丙基)‑1,3,5‑三嗪，分离提纯过程简单，反应时间短，产品收率可以达到94％以上，产品纯度较高，能耗少，环境污染小，成本低，是实现工业化生产的较理想的工艺。

  公开号：

  CN112707872A

文献信息

• Flame-retardant polyester film and processed product including the same
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1441001A2

  公开（公告）日：2004-07-28

  The present invention is a flame-retardant polyester film including resin layers laminated on both surfaces of a polyester film, wherein the resin layer satisfies 15 ≤ (Wc1 - Wc2)/Wc0 × 100 ≤ 99 (where Wc0 represents the weight of the resin layer, Wc1 represents the weight of the resin layer after the temperature thereof is raised from 25°C to 600°C in air, and Wc2 represents the weight of the resin layer after the temperature thereof is raised from 25°C to 800°C in air), and has a non-flammable'gas generating rate of 3 to 40 percent over the range of 180°C to 450°C. The present invention provides a flame-retardant polyester film having an excellent flame retardancy, and adhesive tapes, flexible printed circuits, a membrane switch, a film heater, and a flat cable, each including the flame-retardant polyester film.

  本发明是一种阻燃聚酯薄膜，包括层压在聚酯薄膜两面的树脂层，其中树脂层满足 15 ≤ (Wc1 - Wc2)/Wc0 × 100 ≤ 99（其中 Wc0 表示树脂层的重量、Wc1 表示树脂层在空气中的温度从 25℃升至 600℃后的重量，Wc2 表示树脂层在空气中的温度从 25℃升至 800℃后的重量），并且在 180℃至 450℃的范围内具有 3%至 40%的不可燃'气体产生率。本发明提供了一种阻燃性极佳的阻燃聚酯薄膜，以及包括该阻燃聚酯薄膜的胶带、柔性印刷电路、薄膜开关、薄膜加热器和扁平电缆。
• Flame resistant polyamide and/or polyester composition, and process for manufacture thereof
  申请人：Campine N.V.

  公开号：EP1676877A1

  公开（公告）日：2006-07-05

  Process for manufacturing a flame retarding masterbatch comprising a polyamide (PA) and/or polyester resin and a melamine cyanurate (MeCy), which process comprises the steps of feeding at least a polyamide and/or polyester resin and a melamine cyanurate to a suitable continuous kneading and extruding apparatus, melt-kneading the masterbatch components in the apparatus, and granulating the melt-kneaded masterbatch material, wherein feeding of the components to the apparatus is performed by at least a first inlet and a second inlet, positioned downstream from the first, whereby from 0-100 pbw of the total mass of PA and from 0-100 pbw of the total mass of MeCy are fed to the apparatus through the first top inlet, the remaining being fed to the apparatus through the second top inlet.

  由聚酰胺（PA）和/或聚酯树脂和三聚氰胺氰脲酸酯（MeCy）组成的阻燃母料的制造工艺，该工艺包括以下步骤：将至少一种聚酰胺和/或聚酯树脂和一种三聚氰胺氰脲酸酯喂入合适的连续捏合和挤出设备，在设备中熔融捏合母料组分，并将熔融捏合母料造粒、将熔融捏合的母粒材料造粒，其中向设备中喂入组分的过程至少由一个第一进料口和一个第二进料口进行，它们位于第一进料口的下游，其中 PA 总质量的 0-100 pbw 和 MeCy 总质量的 0-100 pbw 通过第一顶部进料口喂入设备，其余的通过第二顶部进料口喂入设备。
• Laminated polyester film, flame-retardant polyester film thereof copper-clad laminated plate and circuit substrate
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1764214A2

  公开（公告）日：2007-03-21

  A laminated polyester film, with excellent adhesive properties for use in a laminating material, is a film in which a resin layer including a polyester resin and a oxazoline-based cross-linking agent is laminated on at least one side surface of polyester film, diethylene glycol accounts for 40 mole% or more of all diol components constituting the polyester resin and the mass ratio of the polyester resin to the oxazoline-based cross-linking agent resin layer is within a range of 20/80 to 80/20. The film may form part of a flame-retardant polyester film in which a polyimide-including layer is laminated on both sides of the laminated polyester film. The flame-retardant polyester film may be used in a copper-clad laminated plate, which, in turn, may be used in a circuit substrate.

