perfluoro-2,5-dimethyl-3,6-dioxanonanoic γ-triethoxysilylpropylamide | 36148-15-9

• 物质功能分类: 化学试剂 - 硅烷试剂
• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: perfluoro-2,5-dimethyl-3,6-dioxanonanoic γ-triethoxysilylpropylamide
• 英文别名: 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]-N-(3-triethoxysilylpropyl)propanamide
• CAS: 36148-15-9
• 化学式: C₁₈H₂₂F₁₇NO₆Si
• 分子量: 699.434
• InChiKey: ONBUOZZCNKNWEE-UHFFFAOYSA-N

物化性质

• 沸点：
  140-144 °C(Press: 1 Torr)
• 密度：
  1.421±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.41
• 重原子数：
  43
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  75.2
• 氢给体数：
  1
• 氢受体数：
  23

反应信息

• 作为产物：
  描述：

  2,5-双(三氟甲基)-3,6-二氧杂十一氟代壬酰氟 反应 2.0h， 生成 perfluoro-2,5-dimethyl-3,6-dioxanonanoic γ-triethoxysilylpropylamide
  参考文献：
  名称：

  Synthesis of water- and oil-repellent organofluorosilicon compounds

  摘要：

  We have synthesised organofluorosilicon compounds that impart higher water- and oil-repellent properties to construction materials than known organosilicon compounds.

  DOI：

  10.1070/mc2006v016n03abeh002340

文献信息

• Synthesis and properties of fluorosilicon compounds for protection of cultural monuments from harmful environmental exposure
  作者：A. A. Yarosh、S. P. Krukovsky、A. M. Sakharov、M. Yu. Popovich、V. M. Kotov、T. A. Pryakhina

  DOI：10.1007/s11172-014-0467-0

  日期：2014.2

  Methods for the synthesis of perfluorocarboxylic acid derivatives with reactive trialkoxysilyl groups soluble in organic and organofluorine (1,1,2-trichlorotrif1uoroethane, etc.) solvents have been developed. The contact angles of water and decalin, water absorption, resistance to freezing, and salt-resistance of limestone and plaster samples treated with these compounds were determined. Fluorosilicon organic compounds impart more hydro- and oleophobic properties to the protected surfaces than known organosilicon agents and reliably protect sculptures and architectural monuments from mold and algae deposition.

  开发了具有反应性三烷氧基硅烷基团且可溶于有机和有机氟溶剂（如1,1,2-三氯三氟乙烷等）的全氟羧酸衍生物的合成方法。测定了经这些化合物处理的石灰石和石膏样品的水和十氢萘接触角、吸水性、耐冻性以及耐盐性。氟硅有机化合物相较于已知的硅有机剂，为保护表面赋予了更强的疏水和疏油性能，并能可靠地保护雕塑和建筑纪念物免受霉菌和藻类附着。