水合磷酸钇 | 34054-55-2

• 物质功能分类: 无机化工 - 无机盐 - 磷化物、金属的磷酸、偏磷酸、次磷酸和焦磷酸盐
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 中文名称: 水合磷酸钇
• 中文别名: 磷酸钇(III)水合物
• 英文名称: yttrium phosphate dihydrate
• 英文别名: Yttrium(III) phosphate hydrate；yttrium(3+);phosphate;hydrate
• CAS: 34054-55-2
• 化学式: 2H₂O*O₄P*Y
• 分子量: 219.908
• InChiKey: ICIYNWVOHBLOFM-UHFFFAOYSA-K

物化性质

• 稳定性/保质期：
  遵照规定使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  -3.65
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.2
• 氢给体数：
  1
• 氢受体数：
  5

安全信息

• 储存条件：
  存放于阴凉干燥处。

SDS

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Section 1: Product Identification
Chemical Name: Yttrium (III) phosphate hydrate (99.99%-Y) (REO) PURATREM
CAS Registry Number: 34054-55-2
Formula: YPO4.XH2O
EINECS Number: none
Chemical Family: metal phosphate compound
Synonym: Yttrium phosphate tetrahydrate

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 34054-55-2 100% no data no data

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Section 3: Hazards Identification
Emergency Overview: May be irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure: Inhalation, skin, eyes
Eye Contact: May cause slight to mild irritation of the eyes.
Skin Contact: May cause slight to mild irritation of the skin.
Inhalation: May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion: No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects: May be irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Chronic Health Affects: No information on long-term chronic effects.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: none required
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

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SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

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SECTION 7: Handling and Storage
Handling and Storage: Keep container tightly closed. Store in a cool, dry place.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: white powder
Molecular Weight: 183.88
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble

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SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: active metals
Decomposition Products: none

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SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data

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SECTION 12: Ecological Information
Ecological Information: No information available

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

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SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

简介

水合磷酸钇是一种具有矿物针磷钇铒矿（churchite）晶体结构的磷酸钇。这类稀土磷酸盐因其良好的化学稳定性和热稳定性以及大折射率和低声子能量等优点，广泛用作发光材料的基质。

应用

在这些稀土磷酸盐中，钇离子4f轨道上的电子处于全空状态，不会产生f-f跃迁，从而避免了无辐射跃迁额外消耗能量的情况。因此，磷酸钇常作为发光基质首选材料，并且是目前稀土材料化学领域研究的热点之一。

反应信息

• 作为反应物：
  描述：

  水合磷酸钇 生成 yttrium phosphate
  参考文献：
  名称：

  Churchite型REPO4·2H2O(RE = Y, Gd, Dy)纳米晶的合成与结构研究

  摘要：

  Churchite型REPO 4 ·2H 2 O（RE = Gd to Lu & Y）材料是稀土磷酸盐家族的亚稳态多晶型物，采用二维层状结构，水分子占据层间区域。与稀土磷酸盐家族的其他多晶型物相比，Churchite 材料的合成和结构特性尚未得到充分研究，本文旨在通过对 Churchite 型 REPO 4进行详细的合成和结构研究来解决这一问题·2H 2 O (RE = Y, Gd, Dy)材料。相纯 REPO 4 ·2H 2O 材料通过沉淀法在室温（~22°C）至50°C的温度范围内合成。使用光学显微镜、SEM 和 TEM 确定这些材料的微观结构。使用光学显微镜和 SEM 进行的微观结构分析表明，REPO 4 ·2H 2O 材料看起来像针状颗粒，但实际上是单晶纳米棒的聚集体，如 TEM 分析所示。使用 TGA、DSC 和非原位 XRD 确定温度对其结构的影响。TGA-DSC 结果表明，层间水通过

  DOI：

  10.1016/j.jssc.2022.123150
• 作为产物：
  描述：

  磷酸 、 氯化钇 在 HCl 、 NH₄OH 作用下， 以 水 为溶剂， 生成 水合磷酸钇
  参考文献：
  名称：

  Mechanochemical Changes of Weinschenkite-Type RPO4.2H2O (R = Dy, Y, Er, or Yb) by Grinding and Thermal Reactions of the Ground Specimens