  一种层压聚酯薄膜具有优异的粘合性能，可用于层压材料，它是在聚酯薄膜的至少一面表面层压包括聚酯树脂和噁唑啉基交联剂的树脂层，二甘醇在构成聚酯树脂的所有二元醇成分中占 40 摩尔%或以上，聚酯树脂与噁唑啉基交联剂树脂层的质量比在 20/80 至 80/20 之间。该薄膜可构成阻燃聚酯薄膜的一部分，其中包括聚酰亚胺层层压在层压聚酯薄膜的两面。阻燃聚酯薄膜可用于覆铜板，而覆铜板又可用于电路基板。
• OXETANE-CONTAINING RESIN, AND ADHESIVE AGENT AND RESIST AGENT EACH USING THE SAME
  申请人：Toyo Boseki Kabushiki Kaisha

  公开号：EP2090610A1

  公开（公告）日：2009-08-19

  [Object] To provide a thermosetting resin used for the manufacture of layered products for fibrous use, electrical products and automobile parts or, particularly, used for multilayered circuit board and flat cables, being suitable for a latent thermosetting adhesive which shows, upon adhesion, the fluidity necessary for the adhesion but quickly hardens by heat or light and also being excellent in resistance to heat upon soldering; to provide a resin expressing an excellent flame-retarding property in spite of non-use of halogen, and expressing latent hardening properties to quickly harden by heat and light; and to provide an adhesive and a resist agent comprising the same. [Constitution] An oxetane-containing resin which is characterized in having a number-average molecular weight of not less than 2,000, having one or more bonding group (s) selected from ester bond, urethane bond, amide bond and ether bond in its main chain and containing 100 to 10,000 equivalents/ton of oxetane group, 300 to 5, 000 equivalents/ton of carboxyl group, not less than 0.1% by weight of phosphorus atom and 100 to 2,000 equivalents/ton of ethylenic unsaturated double bond in a molecule in a molecule. An adhesive and a resist agent obtained from the same.

  [目的] 提供一种热固性树脂，用于制造纤维用分层产品、电气产品和汽车零件，特别是用于多层电路板和扁平电缆，适用于潜伏热固性粘合剂，这种粘合剂在粘合时具有粘合所需的流动性，但受热或受光后可迅速硬化，而且在焊接时具有优异的耐热性；提供一种在不使用卤素的情况下仍具有优异阻燃性能的树脂，该树脂还具有遇热和遇光迅速硬化的潜伏硬化性能；以及提供包含该树脂的粘合剂和抗蚀剂。 [构成]一种含氧杂环丁烷树脂，其特征在于具有不小于 2 000 的数均分子量，主链上具有一个或多个键基（s），这些键基可从酯键、氨基甲酸酯键、酰胺键和醚键中选择，并含有 100 至 10 000 当量/吨的氧杂环丁烷基团、300 至 5 000 当量/吨的羧基、不小于 0.1%（重量百分比）的磷原子以及分子中 100 至 2,000 当量/吨的乙烯不饱和双键。一种粘合剂和由其制成的抗蚀剂。
• METHOD FOR PRODUCING POLYAMIDE RESIN
  申请人：Toray Industries, Inc.

  公开号：EP2402385A1

  公开（公告）日：2012-01-04

  A method for producing a polyamide resin characterized by comprising thermally polycondension of tetramethylene diamine and either an aliphatic dicarboxylic acid having 7 or more carbon atoms or a salt thereof, and then being melt-polymerized at a temperature equal to or higher than the melting point thereof until the relative viscosity of a 0.01 g/ml solution thereof in 98% sulfuric acid solution with a 0.01 g/ml content at 25 °C becomes 2.2-5.0.

  一种生产聚酰胺树脂的方法，其特征在于包括将四亚甲基二胺与具有 7 个或更多碳原子的脂肪族二羧酸或其盐进行热缩聚，然后在等于或高于其熔点的温度下进行熔融聚合，直至其在 98%的硫酸溶液中 0.01 克/毫升含量的溶液在 25℃时的相对粘度变为 2.2-5.0。

表征谱图