1,1',1''-(1,3,5-Triazine-2,4,6-triyl)tri(pyrrolidin-2-one) | 103615-53-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,1',1''-(1,3,5-Triazine-2,4,6-triyl)tri(pyrrolidin-2-one)
• 英文别名: 1-[4,6-bis(2-oxopyrrolidin-1-yl)-1,3,5-triazin-2-yl]pyrrolidin-2-one
• CAS: 103615-53-8
• 化学式: C₁₅H₁₈N₆O₃
• 分子量: 330.34
• InChiKey: JEKOCBKSHMKPRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  99.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  N,N',N"-tris(4-chlorobutyryl)melamine 、 N,N-二甲基甲酰胺 、 potassium tert-butylate 在 氩 、 silica gel 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以to give 180 mg of pure 2,4,6-tris(pyrrolidin-2-on-1-yl)-1,3,5-triazine的产率得到1,1',1''-(1,3,5-Triazine-2,4,6-triyl)tri(pyrrolidin-2-one)
  参考文献：
  名称：

  Crosslinked film of tris-pyrrolidonyl triazine and polyfunctional active

  摘要：

  一种制备三噁烷交联剂三吡咯烷基三嗪的过程，从N,N'，N"-三（4-氯丁酰基）三聚氰胺通过用碱（如碳酸钠或碳酸钾）处理氯丁酰衍生物来实现分子内环化到三噁烷。所述可固化组合物包括三吡咯烷基三嗪作为交联剂和羟基官能或氨基官能材料作为树脂。使用粉末涂覆技术从可固化组合物制备无针孔的厚膜。

  公开号：

  US06107369A1

文献信息

• Process for preparing tris-pyrrolidonyl triazine crosslinker
  申请人：Cytec Technology Corp.

  公开号：US05496944A1

  公开（公告）日：1996-03-05

  A process for preparing a tris-lactam crosslinking agent, tris-pyrrolidonyl triazine, from N,N',N"-tris(4-chlorobutyryl)melamine by treatment of the chlorobutyryl derivative with a base such as sodium or potassium carbonate to effect intramolecular cyclization to the tris-lactam. A curable composition comprises tris-pyrrolidonyl triazine as the crosslinking agent and a hydroxyfunctional or aminofunctinoal material as a resin. Thick films with no pinholes are prepared from the curable compositions using powder coating techniques.

  一种制备三噁烷交联剂三吡咯烷三嗪的工艺，通过将氯丁酰衍生物与碱（如碳酸钠或碳酸钾）处理以使分子内环化成为三噁烷。一种可固化组合物包括三吡咯烷三嗪作为交联剂和羟基功能或氨基功能材料作为树脂。使用粉末涂覆技术从可固化组合物制备无针孔的厚膜。
• Composition of tris-pyrrolidonyl triazine and polyfunctional active
  申请人：Cytec Technology Corp.

  公开号：US06153672A1

  公开（公告）日：2000-11-28

  A process for preparing a tris-lactam crosslinking agent, tris-pyrrolidonyl triazine, from N,N',N"-tris(4-chlorobutyryl)melamine by treatment of the chlorobutyryl derivative with a base such as sodium or potassium carbonate to effect intramolecular cyclization to the tris-lactam. A curable composition comprised of tris-pyrrolidonyl triazine as the crosslinking agent and a hydroxyfunctional or aminofunctional material as a resin. Thick films with no pinholes are prepared from the curable compositions using powder coating techniques.

  一种制备三噁烷交联剂三吡咯酰基三嗪的方法，从N，N'，N''-三（4-氯丁酰基）三聚氰胺通过使用碱（如碳酸钠或碳酸钾）处理氯丁酰衍生物，使其分子内环化成为三噁烷。一种可固化组合物，包括三吡咯酰基三嗪作为交联剂和羟基功能或胺基功能材料作为树脂。使用粉末涂覆技术从可固化组合物制备无针孔的厚膜。
• Process for preparing amide derivatives from halomines and acid halides
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0541966A2

  公开（公告）日：1993-05-19

  This invention provides a process for preparing amide derivatives of acids by the reaction of haloamines and acid halides. Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process. Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel process of the invention.

  本发明提供了一种通过卤胺和酸卤化物反应制备酸酰胺衍生物的工艺。 三氯和六氯甲胺与氯甲酸酯和酸性氯化物反应制备三聚氰胺衍生酸酰胺。副产品氯可以在此过程中回收利用。 酰胺、氨基甲酸酯、磺酰胺、磷酰胺和相关的酰胺衍生物可通过本发明的新工艺制备。
• Process for preparing amide derivatives from halominotriazines and acid halides
  申请人：CYTEC TECHNOLOGY CORP.

  公开号：EP0565774A2

  公开（公告）日：1993-10-20

  This invention provides a process for preparing amide derivatives of acids by the reaction of haloaminotriazines and acid halides. This invention also provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs. Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process. Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel processes of the invention.

  本发明提供了一种通过卤代氨基三嗪和酸卤化物反应制备酸的酰胺衍生物的工艺。 本发明还提供了一种由卤胺三嗪和草酰氯、光气和光气类似物等酸卤化物衍生的酰胺衍生物制备异氰酸酯和异氰酸酯加合物的工艺。 三氯和六氯甲胺与氯甲酸酯和酸性氯化物反应可制备三聚氰胺衍生酸性酰胺。副产品氯可以在此过程中回收利用。 酰胺、氨基甲酸酯、磺酰胺、磷酰胺和相关的酰胺衍生物可通过本发明的新工艺制备。
• A process for preparing isocyanate compounds from haloaminotriazines and acid halides
  申请人：CYTEC TECHNOLOGY CORP.

  公开号：EP0930303A2

  公开（公告）日：1999-07-21

  This invention provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs. Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process.

  本发明提供了一种由卤胺三嗪和酸性卤化物（如草酰氯、光气和光气类似物）衍生的酰胺衍生物制备异氰酸酯和异氰酸酯加合物的工艺。 三氯和六氯甲胺与氯甲酸酯和酸性氯化物反应可制备三聚氰胺衍生酸性酰胺。副产品氯可以在此过程中回收利用。