  摘要：

  It is reported that, on mechanochemical treatment, weinschenkite‐type RPO4·2H2O (R = Dy, Y, or Er) gradually transforms into rhabdophane‐type RPO4· nH2O (n = 0.5 to 1) and weinschenkite‐type YbPO4·2H2O into xenotime‐type YbPO4, at room temperature in air. Rhabdophane‐type YPO4·0.8H2O and ErPO4·0.9H2O obtained by grinding weinschenkite‐type RPO4·2H2O (R=Y or Er) are new. The new rhabdophane‐type YPO4·0.8H2O and ErPO4·0.9H2O gradually transform to xenotime‐type YPO4 and ErPO4 when heated above 900°C (R = Y) and 700°C (R = Er) in air.

  DOI：

  10.1111/j.1151-2916.1989.tb06276.x

文献信息

• Self-assembly of uniform hexagonal yttrium phosphate nanocrystals
  作者：Ziyang Huo、Chen Chen、Yadong Li

  DOI：10.1039/b606531g

  日期：——

  We report a facile chemical route for the synthesis of uniform hexagonal yttrium phosphate hydrate nanocrystals and their assembly into close-packed regular superstructures through noncovalent interactions of long chain molecules attached to the surfaces of inorganic nanocrystals.

  我们报道了一种简便的化学方法，用于合成均匀的六方晶型磷酸钇水合物纳米晶体，并通过附着在无机纳米晶体表面的长链分子的非共价相互作用，将它们组装成紧密堆积的规则超结构。
• Synthesis and Photoluminescence Characterization of Ellipsoidal Lanthanide Orthophosphate Nanoparticles
  作者：Zhouguang Lu、Rui Gao、Wei Li、Boyun Huang

  DOI：10.1111/j.1551-2916.2010.04116.x

  日期：2011.2

  rare-earth orthophosphates, LnPO4·xH2O (Ln=La, Y, Ce, Sm, Gd, Tb, Dy, Er, and Yb), with a mean diameter of ∼100 nm. The procedure involves the formation of homogeneous, transparent, metal–citrate–ethylenediamine tetraacetic acid (EDTA) gel precursors using both citric acid and EDTA as the complexing agents, followed by hydrothermal mineralization to yield the final LnPO4·xH2O nanocrystallites. Techniques

  本文描述了合成一系列稀土正磷酸盐 LnPO4·xH2O（Ln=La、Y、Ce、Sm、Gd、Tb、Dy、Er 和 Yb）的一般水热路线，平均直径为约 100 纳米。该过程包括使用柠檬酸和 EDTA 作为络合剂形成均匀、透明、金属-柠檬酸盐-乙二胺四乙酸 (EDTA) 凝胶前体，然后进行水热矿化以产生最终的 LnPO4·xH2O 纳米微晶。X 射线衍射、透射电子显微镜和高分辨率透射电子显微镜技术已被用于表征合成的 LnPO4·xH2O 纳米晶体。此外，进行了 Eu3+ 掺杂的 LnPO4·xH2O 纳米晶体的光致发光 (PL) 表征。
• Thermal decomposition of lanthanide orthophosphates synthesized through crystallisation from phosphoric acid solution
  作者：R Kijkowska

  DOI：10.1016/s0040-6031(03)00085-6

  日期：2003.9.4

  phosphates LnPO4·H2O (Ln: La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Y) prepared by crystallisation from boiling phosphoric acid solution has been presented. On the basis of the effects observed on DTA and DTG curves, while heated up to 1000 °C, the phosphates can be divided into two groups: (a) the first group includes hexagonal (La→Tb), and orthorhombic Dy phosphates, (b) the second

