(4R,14S)-3,15-dithiaheptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2(16),5,7,9(26),10,12,17,19,21(25),22-undecaene | 213598-87-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 吖萘类
• 英文名称: (4R,14S)-3,15-dithiaheptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2(16),5,7,9(26),10,12,17,19,21(25),22-undecaene
• CAS: 213598-87-9
• 化学式: C₂₄H₁₄S₂
• 分子量: 366.507
• InChiKey: VDAZMRSBMZJIRI-SZPZYZBQSA-N

物化性质

• 沸点：
  664.5±55.0 °C(Predicted)
• 密度：
  1.48±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (4R,14S)-3,15-dithiaheptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2(16),5,7,9(26),10,12,17,19,21(25),22-undecaene 以 N,N-二甲基甲酰胺 为溶剂， 生成 1,8-亚二萘基噻吩
  参考文献：
  名称：

  Facile Formation of Cyclic Polysulfides by a New Generation Method for Diatomic Sulfur

  摘要：

  A new generation of diatomic sulfur (1) has been achieved in a remarkably simple process by treatment of elemental sulfur with sodium hydride in the presence of phase-transfer catalysts. This facile generation of I has been trapped with olefins, diene, and triene to give cycloadducts as the form of cyclic sulfides in high yields.

  DOI：

  10.3987/com-98-8200
• 作为产物：
  描述：

  苊烯 在 1,2,3,4,5,6,7,8-八硫杂环辛烷 、 三(3,6-二氧杂庚基)胺 、 sodium hydride 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以65%的产率得到(4R,14S)-3,15-dithiaheptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2(16),5,7,9(26),10,12,17,19,21(25),22-undecaene
  参考文献：
  名称：

  Facile Formation of Cyclic Polysulfides by a New Generation Method for Diatomic Sulfur

  摘要：

  A new generation of diatomic sulfur (1) has been achieved in a remarkably simple process by treatment of elemental sulfur with sodium hydride in the presence of phase-transfer catalysts. This facile generation of I has been trapped with olefins, diene, and triene to give cycloadducts as the form of cyclic sulfides in high yields.

  DOI：

  10.3987/com-98-8200