aluminum;2-methylquinolin-8-olate;6-phenylnaphthalen-2-olate | 844435-92-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: aluminum;2-methylquinolin-8-olate;6-phenylnaphthalen-2-olate
• CAS: 844435-92-3；946070-23-1
• 化学式: C₃₆H₂₇AlN₂O₃
• 分子量: 562.604
• InChiKey: CWCXSTLVRPQIKQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  8.74
• 重原子数：
  42
• 可旋转键数：
  5
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  53.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  8-羟基喹哪啶 、 6-phenyl-2-naphthol 、 三异丁基铝 以 甲苯 为溶剂， 以84%的产率得到aluminum;2-methylquinolin-8-olate;6-phenylnaphthalen-2-olate
  参考文献：
  名称：

  The blue aluminum and gallium chelates for OLEDs

  摘要：

  Pentacoordinate Al and Ga complexes of the type ML2OR, where L is a 2- methyl- 8- quinolinolate and OR is a monodentate, anionic O donor ligand, were optimized for robust use in vapor-deposited OLEDs. Photophysical, thermal, and crystallographic properties relevant to OLEDs are reported. The utility of the complexes is illustrated in new formulations for blue fluorescent and red phosphorescent OLEDs. (c) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.07.008

文献信息

• ALUMINUM CHELATE COMPLEX FOR ORGANIC EL MATERIAL
  申请人：MATSUO Shinji

  公开号：US20100256377A1

  公开（公告）日：2010-10-07

  This invention provides an organic EL material useful for the emissive layer of an organic EL element which deteriorates little in luminance when operated over a prolonged period of time and shows excellent durability. The material is an aluminum chelate complex which is represented by general formula (1) in which Ar 1 is a mono- or bicylic arylene group, Ar 2 is a mono- or bicyclic aryl group, R 1 -R 6 are hydrogen or hydrocarbon groups containing 1-8 carbon atoms and contains a compound represented by general formula (1) in which Ar 2 is a halogen as an impurity in an amount of 350 wt ppm or less.

  这项发明提供了一种有机EL材料，适用于有机EL元件的发射层，在长时间运行时，其亮度几乎不会退化，并且具有出色的耐久性。该材料是一种铝螯合物复合物，其由一般式（1）表示，其中Ar1是单环或双环芳烃基团，Ar2是单环或双环芳基团，R1-R6是含有1-8个碳原子的氢或烃基团，并且含有一种以卤素为杂质的化合物，其以350重量ppm或更少的量表示。
• The blue aluminum and gallium chelates for OLEDs
  作者：Joseph C. Deaton、David W. Place、Christopher T. Brown、Manju Rajeswaran、Marina E. Kondakova

  DOI：10.1016/j.ica.2007.07.008

  日期：2008.3

  Pentacoordinate Al and Ga complexes of the type ML2OR, where L is a 2- methyl- 8- quinolinolate and OR is a monodentate, anionic O donor ligand, were optimized for robust use in vapor-deposited OLEDs. Photophysical, thermal, and crystallographic properties relevant to OLEDs are reported. The utility of the complexes is illustrated in new formulations for blue fluorescent and red phosphorescent OLEDs. (c) 2007 Elsevier B. V. All rights reserved.