trimethyl-(2-methyl-pentyloxy)-silane | 17877-22-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: trimethyl-(2-methyl-pentyloxy)-silane
• 英文别名: Trimethyl-(2-methyl-pentyloxy)-silan；Trimethyl[(2-methylpentyl)oxy]silane；trimethyl(2-methylpentoxy)silane
• CAS: 17877-22-4
• 化学式: C₉H₂₂OSi
• 分子量: 174.359
• InChiKey: DZBANYJTCRZHGN-UHFFFAOYSA-N

物化性质

• 保留指数：
  929.5

计算性质

• 辛醇/水分配系数(LogP)：
  3.27
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三甲基氯硅烷 、 2-甲基-1-戊醇 生成 trimethyl-(2-methyl-pentyloxy)-silane
  参考文献：
  名称：

  Consensus Among Economists: Revisited

  摘要：

  The authors explore consensus among economists on specific propositions on the basis of a fall 2000 survey of American Economic Association members. Because some propositions are drawn from earlier studies, the results illustrate the dynamics of opinion within the profession. The authors generally find consensus within the profession, although the degree of consensus varies between propositions that are international, macroeconomic, and microeconomic in nature. Consensus is particularly strong for propositions of free international trade and capital flows. In contrast, macroeconomic propositions exhibit a lower degree of consensus, partly because of increased agreement with monetarist and supply-side propositions over time. The profession displays substantial skepticism concerning claims of the "New Economy.".

  DOI：

  10.1080/00220480309595230

文献信息

• Diastereoselective synthesis of functionally substituted alkene dimers and oligomers, catalysed by chiral zirconocenes
  作者：Pavel V. Kovyazin、Il'giz N. Abdullin、Lyudmila V. Parfenova

  DOI：10.1016/j.catcom.2018.10.032

  日期：2019.1

  The research addresses the reaction of terminal alkenes and propene with AlR3 (R = Me, Et) in the presence of chiral Zr complexes, rac-[Y(η5-C9H10)2]ZrCl2 (Y = C2H4, SiMe2) or (NMI)2ZrCl2 (NMI- η5–neomenthylindenyl), and methylaluminoxane. The effect of reaction conditions, catalyst and trialkylalane structure on the substrate conversion and the reaction chemo- and stereoselectivity has been studied

  研究地址末端烯烃的反应和丙烯与为AlR 3中的手性锆复合物，的存在下（R =甲基，乙基）外消旋- [Y（η 5 -C 9 ħ 10）2 ]的ZrCl 2（Y = C 2 ħ 4，森达2）或（NMI）2的ZrCl 2（NMI- η 5–neomenthylindenyl）和甲基铝氧烷。研究了反应条件，催化剂和三烷基铝烷结构对底物转化率以及反应化学和立体选择性的影响。该反应主要经历烯烃甲基（乙基）锆化的阶段，随后将底物分子引入Zr-C键中。结果，开发了用于合成官能取代的线性末端烯烃二聚体和丙烯低聚物的非对映选择性一锅法。
• Consensus Among Economists: Revisited
  作者：Dan Fuller、Doris Geide-stevenson

  DOI：10.1080/00220480309595230

  日期：2003.1

  The authors explore consensus among economists on specific propositions on the basis of a fall 2000 survey of American Economic Association members. Because some propositions are drawn from earlier studies, the results illustrate the dynamics of opinion within the profession. The authors generally find consensus within the profession, although the degree of consensus varies between propositions that are international, macroeconomic, and microeconomic in nature. Consensus is particularly strong for propositions of free international trade and capital flows. In contrast, macroeconomic propositions exhibit a lower degree of consensus, partly because of increased agreement with monetarist and supply-side propositions over time. The profession displays substantial skepticism concerning claims of the "New Economy.".