Fe diisopropyldithiophosphate | 73062-60-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: Fe diisopropyldithiophosphate
• 英文别名: bis(O,O'-diisopropyl dithiophosphate)iron(II)；Di(propan-2-yloxy)-sulfanylidene-sulfido-lambda5-phosphane;iron(2+)；di(propan-2-yloxy)-sulfanylidene-sulfido-λ5-phosphane;iron(2+)
• CAS: 73062-60-9
• 化学式: C₁₂H₂₈FeO₄P₂S₄
• 分子量: 482.41
• InChiKey: IHIAGJSZCVZNPW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.51
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,10-菲罗啉 、 Fe diisopropyldithiophosphate 以 丙酮 为溶剂， 生成 bis(O,O'-diisopropyl dithiophosphato-S,S')(1,10-phenanthroline-N,N')iron(II)
  参考文献：
  名称：

  Bis(O,O′-diisopropyl dithiophosphato-S,S′)(1,10-phenanthroline-N,N′)metal(II) complexes with cadmium(II) and iron(II)

  摘要：

  The two title compounds, [M(C6H14O2PS2)(2)(C12H8N2)], where M = Cd-II and Fe-II, are isomorphous. Each compound has a crystallographic twofold axis of symmetry through the metal atom and the 1,10-phenanthroline molecule. The central metal atom is coordinated to four S atoms from the two dithiophosphate groups and two N atoms from the 1,10-phenanthroline ligand. The environment of the metal atom is a distorted octahedron.

  DOI：

  10.1107/s0108270100014256

文献信息

• Bis(<i>O</i>,<i>O</i>′-diisopropyl dithiophosphato-<i>S</i>,<i>S</i>′)(1,10-phenanthroline-<i>N</i>,<i>N</i>′)metal(II) complexes with cadmium(II) and iron(II)
  作者：Qingli Hao、Xujie Yang、Fangfang Jian、Lude Lu、Xin Wang、Ibrahim Abdul Razak、Suchada Chantrapromma、Hoong-Kun Fun

  DOI：10.1107/s0108270100014256

  日期：2001.1.15

  The two title compounds, [M(C6H14O2PS2)(2)(C12H8N2)], where M = Cd-II and Fe-II, are isomorphous. Each compound has a crystallographic twofold axis of symmetry through the metal atom and the 1,10-phenanthroline molecule. The central metal atom is coordinated to four S atoms from the two dithiophosphate groups and two N atoms from the 1,10-phenanthroline ligand. The environment of the metal atom is a distorted octahedron.