1,1,2,2,3,3,4,5,5,6-Decafluoro-4,6-dimethylcyclohexane | 29917-43-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1,1,2,2,3,3,4,5,5,6-Decafluoro-4,6-dimethylcyclohexane
• CAS: 29917-43-9
• 化学式: C₈H₆F₁₀
• 分子量: 292.12
• InChiKey: VLDUFRVSJHNFSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  10

文献信息

• [EN] CATALYSTS<br/>[FR] CATALYSEURS
  申请人：BOREALIS AG

  公开号：WO2018091684A1

  公开（公告）日：2018-05-24

  A complex of formula (I) wherein M is zirconium or hafnium; each X independently is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR'2-, -R'2Ge-, wherein each R' is independently a hydrogen atom or a C1-C20-hydrocarbyl group optionally containing one or more silicon atoms or heteroatoms of Group 14-16 of the periodic table or fluorine atoms, and optionally two R' groups taken together can form a ring; R2 and R2' are each independently a C1-C20 hydrocarbyl group, -OC1- hydrocarbyl group or -SC1-20 hydrocarbyl group; R5 is a -OC1-20 hydrocarbyl group or -SC1-20 hydrocarbyl group, said R5 group being optionally substituted by one or more halo groups; R5' is hydrogen or a C1-20 hydrocarbyl group; -OC1-20 hydrocarbyl group or -SC1-20 hydrocarbyl group; said C1-20 hydrocarbyl group being optionally substituted by one or more halo groups; R6 and R6' are each independently a C1-20 hydrocarbyl group; -OC1-20 hydrocarbyl group or -SC1-20 hydrocarbyl group; each R1 and R1' are independently -CH2Rx wherein Rx are each independently H, or a C1-20 hydrocarbyl group, optionally containing heteroatoms.

  式中M为锆或铪；每个X独立地是一个σ配体；L是一个二价桥，选自-R'2C-、-R'2C-CR'2-、-R'2Si-、-R'2Si-SiR'2-、-R'2Ge-，其中每个R'独立地是一个氢原子或一个C1-C20的烃基团，可选地包含一个或多个硅原子或周期表中第14-16族的杂原子或氟原子，并且可选地两个R'基团一起可以形成一个环；R2和R2'各自独立地是一个C1-C20烃基团、-OC1-烃基团或-SC1-20烃基团；R5是一个-OC1-20烃基团或-SC1-20烃基团，所述R5基团可被一个或多个卤素取代；R5'是氢或一个C1-20烃基团；-OC1-20烃基团或-SC1-20烃基团；所述C1-20烃基团可被一个或多个卤素取代；R6和R6'各自独立地是一个C1-20烃基团；-OC1-20烃基团或-SC1-20烃基团；每个R1和R1'各自独立地为-CH2Rx，其中Rx各自独立地为H，或一个C1-20烃基团，可选地含有杂原子。
• NITRILEOXIDE COMPOUND
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：US20180050983A1

  公开（公告）日：2018-02-22

  The present invention provides a compound of the formula (I): wherein, R 1 is a hydrogen atom or a hydrocarbon group; R 2 is —R 4 —R 5 ; R 3 is —R 4 —R 5 or —R 4 —R 6 ; R 4 is a divalent organic group; R 5 is OH, SH, COOH or NHR 9 ; R 9 is a hydrogen atom or an alkyl group having 1-6 carbon atoms; and R 6 is a hydrogen atom or an alkyl group having 1-6 carbon atoms.

  本发明提供了一种具有以下式（I）的化合物：其中，R1是氢原子或烃基；R2是—R4—R5；R3是—R4—R5或—R4—R6；R4是二价有机基；R5是OH、SH、COOH或NHR9；R9是氢原子或具有1-6个碳原子的烷基基团；R6是氢原子或具有1-6个碳原子的烷基基团。
• Method of oxidizing an alcohol using a recyclable fluorous sulfoxide
  申请人：——

  公开号：US20030105363A1

  公开（公告）日：2003-06-05

  A method of oxidizing primary and secondary alcohols to an aldehyde or ketone using a fluorous sulfoxide or a fluorous sulfide is disclosed. The method includes regenerating and recycling the fluorous sulfoxide.

  揭示了一种利用氟烃亚砜或氟烃硫化物将一级和二级醇氧化为醛或酮的方法。该方法包括再生和循环利用氟烃亚砜。
• MULTIFUNCTIONAL NITRILEOXIDE COMPOUND
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：US20150251995A1

  公开（公告）日：2015-09-10

  The present invention provides a compound of the formula (I): wherein: R 2 and R 3 represent each independently a hydrogen atom or a hydrocarbon group; A represents an s-valent organic group; and s is an integer of 2-10. This nitrileoxide compound has stable and can be easily produced.

  本发明提供了一种化合物，其化学式为（I）：其中：R2和R3分别独立地代表氢原子或烃基；A代表s价有机基团；s为2-10的整数。这种腈氧化物化合物具有稳定性，且易于生产。
• [EN] CATALYST<br/>[FR] CATALYSEUR
  申请人：BOREALIS AG

  公开号：WO2014096282A1

  公开（公告）日：2014-06-26

  A catalyst in solid particulate form free from an external carrier material comprising (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-Si R'2-, -R'2 Ge-, wherein each R' is independently a hydrogen atom, C1-20-alkyl, tri(C1-20-alkyl)silyl, C6-20-aryl, C7-20-arylalkyl or C7-20-alkylaryl; R2 is a C1-20-hydrocarbyl radical; R2' is a C1-20-hydrocarbyl radical;R6 is a linear or branched aliphatic C1-20-hydrocarbyl group, SR9or OSR9;R6' is a linear or branched aliphatic C1-20-hydrocarbyl group, SR9'or OR9'; with the proviso that neither R6 or R6' represents a group having a quaternary carbon atom directly attached to the indenyl ring; R9 is a C1-20-hydrocarbyl group;R9' is a C1-20-hydrocarbyl group; Ar is a C6-12-aryl or C5-12-heteroaryl group optionally carrying one or more substituents R8; Ar' is a C6-12-aryl or C5-12-heteroaryl group optionally carrying one or more substituents R8';each R8 is a C1-20-hydrocarbyl group;each R8' is a C1-20 -hydrocarbyl group;wherein at least two of R2 and R2'; R6 and R6'; or Ar and Ar' are the same;and (ii) a cocatalyst comprising a compound of a group 13 metal, e.g. Al or boron.

  固体颗粒形式的催化剂，不含外部载体材料，包括（i）公式（I）的配合物，其中M为锆或铪；每个X为σ配体；L为从-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-中选择的二价桥；其中每个R'独立地是氢原子，C1-20烷基，三(C1-20烷基)硅基，C6-20芳基，C7-20芳基烷基或C7-20烷基芳基；R2为C1-20烃基基团；R2'为C1-20烃基基团；R6为线性或支链脂肪族C1-20烃基团，SR9或OSR9；R6'为线性或支链脂肪族C1-20烃基团，SR9'或OR9'；但R6或R6'均不代表直接连接到茚基环上的季碳原子的基团；R9为C1-20烃基团；R9'为C1-20烃基团；Ar为C6-12芳基或C5-12杂芳基，可选择携带一个或多个取代基R8；Ar'为C6-12芳基或C5-12杂芳基，可选择携带一个或多个取代基R8'；每个R8为C1-20烃基团；每个R8'为C1-20烃基团；其中至少有两个R2和R2'、R6和R6'或Ar和Ar'相同；以及（ii）包括13族金属化合物的共催化剂，例如铝或硼。