N-(2-chlorocyclohexyl)formamide | 140669-93-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: N-(2-chlorocyclohexyl)formamide
• CAS: 140669-93-8
• 化学式: C₇H₁₂ClNO
• 分子量: 161.631
• InChiKey: XBQZGFQYSKBBNU-UHFFFAOYSA-N

物化性质

• 沸点：
  325.1±31.0 °C(Predicted)
• 密度：
  1.12±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-chloroformamide 、 环己烯 以 二氯甲烷 为溶剂， 反应 15.0h， 以35%的产率得到N-(2-chlorocyclohexyl)formamide
  参考文献：
  名称：

  Photolytic and chromium(II)-promoted addition reactions of N-halogenoformamides with alkenes

  摘要：

  Formamidyl radicals (HCONR) do not intramolecularly abstract hydrogen or cyclise onto aromatic rings, but do add intermolecularly to alkenes. The photolytic addition of N-halogenoformamides to alkenes is inhibited by N-alkylation. However, N-alkyl-N-halogenoformamides add to alkenes in the presence of chromium(II) species. The addition of N-halogenoformamides to alkenes occurs regiospecifically with formamidyl bonding to the less substituted terminus of the alkene. The adducts obtained from N-alkylformamidyls exist as mixtures of rotameric isomers whose configurations have been assigned. The reactivity of the formamidyl radical has been discussed in terms of its conformation and electronic state.

  DOI：

  10.1039/p19920000627

文献信息

• AMIDE DERIVATIVE, PEST CONTROL AGENT CONTAINING THE AMIDE DERIVATIVE, AND USE OF THE AMIDE DERIVATIVE
  申请人：Kobayashi Yumi

  公开号：US20110201687A1

  公开（公告）日：2011-08-18

  An amide derivative represented by the following Formula (1) is provided as an amide derivative showing a significantly excellent effect for a pest control action. In the following Formula (1), A represents a carbon atom, a nitrogen atom, or the like, and K represents a non-metal atomic group necessary for forming a cyclic linking group derived from benzene or a heterocyclie. X represents a halogen atom or the like; n represents an integer of from 0 to 4 . R 1 and R 2 represent hydrogen atoms, alkyl groups, or the like. T represents —C(=G 1 )-Q 1 or —C(=G 1 )-G 2 Q 2 , and G 1 to G 3 each represent oxygen atoms or the like. Q 1 and Q 2 each represent a hydrogen atom, an alkyl group, an aryl group, or the like. Y 1 and Y 5 each represent a halogen atom or the like, Y 2 and Y 4 each represent a hydrogen atom or the like, and Y 3 represents a C2-C5 haloalkyl group.

  提供以下式子（1）表示的酰胺衍生物，作为一种表现出显著杀虫作用的酰胺衍生物。在下面的式子（1）中，A代表碳原子、氮原子或类似物，K代表必要的非金属原子团，用于形成从苯或杂环中得到的环链连接基。X代表卤素原子或类似物；n代表0至4的整数。R1和R2代表氢原子、烷基或类似物。T代表- C（= G1）- Q1或- C（= G1）- G2Q2，G1到G3每个代表氧原子或类似物。Q1和Q2每个代表氢原子、烷基、芳基或类似物。Y1和Y5每个代表卤素原子或类似物，Y2和Y4每个代表氢原子或类似物，Y3代表C2-C5卤代烷基。
• AMIDE DERIVATIVE, PEST CONTROL AGENT CONTAINING THE AMIDE DERIVATIVE AND USE OF THE PEST CONTROL AGENT
  申请人：Mitsui Chemicals Agro, Inc.

  公开号：EP2319830A1

  公开（公告）日：2011-05-11

  An amide derivative represented by the following Formula (1) is provided as an amide derivative showing a significantly excellent effect for a pest control action. In the following Formula (1), A represents a carbon atom, a nitrogen atom, or the like, and K represents a non-metal atomic group necessary for forming a cyclic linking group derived from benzene or a heterocyclie. X represents a halogen atom or the like; n represents an integer of from 0 to 4. R1 and R2 represent hydrogen atoms, alkyl groups, or the like. T represents -C(=G1)-Q1 or -C(=G1)-G2Q2, and G1 to G3 each represent oxygen atoms or the like. Q1 and Q2 each represent a hydrogen atom, an alkyl group, an aryl group, or the like. Y1 and Y5 each represent a halogen atom or the like, Y2 and Y4 each represent a hydrogen atom or the like, and Y3 represents a C2-C5 haloalkyl group.

