1,3-dibromo-1,1,2,2,3,3-hexamethyltrisilane | 65160-58-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,3-dibromo-1,1,2,2,3,3-hexamethyltrisilane
• 英文别名: Bis[bromo(dimethyl)silyl]-dimethylsilane
• CAS: 65160-58-9
• 化学式: C₆H₁₈Br₂Si₃
• 分子量: 334.273
• InChiKey: NBGWWEMCEMCDNL-UHFFFAOYSA-N

物化性质

• 沸点：
  209.3±23.0 °C(Predicted)
• 密度：
  1.279±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.05
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,3-dibromo-1,1,2,2,3,3-hexamethyltrisilane 在 zinc(II) fluoride 作用下， 以 六氯-1,3-丁二烯 为溶剂， 生成 1,3-difluorohexamethyltrisilane
  参考文献：
  名称：

  Synthese, Kernresonanzspektren und Schwingungsspektren der Hexamethyltrisilane und Pentamethyltrisilane (XMe2Si)2SiMe2 und (XMe2Si)2SiMeX (XH, F, Cl, Br, I, Ph, OMe)

  摘要：

  The syntheses, IR, Raman and Si-29 spectra of the title compounds are reported. SiSi force constants, calculated with the aid of normal coordinate analyses, are compared with Si-29 Si-29 coupling constants.

  DOI：

  10.1016/0584-8539(94)80120-7
• 作为产物：
  描述：

  二甲基-二(三甲基硅烷基)硅烷 在 aluminum tri-bromide 、 乙酰溴 作用下， 以 正己烷 为溶剂， 以4 g的产率得到1,3-dibromo-1,1,2,2,3,3-hexamethyltrisilane
  参考文献：
  名称：

  Base catalysed hydrogenation of methylbromooligosilanes with trialkylstannanes, identification of the first methylbromohydrogenoligosilanes

  摘要：

  The Lewis base catalysed hydrogenation of methylchlorooligsilanes with trialkylstannanes can also be applied to the hydrogenation of methylbromooligosilanes. In this way methylbromohydrogenoligosilanes were prepared for the first time. Methylbromotrisilanes with an > SiBrMe middle group (e.g. SiBrMe(2)-SiBrMe-SiBrMe(2)) are hydrogenated first at this silicon atom under formation of an > SiHMe group (e.g. SiBrMe(2)-SiHMe-SiBrMe(2)). Brominated silanes containing a quarternary Si(Si)(4) unit (e.g. Si(SiBrMe(2))(4)) do not react with trialkylstannanes.

  DOI：

  10.1016/s0022-328x(96)06552-7

文献信息

• The preparation of α,ω-dibromopermethylpolysilanes and characterization of these and related chloropermethylpolysilanes by mass spectrometry
  作者：Catherine Hurt Middlecamp、Wieslaw Wojnowski、Robert West

  DOI：10.1016/s0022-328x(00)93188-7

  日期：1977.11

  The series of α,ω-dibromopermethylpolysilanes, Br(SiMe2)nBr, (n = 2−6) has been prepared by the action of bromine on dodecamethylcyclohexasilane. The mass spectra of these compounds, of the corresponding chlorine compounds Cl(SiMe2)nCl (n = 2−6), and of the 1-chloropermethylpolysilanes Cl(SiMe2)Me (n = 2, 3, 4, 6) have been recorded at 14 and 70 eV. For compounds with n > 3, the formation of the ions

  通过溴在十二甲基环己硅烷上的作用，制备了一系列α，ω-二溴过甲基聚硅烷Br（SiMe 2）n Br，（n = 2-6）。这些化合物，相应的氯化合物Cl（SiMe 2）n Cl（n = 2-6）和1-氯过甲基聚硅烷Cl（SiMe 2）Me（n = 2、3、4、6 ）的质谱已被记录在14和70 eV。对于n > 3的化合物，形成离子Si 3 Me 6 X +和Si 4 Me 8 X +（X = Cl，Br）非常受青睐，这些离子是光谱中的主要或基础峰。建议这些离子的稳定性归因于环化和桥联：
• Einholz, Wolfgang; Gollinger, Walter; Haubold, Wolfgang, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1990, vol. 45, # 1, p. 25 - 30
  作者：Einholz, Wolfgang、Gollinger, Walter、Haubold, Wolfgang

  DOI：——

  日期：——
• Synthesis of α,ω-dihalopermethyloligosilanes and silane-siloxane copolymers
  作者：A. I. Chernyavskii、B. G. Zavin

  DOI：10.1007/bf02505684

  日期：1997.8

  alpha,omega-Dibromopermethyloligosilanes, Br(SiMe2)(n)Br (n = 2-4, 6), were prepared by the reaction of dodecamethylcyclohexasilane with bromine. The reaction of (Me2Si)(6) with MCl4 (M = Sn, Ti) proceeds with the cleavage of Si-Si- and Si-C-bonds with the formation of alpha,omega-dichloropermethyloligosilanes, CI(SiMe2)(n)Cl (n = 2-4, 6), and chloro derivatives of cyclohexasilane, ClmSi6Me12-m (m = 1, 2). Silane-siloxane copolymers of regular structure were obtained by heterofunctional copolycondensation of alpha,omega-dihalopermethyloligosilanes with 1,5-dihydroxyhexamethyltrisiloxane.
• Conformational Control of Polysilanes: Use of CH₂ Spacers in the Silicon Backbone
  作者：Andreas Wallner、Johann Hlina、Harald Wagner、Judith Baumgartner、Christoph Marschner

  DOI：10.1021/om1011159

  日期：2011.8.8

  By the reaction of a number of oligosilyl potassium compounds with (trimethylsilyl)chloromethane, derivatives containing the (trimethylsilyl)methyl substituent were prepared. Using X-ray single-crystal structure analysis and UV spectroscopy the conformational properties of some of the compounds were studied. It was found that the (trimethylsilyl)methylated examples exhibit UV absorption properties which correspond to lower energy transitions in comparison to those of analogous trimethyl-silylated molecules. The influence of this effect decreases, however, with increasing chain lengths.
• EINHOL, WOLFGANG;GOLLINGER, WALTER;HAUBOLD, WOLFGANG, Z. NATURFORSCH. B , 45,(1990) N, C. 25-30
  作者：EINHOL, WOLFGANG、GOLLINGER, WALTER、HAUBOLD, WOLFGANG

  DOI：——

  日期：——