  摘要 沸腾磷酸结晶制备的镧系磷酸盐 LnPO4·H2O（Ln：La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu 和 Y）的热分解特性已提出解决方案。根据对 DTA 和 DTG 曲线观察到的影响，当加热到 1000 °C 时，磷酸盐可分为两组：（a）第一组包括六方（La→Tb）和正交 Dy 磷酸盐，（ b) 第二组由四方 (Ho→Lu) 和 Y 磷酸盐组成。组 (a) 的特征是两个低于 300 °C 的吸热线，与脱水有关，以及一个高于 700 °C 的放热线，与六方/斜方晶向单斜晶的转变有关。多晶型转变的温度随着镧系元素原子序数从 900 °C (Tb, Dy) 的增加而增加。（b）组在很宽的温度范围（100-600°C）内脱水，即使在 950°C 加热后仍保持四方晶体结构。然而，增加的结晶度、a 轴和 c 轴的收缩以及 IR 光谱的差异表明 (Ho→Lu)
• Controlled synthesis and tunable luminescence of uniform YPO₄·0.8H₂O and YPO₄·0.8H₂O : Tb³⁺/Eu³⁺ nanocrystals by a facile approach
  作者：Lei Zhang、Linlin Fu、Xingxing Yang、Zuoling Fu、Xiangdong Qi、Zhijian Wu

  DOI：10.1039/c4tc01427h

  日期：——

  effectively excited with 380 nm and the luminescence colors of YPO4·0.8H2O : Tb3+, Eu3+ nanocrystals can be easily tuned by changing the concentration of Eu3+ ions due to an efficient energy transfer from Tb3+ to Eu3+. These results revealed that the combination of the defect luminescence and rare earth-doping emission in YPO4·0.8H2O : Tb3+, Eu3+ nanocrystals could result in tunable emission in a large

  柠檬酸三钠（Cit 3−）通过水热法成功地合成了均匀且结晶良好的YPO 4 ·0.8H 2 O和YPO 4 ·0.8H 2 O：Tb 3+，Eu 3+纳米晶体修饰符”。X射线衍射（XRD），场发射扫描电子显微镜（FE-SEM），高分辨率透射电子显微镜（HRTEM）和光致发光（PL）光谱用于表征样品。发现初始溶液的pH决定了最终产物的形状。另外，通过Cit 3−制备的YPO 4 ·0.8H 2 O样品辅助水热合成表现出强烈而明亮的蓝色发射。用傅立叶变换红外光谱（FT-IR）和电子顺磁共振（EPR）光谱进行了表征，证实了柠檬酸三钠（Cit 3-）在水热过程中诱导的碳相关杂质，并证实了与发光有关的顺磁缺陷发光YPO 4 ·0.8H 2 O纳米晶体中存在一定的性质。更有趣的是，YPO 4 ·0.8H 2 ○：铽3+，Eu的3+的样品可以被有效地与380nm的激发和YPO的发光颜色4 ·0.8H 2
• Synthesis and Phase Composition of Lanthanide Phosphate Nanoparticles LnPO₄(Ln=La, Gd, Tb, Dy, Y) and Solid Solutions for Fiber Coatings
  作者：Emmanuel E. Boakye、Pavel Mogilevsky、Randall S. Hay、Geoff E. Fair

  DOI：10.1111/j.1551-2916.2008.02737.x

  日期：2008.12

  Rare earth phosphates with rare earths of Gd, Tb, and Dy can form either monazite or xenotime. Hydrated lanthanide phosphate precursors to monazite and xenotime were made in aqueous solution. The particles were formed by adding dilute phosphoric acid (H3PO4) to either; (a) lanthanide citrate (Ln-Cit) or (b) lanthanide nitrate (LnNO3) [Ln=La, Gd, Tb, Dy, and Y] solutions followed by altering the pH from

  稀土磷酸盐与 Gd、Tb 和 Dy 稀土可形成独居石或磷钇矿。独居石和磷钇矿的水合镧系元素磷酸盐前体在水溶液中制备。颗粒是通过将稀磷酸 (H3PO4) 添加到其中之一而形成的；(a) 镧系元素柠檬酸盐 (Ln-Cit) 或 (b) 镧系元素硝酸盐 (LnNO3) [Ln=La、Gd、Tb、Dy 和 Y] 溶液，然后用氢氧化铵将 pH 从~1 更改为~10。前体粒径和形态通过扫描电子显微镜（SEM）表征，重量损失通过热重分析（TGA）表征。通过差热分析 (DTA) 和 X 射线衍射确定温度下的相存在。讨论了前驱体制备方法对热处理后独居石或磷钇矿存在的影响。