hexane-1,6-diyl-bis(4-(4-(5-chloro-2-methylthiophen-3-yl)furan-3-yl)-5-methylthiophene-2-carboxylate) | 1562225-02-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: hexane-1,6-diyl-bis(4-(4-(5-chloro-2-methylthiophen-3-yl)furan-3-yl)-5-methylthiophene-2-carboxylate)
• 英文别名: 6-[4-[4-(5-Chloro-2-methylthiophen-3-yl)furan-3-yl]-5-methylthiophene-2-carbonyl]oxyhexyl 4-[4-(5-chloro-2-methylthiophen-3-yl)furan-3-yl]-5-methylthiophene-2-carboxylate；6-[4-[4-(5-chloro-2-methylthiophen-3-yl)furan-3-yl]-5-methylthiophene-2-carbonyl]oxyhexyl 4-[4-(5-chloro-2-methylthiophen-3-yl)furan-3-yl]-5-methylthiophene-2-carboxylate
• CAS: 1562225-02-8
• 化学式: C₃₆H₃₂Cl₂O₆S₄
• 分子量: 759.816
• InChiKey: ODQQXGPUIATFBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.3
• 重原子数：
  48
• 可旋转键数：
  15
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  192
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  3,4-bis(5-chloro-2-methylthiophen-3-yl)furan 在 4-二甲氨基吡啶 、 正丁基锂 作用下， 以 四氢呋喃 、 乙醚 、 二氯甲烷 、 正戊烷 为溶剂， 反应 93.92h， 生成 hexane-1,6-diyl-bis(4-(4-(5-chloro-2-methylthiophen-3-yl)furan-3-yl)-5-methylthiophene-2-carboxylate)
  参考文献：
  名称：

  Controlling a Polymer Adhesive Using Light and a Molecular Switch

  摘要：

  A thermally remendable polymer was synthesized by the Diels-Alder reaction between dithienylfuran and maleimide monomers to generate a photoresponsive diarylethene. UV light (312 nm) and visible light (>435 nm) "gate" the reversibility of the Diels Alder reaction and turn the self-healing properties of the polymer "off" and "on", respectively. After exposure to UV light, the strength of the polymer as an adhesive is enhanced. Visible light weakens the adhesive.

  DOI：

  10.1021/ja500496n

文献信息

• Controlling a Polymer Adhesive Using Light and a Molecular Switch
  作者：Amir Mahmoud Asadirad、Stéphanie Boutault、Zach Erno、Neil R. Branda

  DOI：10.1021/ja500496n

  日期：2014.2.26

  A thermally remendable polymer was synthesized by the Diels-Alder reaction between dithienylfuran and maleimide monomers to generate a photoresponsive diarylethene. UV light (312 nm) and visible light (>435 nm) "gate" the reversibility of the Diels Alder reaction and turn the self-healing properties of the polymer "off" and "on", respectively. After exposure to UV light, the strength of the polymer as an adhesive is enhanced. Visible light weakens the adhesive.