  下式(1)代表的酰胺衍生物作为一种酰胺衍生物，在害虫防治方面具有显著的优异效果。 在下式（1）中，A 代表碳原子、氮原子或类似物，K 代表形成源自苯或杂环的环状连接基团所必需的非金属原子团。X 代表卤素原子或类似物；n 代表 0 至 4 的整数。R1 和 R2 代表氢原子、烷基或类似物。T 代表 -C(=G1)-Q1 或 -C(=G1)-G2Q2，G1 至 G3 各自代表氧原子或类似物。Q1 和 Q2 各自代表氢原子、烷基、芳基或类似物。Y1 和 Y5 分别代表卤原子或类似物，Y2 和 Y4 分别代表氢原子或类似物，Y3 代表 C2-C5 卤代烷基。
• PEST CONTROL AGENT CONTAINING AN AMIDE DERIVATIVE AND USE OF THE PEST CONTROL AGENT
  申请人：Mitsui Chemicals Agro, Inc.

  公开号：EP3081552A1

  公开（公告）日：2016-10-19

  An amide derivative represented by the following Formula (1) is provided as an amide derivative showing a significantly excellent effect for a pest control action. In the following Formula (1), A represents a carbon atom, a nitrogen atom, or the like, and K represents a non-metal atomic group necessary for forming a cyclic linking group derived from benzene or a heterocyclie. X represents a halogen atom or the like; n represents an integer of from 0 to 4. R1 and R2 represent hydrogen atoms, alkyl groups, or the like. T represents -C(=G1)-Q1 or -C(=G1)-G2Q2, and G1 to G3 each represent oxygen atoms or the like. Q1 and Q2 each represent a hydrogen atom, an alkyl group, an aryl group, or the like. Y1 and Y5 each represent a halogen atom or the like, Y2 and Y4 each represent a hydrogen atom or the like, and Y3 represents a C2-C5 haloalkyl group.

  下式(1)代表的酰胺衍生物作为一种酰胺衍生物，在害虫防治方面具有显著的优异效果。 在下式（1）中，A 代表碳原子、氮原子或类似物，K 代表形成源自苯或杂环的环状连接基团所必需的非金属原子团。X 代表卤素原子或类似物；n 代表 0 至 4 的整数。R1 和 R2 代表氢原子、烷基或类似物。T 代表 -C(=G1)-Q1 或 -C(=G1)-G2Q2，G1 至 G3 各自代表氧原子或类似物。Q1 和 Q2 各自代表氢原子、烷基、芳基或类似物。Y1 和 Y5 分别代表卤原子或类似物，Y2 和 Y4 分别代表氢原子或类似物，Y3 代表 C2-C5 卤代烷基。
• Amide derivative, pest control agent containing the amide derivative, and use of the amide derivative
  申请人：Mitsui Chemicals Agro, Inc.

  公开号：US10582708B2

  公开（公告）日：2020-03-10

  An amide derivative represented by the following Formula (1) is provided as an amide derivative showing a significantly excellent effect for a pest control action. In the following Formula (1), A represents a carbon atom, a nitrogen atom, or the like, and K represents a non-metal atomic group necessary for forming a cyclic linking group derived from benzene or a heterocyclie. X represents a halogen atom or the like; n represents an integer of from 0 to 4. R1 and R2 represent hydrogen atoms, alkyl groups, or the like. T represents —C(=G1)-Q1 or —C(=G1)-G2Q2, and G1 to G3 each represent oxygen atoms or the like. Q1 and Q2 each represent a hydrogen atom, an alkyl group, an aryl group, or the like. Y1 and Y5 each represent a halogen atom or the like, Y2 and Y4 each represent a hydrogen atom or the like, and Y3 represents a C2-C5 haloalkyl group.

  下式(1)代表的酰胺衍生物作为一种酰胺衍生物，在害虫防治方面具有显著的优异效果。 在下式（1）中，A 代表碳原子、氮原子或类似物，K 代表形成源自苯或杂环的环状连接基团所必需的非金属原子团。X 代表卤素原子或类似物；n 代表 0 至 4 的整数。R1 和 R2 代表氢原子、烷基或类似物。T 代表 -C(=G1)-Q1 或 -C(=G1)-G2Q2，G1 至 G3 各自代表氧原子或类似物。Q1 和 Q2 各自代表氢原子、烷基、芳基或类似物。Y1 和 Y5 分别代表卤原子或类似物，Y2 和 Y4 分别代表氢原子或类似物，Y3 代表 C2-C5 卤代烷基。
• AMIDE DERIVATIVE, PEST CONTROL AGENT CONTAINING THE AMIDE DERIVATIVE AND PEST CONTROLLING METHOD
  申请人：Mitsui Chemicals Agro, Inc.

  公开号：EP2325165B1

  公开（公告）日：2020-02-19